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fusion & nuclear fission reactions</a></li><li><a href="../19429/solar-energy-1.html">Solar energy</a></li><li><a href="../19437/environmental-impact-global-warming-1.html">Environmental impact - global warming</a></li><li><a href="../19453/electrochemistry-rechargeable-batteries-fuel-cells-1.html">Electrochemistry, rechargeable batteries & fuel cells</a></li><li><a href="../19458/nuclear-fusion-fission-hl--1.html">Nuclear fusion & fission (HL)    </a></li><li><a href="../19470/photovoltaic-cells-and-dsscs-1.html">Photovoltaic cells and DSSCs</a></li></ul></li><li><a href="../19078/option-d-1.html" class="father">Option D</a><ul class="level-2"><li><a href="../19079/pharmaceutical-products-drug-action--1.html">Pharmaceutical products & drug action </a></li><li><a href="../19158/aspirin-penicillin--1.html">Aspirin & penicillin  </a></li><li><a href="../19174/opiates-1.html">Opiates</a></li><li><a href="../19184/ph-regulation-of-the-stomach-1.html">pH regulation of the stomach</a></li><li><a href="../19194/antiviral-medications--1.html">Antiviral medications </a></li><li><a href="../19211/environmental-impact-of-some-medications-1.html">Environmental impact of some medications</a></li><li><a href="../19254/taxol-a-chiral-auxiliary-case-study-1.html">Taxol - a chiral auxiliary case study</a></li><li><a href="../19258/nuclear-medicine--1.html">Nuclear medicine  </a></li><li><a href="../19273/drug-detection-analysis--1.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../16592/practical-scheme-of-work-ia--1.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../16682/internal-assessment-1.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../18892/scaffolding-the-investigation-1.html">&#039;Scaffolding&#039; the investigation</a></li><li><a href="../18896/timing-organisation--1.html">Timing & organisation </a></li><li><a href="../18905/choosing-the-research-question-1.html">Choosing the research question</a></li><li><a href="../18946/personal-engagement-1.html">Personal engagement</a></li><li><a href="../18950/exploration-1.html">Exploration</a></li><li><a href="../18957/analysis-1.html">Analysis</a></li><li><a href="../18965/evaluation-1.html">Evaluation</a></li><li><a href="../18966/communication-1.html">Communication</a></li><li><a href="../19882/internal-standardization-of-the-ia-1.html">Internal standardization of the IA</a></li><li><a href="../19901/submitting-the-samples-for-moderation-2.html">Submitting the samples for moderation</a></li><li><a href="../33754/ten-suggestions-for-ias-using-secondary-data-1.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../37544/gaining-full-marks-for-a-databased-ia--1.html">Gaining full marks for a databased IA </a></li><li><a href="../19506/ia-example-marking-exercise--1.html">IA example & marking exercise </a></li><li><a href="../23929/genuine-examples-of-moderated-ia-reports-1.html">Genuine examples of moderated IA reports</a></li><li><a href="../25234/examples-of-teacher-marked-ia-reports--1.html">Examples of teacher-marked IA reports </a></li><li><a href="../37542/history-of-internal-assessment-1.html">History of Internal Assessment</a></li></ul></li><li><a href="../16598/mandatory-laboratory-components-1.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../16613/formula-of-magnesium-oxide--1.html">Formula of magnesium oxide </a></li><li><a href="../16612/determining-the-mr-of-an-unknown-gas-1.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../16615/acid-base-titrations--1.html">Acid-base titrations </a></li><li><a href="../16616/a-green-acid-base-practical-1.html">A green acid-base practical</a></li><li><a href="../16617/analysis-of-aspirin-tablets-1.html">Analysis of aspirin tablets</a></li><li><a href="../16618/caco3-in-egg-shells-1.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../16644/enthalpy-changes-1.html">Enthalpy changes</a></li><li><a href="../16631/reaction-rates-1.html">Reaction rates</a></li><li><a href="../16635/rate-dependent-factors-1.html">Rate-dependent factors</a></li><li><a href="../16636/determining-ea-for-a-reaction-1.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../16637/iodination-of-propanone-1.html">Iodination of propanone</a></li><li><a href="../18144/titrations-with-a-ph-meter-1.html">Titrations with a pH meter</a></li><li><a href="../18355/redox-titration-with-kmno4--1.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../16640/voltaic-cells-1.html">Voltaic cells</a></li><li><a href="../16659/3-d-molecular-modelling--1.html">3-D molecular modelling </a></li></ul></li><li><a href="../17168/other-good-practicals-1.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../17196/common-chemical-reactions-1.html">Common chemical reactions</a></li><li><a href="../227/elements-oxides-of-the-third-period--1.html">Elements & oxides of the third period </a></li><li><a href="../17239/the-halogens-1.html">The halogens</a></li><li><a href="../17162/boiling-points-of-mixtures-1.html">Boiling points of mixtures</a></li><li><a href="../17170/polarity-of-molecules-1.html">Polarity of molecules</a></li><li><a href="../18083/le-chateliers-principle--1.html">Le Chatelier&#039;s principle </a></li><li><a href="../19582/determining-kc-for-an-esterification-reaction-1.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../18164/redox-reactions-of-vanadium--1.html">Redox reactions of vanadium </a></li><li><a href="../18351/chlorine-in-swimming-pools--1.html">Chlorine in swimming pools </a></li><li><a href="../18178/analysis-of-cuii-ions-in-solution--1.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../18179/percentage-of-copper-in-brass-1.html">Percentage of copper in brass</a></li><li><a href="../18356/electrolytic-cells--1.html">Electrolytic cells </a></li><li><a href="../18598/reactions-of-organic-compounds-1.html">Reactions of organic compounds</a></li><li><a href="../18752/hydrolysis-of-halogenoalkanes-1.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../18784/preparation-of-13-dinitrobenzene--1.