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<title>DP Chemistry: Equilibrium </title>
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<meta name="description" content="Once you have explained the concept of dynamic equilibrium (as opposed to static equilibrium) it is worth challenging your students by asking them to suggest how it could be shown experimentally that either chemical or physical equilibrium is dynamic and not static. There are several ways in which it could be done but one of the most obvious is to use a radioactive isotope. Although there is no need to mention examples...">
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<meta itemprop="description" content="Once you have explained the concept of dynamic equilibrium (as opposed to static equilibrium) it is worth challenging your students by asking them to suggest how it could be shown experimentally that either chemical or physical equilibrium is dynamic and not static. There are several ways in which it could be done but one of the most obvious is to use a radioactive isotope. Although there is no need to mention examples...">
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href="../19287/proteins-enzymes--1.html">Proteins & enzymes </a></li><li><a href="../19291/lipids-1.html">Lipids</a></li><li><a href="../19299/carbohydrates--1.html">Carbohydrates </a></li><li><a href="../19305/vitamins--1.html">Vitamins </a></li><li><a href="../19313/biochemistry-the-environment--1.html">Biochemistry & the environment </a></li><li><a href="../19336/proteins-enzymes-ahl--1.html">Proteins & enzymes (AHL) </a></li><li><a href="../19347/nucleic-acids--1.html">Nucleic acids </a></li><li><a href="../19361/biological-pigments--1.html">Biological pigments </a></li><li><a href="../19366/stereochemistry-in-biomolecules-1.html">Stereochemistry in biomolecules</a></li></ul></li><li><a href="../19390/option-c--1.html" class="father">Option C </a><ul class="level-2"><li><a href="../19391/energy-sources-1.html">Energy sources</a></li><li><a href="../19407/fossil-fuels-1.html">Fossil fuels</a></li><li><a href="../19411/nuclear-fusion-nuclear-fission-reactions-1.html">Nuclear fusion & nuclear fission reactions</a></li><li><a href="../19429/solar-energy-1.html">Solar energy</a></li><li><a href="../19437/environmental-impact-global-warming-1.html">Environmental impact - global warming</a></li><li><a href="../19453/electrochemistry-rechargeable-batteries-fuel-cells-1.html">Electrochemistry, rechargeable batteries & fuel cells</a></li><li><a href="../19458/nuclear-fusion-fission-hl--1.html">Nuclear fusion & fission (HL) </a></li><li><a href="../19470/photovoltaic-cells-and-dsscs-1.html">Photovoltaic cells and DSSCs</a></li></ul></li><li><a href="../19078/option-d-1.html" class="father">Option D</a><ul class="level-2"><li><a href="../19079/pharmaceutical-products-drug-action--1.html">Pharmaceutical products & drug action </a></li><li><a href="../19158/aspirin-penicillin--1.html">Aspirin & penicillin </a></li><li><a href="../19174/opiates-1.html">Opiates</a></li><li><a href="../19184/ph-regulation-of-the-stomach-1.html">pH regulation of the stomach</a></li><li><a href="../19194/antiviral-medications--1.html">Antiviral medications </a></li><li><a href="../19211/environmental-impact-of-some-medications-1.html">Environmental impact of some medications</a></li><li><a href="../19254/taxol-a-chiral-auxiliary-case-study-1.html">Taxol - a chiral auxiliary case study</a></li><li><a href="../19258/nuclear-medicine--1.html">Nuclear medicine </a></li><li><a href="../19273/drug-detection-analysis--1.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../16592/practical-scheme-of-work-ia--1.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../16682/internal-assessment-1.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../18892/scaffolding-the-investigation-1.html">'Scaffolding' the investigation</a></li><li><a href="../18896/timing-organisation--1.html">Timing & organisation </a></li><li><a href="../18905/choosing-the-research-question-1.html">Choosing the research question</a></li><li><a href="../18946/personal-engagement-1.html">Personal engagement</a></li><li><a href="../18950/exploration-1.html">Exploration</a></li><li><a href="../18957/analysis-1.html">Analysis</a></li><li><a href="../18965/evaluation-1.html">Evaluation</a></li><li><a href="../18966/communication-1.html">Communication</a></li><li><a href="../19882/internal-standardization-of-the-ia-1.html">Internal standardization of the IA</a></li><li><a href="../19901/submitting-the-samples-for-moderation-2.html">Submitting the samples for moderation</a></li><li><a href="../33754/ten-suggestions-for-ias-using-secondary-data-1.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../37544/gaining-full-marks-for-a-databased-ia--1.html">Gaining full marks for a databased IA </a></li><li><a href="../19506/ia-example-marking-exercise--1.html">IA example & marking exercise </a></li><li><a href="../23929/genuine-examples-of-moderated-ia-reports-1.html">Genuine examples of moderated IA reports</a></li><li><a href="../25234/examples-of-teacher-marked-ia-reports--1.html">Examples of teacher-marked IA reports </a></li><li><a href="../37542/history-of-internal-assessment-1.html">History of Internal Assessment</a></li></ul></li><li><a href="../16598/mandatory-laboratory-components-1.