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</div><h2>SL Paper 1</h2><div class="question">
<p>Which combination best describes the substitution reaction between bromoethane and dilute aqueous sodium hydroxide?</p>
<p>\[{\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{Br}} + {\text{O}}{{\text{H}}^ - } \to {\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{OH}} + {\text{B}}{{\text{r}}^ - }\]</p>
<p><img src="images/Schermafbeelding_2016-08-09_om_10.44.43.png" alt="M15/4/CHEMI/SPM/ENG/TZ2/29"></p>
</div>
<h2 style="margin-top: 1em">Markscheme</h2>
<div class="question">
<p>B</p>
</div>
<h2 style="margin-top: 1em">Examiners report</h2>
<div class="question">
[N/A]
</div>
<br><hr><br><div class="question">
<p>In organic reaction mechanisms, what does a curly arrow represent?</p>
<p>A. The movement of a pair of electrons towards a nucleophile</p>
<p>B. The movement of a pair of electrons towards a positively charged species</p>
<p>C. The movement of a pair of electrons away from a positively charged species</p>
<p>D. The movement of a pair of electrons towards a Lewis base</p>
</div>
<h2 style="margin-top: 1em">Markscheme</h2>
<div class="question">
<p>B</p>
</div>
<h2 style="margin-top: 1em">Examiners report</h2>
<div class="question">
<p>This question generated considerable discussion both in the G2s and on-line. The examiners accept that the question could have been worded better. Candidates are, however, instructed to choose the best answer and this 40% of them did. Interestingly, 36% thought the answer to be A which is clearly wrong.</p>
</div>
<br><hr><br><div class="question">
<p class="p1">Which type of reaction occurs when 2-iodo-2-methylpropane, \({\text{C(C}}{{\text{H}}_{\text{3}}}{{\text{)}}_{\text{3}}}{\text{I}}\), reacts with aqueous sodium hydroxide, NaOH(aq)?</p>
<p class="p1">A. <span class="Apple-converted-space"> </span>Addition</p>
<p class="p1">B. <span class="Apple-converted-space"> </span>Free-radical substitution</p>
<p class="p1">C. <span class="Apple-converted-space"> </span>\({{\text{S}}_{\text{N}}}{\text{1}}\)</p>
<p class="p1">D. <span class="Apple-converted-space"> </span>\({{\text{S}}_{\text{N}}}{\text{2}}\)</p>
</div>
<h2 style="margin-top: 1em">Markscheme</h2>
<div class="question">
<p>C</p>
</div>
<h2 style="margin-top: 1em">Examiners report</h2>
<div class="question">
[N/A]
</div>
<br><hr><br><div class="question">
<p class="p1">Propene is converted to propanone in a two stage process.</p>
<p class="p1">\[{\text{Propene}} \to {\text{X}} \to {\text{Propanone}}\]</p>
<p class="p1">What is the formula of compound X?</p>
<p class="p1">A. <span class="Apple-converted-space"> </span>\({\text{C}}{{\text{H}}_{\text{3}}}{\text{CHBrC}}{{\text{H}}_{\text{3}}}\)</p>
<p class="p1">B. <span class="Apple-converted-space"> </span>\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{Br}}\)</p>
<p class="p1">C. <span class="Apple-converted-space"> </span>\({\text{C}}{{\text{H}}_{\text{3}}}{\text{CHOHC}}{{\text{H}}_{\text{3}}}\)</p>
<p class="p1">D. <span class="Apple-converted-space"> </span>\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{OH}}\)</p>
</div>
<h2 style="margin-top: 1em">Markscheme</h2>
<div class="question">
<p>C</p>
</div>
<h2 style="margin-top: 1em">Examiners report</h2>
<div class="question">
[N/A]
</div>
<br><hr><br><div class="question">
<p>Chloroethane, \({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{Cl}}\), reacts with aqueous sodium hydroxide, NaOH, to form ethanol, \({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{OH}}\).</p>
<p>Which statement about the mechanism of this reaction is correct?</p>
<p>A. The reaction follows an \({{\text{S}}_{\text{N}}}{\text{1}}\) mechanism.</p>
<p>B. Homolytic fission of the carbon-chlorine bond occurs in chloroethane.</p>
<p>C. The reaction is unimolecular.</p>
<p>D. The transition state formed is negatively charged.</p>
</div>
<h2 style="margin-top: 1em">Markscheme</h2>
<div class="question">
<p>D</p>
</div>
<h2 style="margin-top: 1em">Examiners report</h2>
<div class="question">
<p>Answers A and B were often chosen as candidates presumably thought the mechanism to be either \({{\text{S}}_{\text{N}}}{\text{1}}\) or free radical.</p>
</div>
<br><hr><br><div class="question">
<p>Which type of halogenoalkane is the substance shown below, and which type of nucleophilic reaction does it undergo with an aqueous sodium hydroxide solution?</p>
<p style="text-align: center;"><img src="images/Schermafbeelding_2016-08-16_om_08.08.12.png" alt="M14/4/CHEMI/SPM/ENG/TZ1/28.01"></p>
<p style="text-align: left;"><img src="images/Schermafbeelding_2016-08-16_om_08.09.33.png" alt="M14/4/CHEMI/SPM/ENG/TZ1/28.02"></p>
</div>
<h2 style="margin-top: 1em">Markscheme</h2>
<div class="question">
<p>C</p>
</div>
<h2 style="margin-top: 1em">Examiners report</h2>
<div class="question">
[N/A]
</div>
<br><hr><br><div class="question">
<p class="p1">What is the type of mechanism and an important feature of the reaction between \({\text{C(C}}{{\text{H}}_{\text{3}}}{{\text{)}}_{\text{3}}}{\text{Br}}\) and aqueous NaOH?</p>
<p class="p1"><img src="images/Schermafbeelding_2016-10-25_om_06.08.48.png" alt="M11/4/CHEMI/SPM/ENG/TZ1/27"></p>
</div>
<h2 style="margin-top: 1em">Markscheme</h2>
<div class="question">
<p>B</p>
</div>
<h2 style="margin-top: 1em">Examiners report</h2>
<div class="question">
<p class="p1">There were several comments on this question. One respondent stated that the terms were not covered in their IB textbook. It should be emphasised that it is the guide which defines the syllabus ONLY and NOT any one particular textbook which may be written for the programme itself. Other respondents stated that terms such as transition state and intermediate were not covered in the programme. However, this question relates to AS 10.5.2 and as such it is expected that some universally used terms would be introduced to candidates in explaining both \({{\text{S}}_{\text{N}}}\) mechanisms. The question certainly was very challenging for candidates and only 32.68% of candidates got the correct answer B.</p>
</div>
<br><hr><br><div class="question">
<p class="p1">From which monomer is this polymer made?</p>
<p class="p1" style="text-align: center;"><img src="images/Schermafbeelding_2016-11-03_om_14.22.36.png" alt="N11/4/CHEMI/SPM/ENG/TZ0/28_1"></p>
<p class="p1" style="text-align: left;"><img src="images/Schermafbeelding_2016-11-03_om_14.23.36.png" alt="N11/4/CHEMI/SPM/ENG/TZ0/28_2"></p>
</div>
<h2 style="margin-top: 1em">Markscheme</h2>
<div class="question">
<p>A</p>
</div>
<h2 style="margin-top: 1em">Examiners report</h2>
<div class="question">
[N/A]
</div>
<br><hr><br>