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../19022/determination-of-an-organic-structure-1.html">Determination of an organic structure</a></li><li><a href="../19887/preparation-of-nylon-66-1.html">Preparation of nylon 6,6</a></li><li><a href="../19343/determination-of-vitamin-c-content--1.html">Determination of vitamin C content </a></li><li><a href="../19342/hydrolysis-of-starch--1.html">Hydrolysis of starch </a></li><li><a href="../19159/preparation-purification-of-aspirin--1.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../18851/ict-in-practical-work-1.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../18852/data-logging--1.html">Data logging </a></li><li><a href="../18853/software-for-graph-plotting--1.html">Software for graph plotting </a></li><li><a href="../18854/spreadsheets-for-data-processing--1.html">Spreadsheets for data processing </a></li><li><a href="../18855/databases-1.html">Databases</a></li><li><a href="../18856/computer-modelling-simulations--1.html">Computer modelling & simulations </a></li></ul></li><li><a href="../16594/group-4-project-1.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../16595/practicalities-1.html">Practicalities</a></li><li><a href="../16596/reflective-statement--2.html">Reflective statement </a></li></ul></li><li><a href="../16666/a-new-laboratory-1.html">A new laboratory?</a></li></ul></li><li><a href="../16284/exams-1.html">Exams</a><ul class="level-1"><li><a href="../16286/essential-facts-1.html" class="father">Essential Facts</a><ul class="level-2"><li><a href="../16287/objectives-command-terms-1.html">Objectives & command terms</a></li><li><a href="../16288/grade-descriptors-1.html">Grade descriptors</a></li><li><a href="../16289/grade-boundaries-1.html">Grade boundaries</a></li></ul></li><li><a href="../16302/paper-1-multiple-choice-1.html" class="father">Paper 1 (Multiple Choice)</a><ul class="level-2"><li><a href="../16303/advice-to-students-paper-1-1.html">Advice to students (Paper 1)</a></li><li><a href="../31515/practice-paper-1-exams-1.html">Practice Paper 1 exams</a></li></ul></li><li><a href="../16305/paper-2-1.html" class="father">Paper 2</a><ul class="level-2"><li><a href="../16306/advice-to-students-paper-2-1.html">Advice to students (Paper 2)</a></li><li><a href="../16307/areas-of-difficulty-1.html">Areas of difficulty</a></li></ul></li><li><a href="../16313/paper-3--1.html" class="father">Paper 3 </a><ul class="level-2"><li><a href="../16314/advice-to-students-paper-3-1.html">Advice to students (Paper 3)</a></li><li><a href="../16342/data-response-questions-1.html">Data response questions</a></li><li><a href="../20054/experimental-work-questions-1.html">Experimental work questions</a></li></ul></li><li><a href="../16324/the-examination-process-1.html" class="father">The examination process</a><ul class="level-2"><li><a href="../16316/setting-the-exam-papers-1.html">Setting the exam papers</a></li><li><a href="../16317/predicted-grades-1.html">Predicted grades</a></li><li><a href="../16318/marking-the-papers-1.html">Marking the papers</a></li><li><a href="../16319/commenting-on-the-exams-1.html">Commenting on the exams</a></li><li><a href="../16320/grade-awarding-1.html">Grade Awarding</a></li><li><a href="../16321/enquiry-upon-results-1.html">Enquiry upon results</a></li><li><a href="../16322/chief-examiners-report-1.html">Chief Examiner&#039;s report</a></li><li><a href="../16323/retaking-the-exam-1.html">Retaking the exam</a></li></ul></li><li><a 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concepts</a></li><li><a href="../3507/why-tok-chemistry-1.html">Why TOK & Chemistry?</a></li><li><a href="../3505/a-modern-paradigm-1.html">A modern paradigm</a></li></ul></li></ul></li><li><a href="../17783/fast-track-to-tests-questions-1.html">Fast track to tests & questions</a><ul class="level-1"><li><a href="../17784/sl-multiple-choice-tests-on-individual-topics-1.html">SL Multiple choice tests on individual topics</a></li><li><a href="../24351/sl-multiple-choice-quizzes-on-sub-topics-1.html">SL Multiple choice &#039;quizzes&#039; on sub-topics</a></li><li><a href="../31519/sl-practice-paper-1-exams-1.html">SL Practice Paper 1 exams</a></li><li><a href="../17786/sl-questions-on-each-sub-topic-1.html">SL Questions on each sub-topic</a></li><li><a href="../20431/sl-paper-3-section-a-questions-1.html">SL Paper 3 Section A questions</a></li><li><a href="../17792/sl-questions-on-the-options-1.html">SL Questions on the options</a></li><li><a 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Theories of acids & bases">MC test: Theories of acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40963/theories-of-acids-bases-questions-1.html" title="Theories of acids & bases questions">Theories of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18126/properties-of-acids-bases-1.html" title="Properties of acids & bases">Properties of acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24663/mc-test-properties-of-acids-bases--1.html" title="MC test: Properties of acids & bases ">MC test: Properties of acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40964/properties-of-acids-bases-questions-1.html" title="Properties of acids & bases questions">Properties of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18140/ph-scale-1.html" title="pH scale">pH scale</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24668/mc-test-the-ph-scale-1.html" title="MC test: The pH scale">MC test: The pH scale</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40971/ph-scale-questions-1.html" title="pH scale questions">pH scale questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18152/strong-weak-acids-bases-1.html" title="Strong & weak acids & bases">Strong & weak acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24670/mc-test-strong-weak-acids-bases-1.html" title="MC test: Strong & weak acids & bases">MC test: Strong & weak acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40972/strong-weak-acid-bases-questions-1.html" title="Strong & weak acid & bases questions">Strong & weak acid & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18156/acid-deposition-1.html" title="Acid deposition">Acid deposition</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24674/mc-test-acid-deposition-1.html" title="MC test: Acid deposition">MC test: Acid