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../16613/formula-of-magnesium-oxide--1.html">Formula of magnesium oxide </a></li><li><a href="../16612/determining-the-mr-of-an-unknown-gas-1.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../16615/acid-base-titrations--1.html">Acid-base titrations </a></li><li><a href="../16616/a-green-acid-base-practical-1.html">A green acid-base practical</a></li><li><a href="../16617/analysis-of-aspirin-tablets-1.html">Analysis of aspirin tablets</a></li><li><a href="../16618/caco3-in-egg-shells-1.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../16644/enthalpy-changes-1.html">Enthalpy changes</a></li><li><a href="../16631/reaction-rates-1.html">Reaction rates</a></li><li><a href="../16635/rate-dependent-factors-1.html">Rate-dependent factors</a></li><li><a href="../16636/determining-ea-for-a-reaction-1.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../16637/iodination-of-propanone-1.html">Iodination of propanone</a></li><li><a href="../18144/titrations-with-a-ph-meter-1.html">Titrations with a pH meter</a></li><li><a href="../18355/redox-titration-with-kmno4--1.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../16640/voltaic-cells-1.html">Voltaic cells</a></li><li><a href="../16659/3-d-molecular-modelling--1.html">3-D molecular modelling </a></li></ul></li><li><a href="../17168/other-good-practicals-1.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../17196/common-chemical-reactions-1.html">Common chemical reactions</a></li><li><a href="../227/elements-oxides-of-the-third-period--1.html">Elements & oxides of the third period </a></li><li><a href="../17239/the-halogens-1.html">The halogens</a></li><li><a href="../17162/boiling-points-of-mixtures-1.html">Boiling points of mixtures</a></li><li><a href="../17170/polarity-of-molecules-1.html">Polarity of molecules</a></li><li><a href="../18083/le-chateliers-principle--1.html">Le Chatelier's principle </a></li><li><a href="../19582/determining-kc-for-an-esterification-reaction-1.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../18164/redox-reactions-of-vanadium--1.html">Redox reactions of vanadium </a></li><li><a href="../18351/chlorine-in-swimming-pools--1.html">Chlorine in swimming pools </a></li><li><a href="../18178/analysis-of-cuii-ions-in-solution--1.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../18179/percentage-of-copper-in-brass-1.html">Percentage of copper in brass</a></li><li><a href="../18356/electrolytic-cells--1.html">Electrolytic cells </a></li><li><a href="../18598/reactions-of-organic-compounds-1.html">Reactions of organic compounds</a></li><li><a href="../18752/hydrolysis-of-halogenoalkanes-1.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../18784/preparation-of-13-dinitrobenzene--1.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../19022/determination-of-an-organic-structure-1.html">Determination of an organic structure</a></li><li><a href="../19887/preparation-of-nylon-66-1.html">Preparation of nylon 6,6</a></li><li><a href="../19343/determination-of-vitamin-c-content--1.html">Determination of vitamin C content </a></li><li><a href="../19342/hydrolysis-of-starch--1.html">Hydrolysis of starch </a></li><li><a href="../19159/preparation-purification-of-aspirin--1.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../18851/ict-in-practical-work-1.html" class="father">ICT in practical work</a><ul 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Chemistry?</a></li><li><a href="../3505/a-modern-paradigm-1.html">A modern paradigm</a></li></ul></li></ul></li><li><a href="../17783/fast-track-to-tests-questions-1.html">Fast track to tests & questions</a><ul class="level-1"><li><a href="../17784/sl-multiple-choice-tests-on-individual-topics-1.html">SL Multiple choice tests on individual topics</a></li><li><a href="../24351/sl-multiple-choice-quizzes-on-sub-topics-1.html">SL Multiple choice 'quizzes' on sub-topics</a></li><li><a href="../31519/sl-practice-paper-1-exams-1.html">SL Practice Paper 1 exams</a></li><li><a href="../17786/sl-questions-on-each-sub-topic-1.html">SL Questions on each sub-topic</a></li><li><a href="../20431/sl-paper-3-section-a-questions-1.html">SL Paper 3 Section A questions</a></li><li><a href="../17792/sl-questions-on-the-options-1.html">SL Questions on the options</a></li><li><a href="../24897/sl-quizzes-on-option-sub-topics--1.html">SL Quizzes on option sub-topics </a></li><li><a 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class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24660/mc-test-the-equilibrium-law-1.html" title="MC test: The equilibrium law">MC test: The equilibrium law</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40961/equilibrium-law-questions-1.html" title="Equilibrium law questions">Equilibrium law questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18120/topics-8-18--1.html" title="Topics 8 & 18 ">Topics 8 & 18 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18124/theories-of-acids-bases--1.html" title="Theories of acids & bases ">Theories of acids & bases </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24662/mc-test-theories-of-acids-bases-1.html" title="MC test: Theories of acids & bases">MC