deposition</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40983/acid-deposition-questions-1.html" title="Acid deposition questions">Acid deposition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18160/lewis-acids-bases-1.html" title="Lewis acids & bases">Lewis acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24710/mc-test-lewis-acids-bases-1.html" title="MC test: Lewis acids & bases">MC test: Lewis acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40986/lewis-acids-bases-questions-1.html" title="Lewis acids & bases questions">Lewis acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18250/acid-base-calculations-1.html" title="Acid base calculations">Acid base calculations</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24714/mc-test-calculations-involving-acids-bases--1.html" title="MC test: Calculations involving acids & bases ">MC test: Calculations involving acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40988/acid-base-calculations-questions--1.html" title="Acid-base calculations questions ">Acid-base calculations questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../26161/ph-titration-curves-1.html" title="pH titration curves">pH titration curves</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../26158/mc-test-ph-curves-1.html" title="MC test: pH curves">MC test: pH curves</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41000/ph-curves-questions--1.html" title="pH curves questions ">pH curves questions </a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18350/topics-9-19-1.html" title="Topics 9 & 19">Topics 9 & 19</a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18365/oxidation-reduction-1.html" title="Oxidation & reduction">Oxidation & reduction</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24725/mc-test-oxidation-reduction-1.html" title="MC test: Oxidation & reduction">MC test: Oxidation & reduction</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41033/oxidation-reduction-questions-1--1.html" title="Oxidation & reduction questions (1) ">Oxidation & reduction questions (1) </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41034/oxidation-reduction-questions-2-1.html" title="Oxidation & reduction questions (2)">Oxidation & reduction questions (2)</a></li><li class="" style="padding-left: 42px"><i class="expander 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title="Electrochemical cells (AHL) ">Electrochemical cells (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24742/mc-test-electrochemical-cells-ahl-1.html" title="MC test: Electrochemical cells (AHL)">MC test: Electrochemical cells (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41098/electrochemical-cells-1-ahl-questions-1.html" title="Electrochemical cells (1) (AHL) questions">Electrochemical cells (1) (AHL) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41099/electrochemical-cells-2-ahl-questions-1.html" title="Electrochemical cells (2) (AHL) questions">Electrochemical cells (2) (AHL) questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18475/topics-10-20--1.html" title="Topics 10 & 20 ">Topics 10 & 20 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18497/fundamentals-of-organic-chemistry--1.html" title="Fundamentals of organic chemistry ">Fundamentals of organic chemistry </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24749/mc-test-fundamentals-of-organic-chemistry-1.html" title="MC test: Fundamentals of organic chemistry">MC test: Fundamentals of organic chemistry</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41111/fundamentals-of-organic-chemistry-1-questions-1.html" title="Fundamentals of organic chemistry (1) questions">Fundamentals of organic chemistry (1) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41112/fundamentals-of-organic-chemistry-2-questions-1.html" title="Fundamentals of organic chemistry (2) questions">Fundamentals of organic chemistry (2) questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18597/alkanes-alkenes-addition-polymers-1.html" title="Alkanes, alkenes & addition polymers">Alkanes, alkenes & addition polymers</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24750/mc-test-alkanes-alkenes-addition-polymers-1.html" title="MC test: Alkanes, alkenes & addition polymers">MC test: Alkanes, alkenes & addition polymers</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41121/alkanes-questions-1.html" title="Alkanes questions">Alkanes questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41124/alkenes-questions-1.html" title="Alkenes questions">Alkenes questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18741/alcohols--1.html" title="Alcohols ">Alcohols </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24772/mc-test-alcohols-1.html" title="MC test: Alcohols">MC test: Alcohols</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41125/alcohols-questions-1.html" title="Alcohols questions">Alcohols questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18742/halogenoalkanes-benzene--1.html" title="Halogenoalkanes & benzene ">Halogenoalkanes & benzene </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24797/mc-test-halogenoalkanes-benzene-1.html" title="MC test: Halogenoalkanes & benzene">MC test: Halogenoalkanes & benzene</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41130/halogenoalkanes-benzene-questions-1.html" title="Halogenoalkanes & benzene questions">Halogenoalkanes & benzene questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18762/nucleophilic-substitution--1.html" title="Nucleophilic substitution ">Nucleophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24757/mc-test-nucleophilic-substitution-1.html" title="MC test: Nucleophilic substitution">MC test: Nucleophilic substitution</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41138/nucleophilic-substitution-questions-1.html" title="Nucleophilic substitution questions">Nucleophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18766/electrophilic-addition--1.html" title="Electrophilic addition ">Electrophilic addition </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24805/mc-test-electrophilic-addition-electrophilic-substitution-reacti-2.html" title="MC test: Electrophilic addition & electrophilic substitution reactions">MC test: Electrophilic addition & electrophilic substitution reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41148/electrophilic-addition-questions-1.html" title="Electrophilic addition questions">Electrophilic addition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18780/electrophilic-substitution--2.html" title="Electrophilic substitution ">Electrophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41149/electrophilic-substitution-questions-1.html" title="Electrophilic substitution questions">Electrophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18793/reduction-reactions--1.html" title="Reduction reactions ">Reduction reactions </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24811/mc-test-reduction-reactions-1.html" title="MC test: Reduction reactions">MC test: Reduction reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41150/reduction-reactions-questions-1.html" title="Reduction reactions questions">Reduction reactions questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18797/synthetic-routes--1.html" title="Synthetic routes ">Synthetic routes </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24822/mc-test-synthetic-routes-1.html" title="MC test: Synthetic routes">MC test: Synthetic routes</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41152/synthetic-routes-questions--1.html" title="Synthetic routes questions ">Synthetic routes questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18844/stereoisomerism--1.html" title="Stereoisomerism  ">Stereoisomerism  </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24817/mc-test-stereoisomerism-1.html" title="MC test: Stereoisomerism">MC test: Stereoisomerism</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41166/stereoisomerism-questions-1.html" title="Stereoisomerism questions">Stereoisomerism questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17285/topics-11-21--1.html" title="Topics 11 & 21 ">Topics 11 & 21 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17276/uncertainty-errors--1.html" title="Uncertainty & errors ">Uncertainty & errors </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24818/mc-test-uncertainties-errors-1.html" title="MC test: Uncertainties & errors">MC test: Uncertainties & errors</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../38869/uncertainty-error-questions--1.html" title="Uncertainty & error questions ">Uncertainty & error questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../15014/graphical-techniques-1.html" title="Graphical techniques">Graphical techniques</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24819/mc-test-graphical-techniques-1.html" title="MC test: Graphical techniques">MC test: Graphical techniques</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39387/graphical-techniques-questions--1.html" title="Graphical techniques questions ">Graphical techniques questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18968/spectroscopic-identification-of-organic-compounds-1.html" title="Spectroscopic identification of organic compounds">Spectroscopic identification of organic compounds</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24820/mc-test-spectroscopic-identification-of-organic-compounds--1.html" title="MC test: Spectroscopic identification of organic compounds ">MC test: Spectroscopic identification of organic compounds </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39388/index-of-hydrogen-deficiency-questions-1.html" title="Index of hydrogen deficiency questions">Index of hydrogen deficiency questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39351/identification-from-spectra-question-1-1.html" title="Identification from spectra - Question 1">Identification from spectra - Question 1</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39353/identification-from-spectra-question-2-1.html" title="Identification from spectra - Question 2">Identification from spectra - Question 2</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39354/identification-from-spectra-question-3-1.html" title="Identification from spectra - Question 3">Identification from spectra - Question 3</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39355/identification-from-spectra-question-4-1.html" title="Identification from spectra - Question 4">Identification from spectra - Question 4</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39356/identification-from-spectra-question-5-1.html" title="Identification from spectra - Question 5">Identification from spectra - Question 5</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39357/identification-from-spectra-question-6-1.html" title="Identification from spectra - Question 6">Identification from spectra - Question 6</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39358/identification-from-spectra-question-7-1.html" title="Identification from spectra - Question 7">Identification from spectra - Question 7</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39359/identification-from-spectra-question-8-1.html" title="Identification from spectra - Question 8">Identification from spectra - Question 8</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39360/identification-from-spectra-question-9-1.html" title="Identification from spectra - Question 9">Identification from spectra - Question 9</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39361/identification-from-spectra-question-10-1.html" title="Identification from spectra - Question 10">Identification from spectra - Question 10</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19027/spectroscopic-identification-of-organic-compounds-ahl--1.html" title="Spectroscopic identification of organic compounds (AHL) ">Spectroscopic identification of organic compounds (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24821/mc-test-spectroscopic-identification-of-organic-compounds-ahl-1.html" title="MC test: Spectroscopic identification of organic compounds (AHL)">MC test: Spectroscopic identification of organic compounds (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39375/identification-from-spectra-question-11-1.html" title="Identification from spectra - Question 11">Identification from spectra - Question 11</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39376/identification-from-spectra-question-12-1.html" title="Identification from spectra - Question 12">Identification from spectra - Question 12</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39377/identification-from-spectra-question-13-1.html" title="Identification from spectra - Question 13">Identification from spectra - Question 13</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39378/identification-from-spectra-question-14-1.html" title="Identification from spectra - Question 14">Identification from spectra - Question 14</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39379/identification-from-spectra-question-15-1.html" title="Identification from spectra - Question 15">Identification from spectra - Question 15</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39380/identification-from-spectra-question-16-1.html" title="Identification from spectra - Question 16">Identification from spectra - Question 16</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39381/identification-from-spectra-question-17-1.html" title="Identification from spectra - Question 17">Identification from spectra - Question 17</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39382/identification-from-spectra-question-18-1.html" title="Identification from spectra - Question 18">Identification from spectra - Question 18</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39383/identification-from-spectra-question-19-1.html" title="Identification from spectra - Question 19">Identification from spectra - Question 19</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39385/identification-from-spectra-question-20-1.html" title="Identification from spectra - Question 20">Identification from spectra - Question 20</a></li></ul></ul></ul><li class="ancestor parent" style="padding-left: 0px"><i class="expander fa fa-caret-right fa-rotate-90"></i><a href="../16441/the-nature-of-science-1.html" title="The Nature of Science">The Nature of Science</a></li><ul class="level-1 expanded"><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16450/key-terms-concepts-1.html" title="Key terms & concepts">Key terms & concepts</a></li><li class="current" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="nos-critical-thinking-1.html" title="NOS & Critical Thinking">NOS & Critical Thinking</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../32100/how-the-elements-were-named-1.html" title="How the elements were named">How the elements were named</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../36753/the-culture-of-chemistry-1.html" title="The Culture of Chemistry">The Culture of Chemistry</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17333/nature-of-science-questions-1.html" title="Nature of Science questions">Nature of Science questions</a></li></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../16413/incorporating-im-tok-utilization-etc-1.html" title="Incorporating IM, TOK, &#039;Utilization&#039; etc.">Incorporating IM, TOK, &#039;Utilization&#039; etc.</a></li><ul class="level-1 "><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16414/topic-1-1.html" title="Topic 1">Topic 1</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16916/topics-2-12-1.html" title="Topics 2 & 12">Topics 2 & 12</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17023/topics-3-13--1.html" title="Topics 3 & 13  ">Topics 3 & 13  </a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17055/topics-4-14--1.html" title="Topics 4 & 14 ">Topics 4 & 14 </a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17270/topics-5-15--1.html" title="Topics 5 & 15  ">Topics 5 & 15  </a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17854/topics-6-16--1.html" title="Topics 6 & 16 ">Topics 6 & 16 </a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18041/topics-7-17--1.html" title="Topics 7 & 17 ">Topics 7 & 17 </a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a 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href="../17867/relating-topics-4-14-to-all-the-other-topics-1.html" title="Relating Topics 4 & 14 to all the other topics">Relating Topics 4 & 14 to all the other topics</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17868/example-of-connections-1.html" title="Example of connections">Example of connections</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../34404/hydroxychloroquine-ib-chemistry-1.html" title="Hydroxychloroquine & IB Chemistry">Hydroxychloroquine & IB Chemistry</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../35418/ammonium-nitrate-ib-chemistry-1.html" title="Ammonium nitrate & IB Chemistry">Ammonium nitrate & IB Chemistry</a></li></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../16685/multiple-choice-tests-for-each-topic-1.html" title="Multiple choice tests for each topic">Multiple choice tests for each topic</a></li><ul class="level-1 "><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16687/sl-questions-by-topic-1.html" title="SL Questions by topic">SL Questions by topic</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16903/1-stoichiometric-relationships-1--1.html" title="1. Stoichiometric relationships (1) ">1. Stoichiometric relationships (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16904/1-stoichiometric-relationships-2--1.html" title="1. Stoichiometric relationships (2) ">1. Stoichiometric relationships (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16710/2-atomic-structure-1.html" title="2. Atomic structure">2. Atomic structure</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16738/3-periodicity-1.html" title="3. Periodicity">3. Periodicity</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16822/4-chemical-bonding-structure-1-1.html" title="4. Chemical bonding & structure (1)">4. Chemical bonding & structure (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16823/4-chemical-bonding-structure-2-1.html" title="4. Chemical bonding & structure (2)">4. Chemical bonding & structure (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16887/5-energetics-thermochemistry-1.html" title="5. Energetics & thermochemistry">5. Energetics & thermochemistry</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16906/6-chemical-kinetics-1.html" title="6. Chemical kinetics">6. Chemical kinetics</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17464/7-equilibrium-1.html" title="7. Equilibrium">7. Equilibrium</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17420/8-acids-and-bases-1.html" title="8. Acids and bases">8. Acids and bases</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17416/9-redox-processes-1.html" title="9. Redox processes">9. Redox processes</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17411/10-organic-chemistry-1--1.html" title="10. Organic chemistry (1) ">10. Organic chemistry (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17412/10-organic-chemistry-2--1.html" title="10. Organic chemistry (2) ">10. Organic chemistry (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17286/11-measurement-data-processing-1--1.html" title="11. Measurement & data processing (1) ">11. Measurement & data processing (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17287/11-measurement-data-processing-2-1.html" title="11. Measurement & data processing (2)">11. Measurement & data processing (2)</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16688/hl-questions-by-topic-1.html" title="HL Questions by topic">HL Questions by topic</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16709/1-stoichiometric-relationships-1-1.html" title="1. Stoichiometric relationships (1)">1. Stoichiometric relationships (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16735/1-stoichiometric-relationships-2-1.html" title="1. Stoichiometric relationships (2)">1. Stoichiometric relationships (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../37016/2-12-atomic-structure-1-1.html" title="2 &12. Atomic structure (1)">2 &12. Atomic structure (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16721/2-12-atomic-structure-2-1.html" title="2 &12. Atomic structure (2)">2 &12. Atomic structure (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16815/3-13-periodicity-transition-metals-1--1.html" title="3 & 13. Periodicity & transition metals (1) ">3 & 13. Periodicity & transition metals (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16816/3-13-periodicity-transition-metals-2--1.html" title="3 & 13. Periodicity & transition metals (2) ">3 & 13. Periodicity & transition metals (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16861/4-14-chemical-bonding-structure-1-1.html" title="4 & 14. Chemical bonding & structure (1)">4 & 14. Chemical bonding & structure (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16862/4-14-chemical-bonding-structure-2-1.html" title="4 & 14. Chemical bonding & structure (2)">4 & 14. Chemical bonding & structure (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16894/5-15-energetics-thermochemistry-1--1.html" title="5 & 15. Energetics & thermochemistry (1) ">5 & 15. Energetics & thermochemistry (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16893/5-15-energetics-thermochemistry-2--1.html" title="5 & 15. Energetics & thermochemistry (2) ">5 & 15. Energetics & thermochemistry (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17654/6-16-chemical-kinetics-1--1.html" title="6 & 16. Chemical kinetics (1) ">6 & 16. Chemical kinetics (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17655/6-16-chemical-kinetics-2--1.html" title="6 & 16. Chemical kinetics (2)  ">6 & 16. Chemical kinetics (2)  </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17471/7-17-equilibrium-1--1.html" title="7 & 17. Equilibrium (1) ">7 & 17. Equilibrium (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17472/7-17-equilibrium-2--1.html" title="7 & 17. Equilibrium (2) ">7 & 17. Equilibrium (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17421/8-18-acids-bases-1--1.html" title="8 & 18. Acids & bases (1) ">8 & 18. Acids & bases (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17422/8-18-acids-bases-2--1.html" title="8 & 18. Acids & bases (2) ">8 & 18. Acids & bases (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17417/9-19-redox-processes-1--1.html" title="9 & 19 Redox processes (1) ">9 & 19 Redox processes (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17418/9-19-redox-processes-2--1.html" title="9 & 19. Redox processes (2) ">9 & 19. Redox processes (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17413/10-20-organic-chemistry-1--1.html" title="10 & 20. 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</div><section id="main-content"><div id="toc-1672969608" class="toc"><a href="#" class="toc-switcher" title="Show table of contents"><small><i class="fa fa-reorder"></i> Table of contents <span class="pull-right"><i class="fa fa-chevron-down"></i></span></small></a></div><p>In order to think critically in chemistry a knowledge of both chemistry and the nature of science is required. This page gives a simple example of this then provides a full worked example you can give to your HL students to guide them. It will show them that even if the assumptions they make to arrive at a prediction give the correct prediction it does not follow that the assumptions used are correct.</p><div class="blueBg"><h1>Introduction</h1><p><img alt="" class="noborder" src="../../../ib/chemistry/images/2014-blog/transition-2--ion-radii(1).png" style="width: 1px;"><a href="../22523/critical-thinking-1.html" title="Basic information » Getting started » Critical thinking">Critical thinking</a> cannot take place in a vacuum. In order to be able to think critically about chemistry a good knowledge and understanding of chemistry and its underlying culture, i.e. the nature of science, is required. As teachers it is our job to provide examples, and sometimes the context, to guide students to question the source and accuracy of their knowledge and the way in which they use it.</p><p>Some years ago I wrote a blog titled &ldquo;<a href="chemistry/blog/29985/104ku-an-anachronism-in-a-gulag"><sup>104</sup>Ku - an anachronism in a gulag</a>&rdquo;<a href="chemistry/blog/29985/104ku-an-anachronism-in-a-gulag"> </a>about a visit I made to the site of Karlag, one of the former Soviet gulags. In the museum I found a room with chemical apparatus and a periodic table which was said to have been used by some of the scientists who had been prisoners there during the Stalinist period.