test: Theories of acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40963/theories-of-acids-bases-questions-1.html" title="Theories of acids & bases questions">Theories of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18126/properties-of-acids-bases-1.html" title="Properties of acids & bases">Properties of acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24663/mc-test-properties-of-acids-bases--1.html" title="MC test: Properties of acids & bases ">MC test: Properties of acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40964/properties-of-acids-bases-questions-1.html" title="Properties of acids & bases questions">Properties of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18140/ph-scale-1.html" title="pH scale">pH scale</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24668/mc-test-the-ph-scale-1.html" title="MC test: The pH scale">MC test: The pH scale</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40971/ph-scale-questions-1.html" title="pH scale questions">pH scale questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18152/strong-weak-acids-bases-1.html" title="Strong & weak acids & bases">Strong & weak acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24670/mc-test-strong-weak-acids-bases-1.html" title="MC test: Strong & weak acids & bases">MC test: Strong & weak acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40972/strong-weak-acid-bases-questions-1.html" title="Strong & weak acid & bases questions">Strong & weak acid & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18156/acid-deposition-1.html" title="Acid deposition">Acid deposition</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24674/mc-test-acid-deposition-1.html" title="MC test: Acid deposition">MC test: Acid deposition</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40983/acid-deposition-questions-1.html" title="Acid deposition questions">Acid deposition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18160/lewis-acids-bases-1.html" title="Lewis acids & bases">Lewis acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24710/mc-test-lewis-acids-bases-1.html" title="MC test: Lewis acids & bases">MC test: Lewis acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40986/lewis-acids-bases-questions-1.html" title="Lewis acids & bases questions">Lewis acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18250/acid-base-calculations-1.html" title="Acid base calculations">Acid base calculations</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24714/mc-test-calculations-involving-acids-bases--1.html" title="MC test: Calculations involving acids & bases ">MC test: Calculations involving acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40988/acid-base-calculations-questions--1.html" title="Acid-base calculations questions ">Acid-base calculations questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../26161/ph-titration-curves-1.html" title="pH titration curves">pH titration curves</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../26158/mc-test-ph-curves-1.html" title="MC test: pH curves">MC test: pH curves</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41000/ph-curves-questions--1.html" title="pH curves questions ">pH curves questions </a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18350/topics-9-19-1.html" title="Topics 9 & 19">Topics 9 & 19</a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18365/oxidation-reduction-1.html" title="Oxidation & reduction">Oxidation & reduction</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24725/mc-test-oxidation-reduction-1.html" title="MC test: Oxidation & reduction">MC test: Oxidation & reduction</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41033/oxidation-reduction-questions-1--1.html" title="Oxidation & reduction questions (1) ">Oxidation & reduction questions (1) </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41034/oxidation-reduction-questions-2-1.html" title="Oxidation & reduction questions (2)">Oxidation & reduction questions (2)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41035/oxidation-reduction-questions-3-1.html" title="Oxidation & reduction questions (3)">Oxidation & reduction questions (3)</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18383/electrochemical-cells-1.html" title="Electrochemical cells">Electrochemical cells</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24740/mc-test-electrochemical-cells-1.html" title="MC test: Electrochemical cells">MC test: Electrochemical cells</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41072/electrochemical-cells-questions--1.html" title="Electrochemical cells questions ">Electrochemical cells questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18401/electrochemical-cells-ahl--1.html" title="Electrochemical cells (AHL) ">Electrochemical cells (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24742/mc-test-electrochemical-cells-ahl-1.html" title="MC test: Electrochemical cells (AHL)">MC test: Electrochemical cells (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41098/electrochemical-cells-1-ahl-questions-1.html" title="Electrochemical cells (1) (AHL) questions">Electrochemical cells (1) (AHL) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41099/electrochemical-cells-2-ahl-questions-1.html" title="Electrochemical cells (2) (AHL) questions">Electrochemical cells (2) (AHL) questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18475/topics-10-20--1.html" title="Topics 10 & 20 ">Topics 10 & 20 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18497/fundamentals-of-organic-chemistry--1.html" title="Fundamentals of organic chemistry ">Fundamentals of organic chemistry </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24749/mc-test-fundamentals-of-organic-chemistry-1.html" title="MC test: Fundamentals of organic chemistry">MC test: Fundamentals of organic chemistry</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41111/fundamentals-of-organic-chemistry-1-questions-1.html" title="Fundamentals of organic chemistry (1) questions">Fundamentals of organic chemistry (1) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41112/fundamentals-of-organic-chemistry-2-questions-1.html" title="Fundamentals of organic chemistry (2) questions">Fundamentals of organic chemistry (2) questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18597/alkanes-alkenes-addition-polymers-1.html" title="Alkanes, alkenes & addition polymers">Alkanes, alkenes & addition polymers</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24750/mc-test-alkanes-alkenes-addition-polymers-1.html" title="MC test: Alkanes, alkenes & addition polymers">MC test: Alkanes, alkenes & addition polymers</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41121/alkanes-questions-1.html" title="Alkanes questions">Alkanes questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41124/alkenes-questions-1.html" title="Alkenes questions">Alkenes questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18741/alcohols--1.html" title="Alcohols ">Alcohols </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24772/mc-test-alcohols-1.html" title="MC test: Alcohols">MC test: Alcohols</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41125/alcohols-questions-1.html" title="Alcohols questions">Alcohols questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18742/halogenoalkanes-benzene--1.html" title="Halogenoalkanes & benzene ">Halogenoalkanes & benzene </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24797/mc-test-halogenoalkanes-benzene-1.html" title="MC test: Halogenoalkanes & benzene">MC test: Halogenoalkanes & benzene</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41130/halogenoalkanes-benzene-questions-1.html" title="Halogenoalkanes & benzene questions">Halogenoalkanes & benzene questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18762/nucleophilic-substitution--1.html" title="Nucleophilic substitution ">Nucleophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24757/mc-test-nucleophilic-substitution-1.html" title="MC test: Nucleophilic substitution">MC test: Nucleophilic substitution</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41138/nucleophilic-substitution-questions-1.html" title="Nucleophilic substitution questions">Nucleophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18766/electrophilic-addition--1.html" title="Electrophilic addition ">Electrophilic addition </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24805/mc-test-electrophilic-addition-electrophilic-substitution-reacti-2.html" title="MC test: Electrophilic addition & electrophilic substitution reactions">MC test: Electrophilic addition & electrophilic substitution reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41148/electrophilic-addition-questions-1.html" title="Electrophilic addition questions">Electrophilic addition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18780/electrophilic-substitution--2.html" title="Electrophilic substitution ">Electrophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41149/electrophilic-substitution-questions-1.html" title="Electrophilic substitution questions">Electrophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18793/reduction-reactions--1.html" title="Reduction reactions ">Reduction reactions </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24811/mc-test-reduction-reactions-1.html" title="MC test: Reduction reactions">MC test: Reduction reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41150/reduction-reactions-questions-1.html" title="Reduction reactions questions">Reduction reactions questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18797/synthetic-routes--1.html" title="Synthetic routes ">Synthetic routes </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24822/mc-test-synthetic-routes-1.html" title="MC test: Synthetic routes">MC test: Synthetic routes</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41152/synthetic-routes-questions--1.html" title="Synthetic routes questions ">Synthetic routes questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18844/stereoisomerism--1.html" title="Stereoisomerism ">Stereoisomerism </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24817/mc-test-stereoisomerism-1.html" title="MC test: Stereoisomerism">MC test: Stereoisomerism</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41166/stereoisomerism-questions-1.html" title="Stereoisomerism questions">Stereoisomerism questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17285/topics-11-21--1.html" title="Topics 