</p><hr class="hidden"><p style="text-align: center;"><img alt="" class="noborder" src="../../../ib/chemistry/images/2014-blog/karlag-ku.png" style="width: 600px; height: 276px;"></p><p style="text-align: center;">Mendeleev periodic table in the museum at Karlag, a former Soviet gulag</p><hr class="hidden"><p>Note that the &lsquo;periodic table&rsquo; is called the Mendeleev table, the name by which it is still known in the former Soviet Union countries. The periodic table shows one of the elements having the symbol Ku.</p><p>Only a scientist who is familiar with the elements and the way in which they can be arranged in a periodic table might question the symbol Ku for element 104, as the accepted symbol is Rf. This led me to research the origin of element 104. It &nbsp;was first discovered in 1964 by scientists working at the Joint Institute of Soviet Research in Dubna in the USSR by bombarding plutonium-242 with neon-22. The Soviet scientists named it kurchatovium with the symbol Ku after <a href="https://en.wikipedia.org/wiki/Igor_Kurchatov">Igor Kurchatov</a> (1903-1960) who was the &ldquo;father of the Soviet atomic bomb&rdquo;. In 1969 element 104 was independently synthesised at the University of California, Berkeley by bombarding californium-249 with carbon-12. The Americans claimed that they published their results first and that their work was the first to be verified independently and so claimed the right to name the element and proposed the name rutherfordium (Rf) after Ernest Rutherford (1871 &ndash; 1937). It took until 1997 before IUPAC accepted the name of the element officially as rutherfordium. What this research does show is that the Mendeleev table in the museum cannot have been in use at the gulag as the last prisoners left the gulag in 1959 &ndash; five years before kurchatovium was first discovered.&nbsp;</p><p>This story illustrates the need to have some prior knowledge to be able to think critically. Teachers often ask for examples that they can give to their students. One good source is either past examination questions or practice IB questions that can be found on the Internet where the chemistry required to solve the question has not really been thought through properly. The following question is one such example. Since most teachers cover the energetics part of the syllabus after they have done periodicity, Higher Level students should have the necessary prior knowledge to answer the question critically.</p><hr class="hidden"></div><hr class="hidden"><div class="greenBg"><h1>Question</h1><p><strong>Predict whether the hydration enthalpy of Fe<sup>2+</sup> ions will be more or less exothermic than the&nbsp; hydration enthalpy of Mn<sup>2+</sup> ions.</strong></p><hr class="hidden"><p>Some hydration enthalpies of ions are given in Section 20 of the IB data booklet but the values for Fe<sup>2+</sup> and Mn<sup>2+ </sup>are not included so students might use their prior knowledge of IB chemistry together with the accompanying logic to answer this question in the following way.</p><p>First they need to recall that hydration energy involves the reaction converting the gaseous M<sup>2+</sup>(g) ion into the hydrated ion M<sup>2+</sup>(aq). The smaller the ion and the more highly charged the ion the greater the charge density and the greater the attraction to water molecules and hence the more exothermic the hydration enthalpy.</p><p>Both Fe<sup>2+</sup> and Mn<sup>2+</sup> ions have the same charge of 2+ so their relative charge densities will depend upon their radii. The electron configurations are [Ar]3d<sup>6</sup> for Fe<sup>2+</sup> and [Ar]3d<sup>5</sup> for Mn<sup>2+</sup>. As <em>Z</em> = 26 for Fe and <em>Z</em> = 25 for Mn, Fe<sup>2+</sup> ions have one more proton in their nucleus acting on electrons in the same outer energy level so will have a smaller radius than Mn<sup>2+</sup> ions. This means that Fe<sup>2+</sup> ions will have the greater charge density so the enthalpy of hydration will be predicted to be more exothermic.</p><p>This answer agrees with the actual data as the values for the hydration energies of Fe<sup>2+</sup> and Mn<sup>2+</sup> are &minus; 1950 and &ndash; 1851 kJ mol<sup>&minus;1</sup> respectively (see table at foot of page). This deduction and prediction seems fine but supposing the question had asked students to predict which of&nbsp; Fe<sup>2+</sup> ions or Co<sup>2+</sup> ions is more likely to have the greater exothermic enthalpy of hydration. Both have the same charge of 2+,&nbsp; the electron configurations for Fe<sup>2+ </sup>and Co<sup>2+</sup> are [Ar]3d<sup>6</sup> and [Ar]3d<sup>7 </sup>respectively and the atomic numbers of Fe and Co are 26 and 27 respectively. Following the same logic, we can predict that Co<sup>2+</sup> has a smaller ionic radius than Fe<sup>2+</sup> and the enthalpy of hydration of Co<sup>2+</sup> will be greater than Fe<sup>2+</sup> as it has a greater charge density. This again agrees with the hydration enthalpy data as the value for Co<sup>2+</sup> is &minus; 2010 kJ mol<sup>&minus;1</sup> which is more exothermic than the value of &minus; 1950 kJ mol<sup>&minus;1 </sup>for Fe<sup>2+</sup>. This too all looks fine and it seems reasonable for students to assume that as their predictions are correct the logic and knowledge used to arrive at them must also be correct.</p><p>However all is not well if you go to Section 9 of the IB data booklet.</p><p>The IB data booklet shows that the ionic radius of Fe<sup>2+</sup> (61 x 10<sup>&minus;12</sup> m) is indeed smaller than the ionic radius of Mn<sup>2+</sup> (83 x 10<sup>&minus;12</sup> m) but the ionic radius of Co<sup>2+</sup>&nbsp;(65 x 10<sup>&minus;12</sup> m) is actually greater (<strong>not</strong> smaller) than the ionic radius of Fe<sup>2+</sup>. This means that the charge density of Co<sup>2+</sup> should be less than the charge density of Fe<sup>2+</sup> and the hydration energy would be predicted to be less exothermic for Co<sup>2+</sup> compared to Fe<sup>2+</sup> which is not the case.</p><p>The problem with the argument given above lies in the statement that as the number of protons increases the radius decreases as you move across the period as the outer electrons are in the same energy level. This is true for the atomic radius of the elements in the periods Li - F and Na &ndash; Cl but only just holds true for the transition metals.</p><hr class="hidden"><p style="text-align: center;"><img alt="" class="noborder" src="../../../ib/chemistry/images/2014-blog/atomic-radii.png" style="width: 600px; height: 176px;"></p><p>Atomic radii for elements in Periods 2 and 3. Note that even if the metallic radii are taken for the metals (as in the 2009 IB data booklet) the trend is still the same.</p><hr class="hidden"><p style="text-align: center;"><img alt="" class="noborder" src="../../../ib/chemistry/images/2014-blog/transition-metals-atomic-radius.png" style="width: 600px; height: 73px;"></p><p style="text-align: center;">Atomic radii for the first row transition elements</p><hr class="hidden"><p>In fact the transition metal atoms have rather similar atomic radii which only gradually decrease across the period (although copper atoms have a greater atomic radius than nickel atoms). This is one of the reasons why transition metals readily form alloys. As for the 2+ ions the ionic radius does not really follow a pattern at all. When studying periodicity students do look at the size of ions but only tend to compare isoelectronic ions such as&nbsp; Na<sup>+</sup>, Mg<sup>2+</sup> and Al<sup>3+</sup> which do decrease in size, but they do not generally compare the size of similarly charged ions such as Na<sup>+</sup>, Mg<sup>+</sup> and Al<sup>+</sup>. The values for the radii of the 2+ first row transition metal ions which are given in the IB data booklet are as follows:</p><hr class="hidden"><p style="text-align: center;"><img alt="" src="../../../ib/chemistry/images/2014-blog/transition-2--ion-radii(1).png" style="width: 613px; height: 72px;"></p><p style="text-align: center;">Ionic radii of some dipositive first row transition metal ions</p><hr class="hidden"><p>I would suggest that an IB student cannot answer this question based on their knowledge of IB chemistry without the data booklet as there is no way they could correctly predict which of any two given dipositive transition metal ions will have the smallest radius. Even using the values given for the ionic radii in the IB data booklet might still lead to an incorrect prediction since Co<sup>2+</sup> has a larger ionic radius than Fe<sup>2+</sup> and yet Co<sup>2+</sup> still has a greater exothermic enthalpy of hydration than Fe<sup>2+</sup>. So the relationship between the predicted relative charge densities and hydration energy is also not clear cut, assuming the ionic radii given in the data booklet are correct. In fact the ionic radius of the dipositive transition metal ion in a complex as opposed to the free ion in the gaseous state is not a fixed value as inferred from the IB data booklet but varies according to the coordination number of the compound, the shape of the compound and on whether it is a high-spin or low-spin complex (see <a href="../17041/first-row-d-block-elements--1.html" title="Core &amp; AHL » Teaching each topic &amp; sub-topic » Topics 3 &amp; 13 » First-row d-block elements ">First-row d-block elements)</a>, i.e. on how many unpaired electrons it contains. If there is a decrease in ionic radii in the gaseous ions as the atomic number increases then one would expect there to be a similar increase in the quantitative value of the hydration enthalpies. From the table below it can be seen this is generally true but not completely true.</p><hr class="hidden"><p style="text-align: center;"><img alt="" class="noborder" src="../../../ib/chemistry/images/2014%20Basic%20information/hydration-enthalpies-of-m2-.png" style="width: 182px; height: 359px;"></p><p style="text-align: center;">Enthalpies of hydration of some d-block dipositive ions (values from <a href="http://www.wiredchemist.com/chemistry/data/enthalpies-hydration">wiredchemist</a>)</p><hr class="hidden"></div></section></article><section id="media-extras"><div class="page-actions no-print navbar inline hidden-desktop"><div class="navbar-inner"><ul class="nav"><li><a class="presentation" href="#" onclick="return false;"><i class="fa fa-desktop"></i></a></li><li><a class="print-section-blog" href="#" onclick="return false;"><i class="fa fa-print"></i></a></li><li><a class="page-bookmarker" data-ticket="IB Docs (2) Team" data-pid="34566" href="#" onclick="return false;"><i class="fa fa-star"></i></a></li><li><a class="personal-notes" href="#" onclick="return false;"><i class="fa fa-file-text"></i></a></li><li><a class="" data-toggle="modal" href="#modal-feedback" onclick="return false;"><i class="fa fa-envelope-o"></i></a></li><li class="dropdown"><a class="dropdown-toggle" data-toggle="dropdown" data-target="#" href="#"><i class="fa fa-share-alt"></i></a><ul class="dropdown-menu" role="menu"><li><a class="" target="_blank" title="Share on Twitter" href="https://twitter.com/share?text=%22NOS+%26+Critical+Thinking%22+-+via+%40InThinker+%23chemistry%0A&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F34566%2Fnos-critical-thinking"><i class="fa fa-twitter-square"></i><span>Twitter</span></a></li><li><a class="" target="_blank" title="Share on Facebook" href="https://www.facebook.com/sharer.php?u=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F34566%2Fnos-critical-thinking&t=NOS+&+Critical+Thinking"><i class="fa fa-facebook-square"></i><span>Facebook</span></a></li><li><a class="" href="http://www.linkedin.com/shareArticle?mini=true&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F34566%2Fnos-critical-thinking"><i class="fa fa-linkedin-square"></i><span>LinkedIn</span></a></li><li><a class="" href="https://plus.google.com/share?url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F34566%2Fnos-critical-thinking"><i class="fa fa-google-plus-square"></i><span>Google +</span></a></li><li><a class="" href="mailto:?subject=NOS & Critical Thinking&body=In order to think critically in chemistry a knowledge of both chemistry and the nature of science is required. 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