11 & 21 ">Topics 11 & 21 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17276/uncertainty-errors--1.html" title="Uncertainty & errors ">Uncertainty & errors </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24818/mc-test-uncertainties-errors-1.html" title="MC test: Uncertainties & errors">MC test: Uncertainties & errors</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../38869/uncertainty-error-questions--1.html" title="Uncertainty & error questions ">Uncertainty & error questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../15014/graphical-techniques-1.html" title="Graphical techniques">Graphical techniques</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24819/mc-test-graphical-techniques-1.html" title="MC test: Graphical techniques">MC test: Graphical techniques</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39387/graphical-techniques-questions--1.html" title="Graphical techniques questions ">Graphical techniques questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18968/spectroscopic-identification-of-organic-compounds-1.html" title="Spectroscopic identification of organic compounds">Spectroscopic identification of organic compounds</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24820/mc-test-spectroscopic-identification-of-organic-compounds--1.html" title="MC test: Spectroscopic identification of organic compounds ">MC test: Spectroscopic identification of organic compounds </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39388/index-of-hydrogen-deficiency-questions-1.html" title="Index of hydrogen deficiency questions">Index of hydrogen deficiency questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39351/identification-from-spectra-question-1-1.html" title="Identification from spectra - Question 1">Identification from spectra - Question 1</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39353/identification-from-spectra-question-2-1.html" title="Identification from spectra - Question 2">Identification from spectra - Question 2</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39354/identification-from-spectra-question-3-1.html" title="Identification from spectra - Question 3">Identification from spectra - Question 3</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39355/identification-from-spectra-question-4-1.html" title="Identification from spectra - Question 4">Identification from spectra - Question 4</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39356/identification-from-spectra-question-5-1.html" title="Identification from spectra - Question 5">Identification from spectra - Question 5</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39357/identification-from-spectra-question-6-1.html" title="Identification from spectra - Question 6">Identification from spectra - Question 6</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39358/identification-from-spectra-question-7-1.html" title="Identification from spectra - Question 7">Identification from spectra - Question 7</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39359/identification-from-spectra-question-8-1.html" title="Identification from spectra - Question 8">Identification from spectra - Question 8</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39360/identification-from-spectra-question-9-1.html" title="Identification from spectra - Question 9">Identification from spectra - Question 9</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39361/identification-from-spectra-question-10-1.html" title="Identification from spectra - Question 10">Identification from spectra - Question 10</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19027/spectroscopic-identification-of-organic-compounds-ahl--1.html" title="Spectroscopic identification of organic compounds (AHL) ">Spectroscopic identification of organic compounds (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24821/mc-test-spectroscopic-identification-of-organic-compounds-ahl-1.html" title="MC test: Spectroscopic identification of organic compounds (AHL)">MC test: Spectroscopic identification of organic compounds (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39375/identification-from-spectra-question-11-1.html" title="Identification from spectra - Question 11">Identification from spectra - Question 11</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39376/identification-from-spectra-question-12-1.html" title="Identification from spectra - Question 12">Identification from spectra - Question 12</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39377/identification-from-spectra-question-13-1.html" title="Identification from spectra - Question 13">Identification from spectra - Question 13</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39378/identification-from-spectra-question-14-1.html" title="Identification from spectra - Question 14">Identification from spectra - Question 14</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39379/identification-from-spectra-question-15-1.html" title="Identification from spectra - Question 15">Identification from spectra - Question 15</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39380/identification-from-spectra-question-16-1.html" title="Identification from spectra - Question 16">Identification from spectra - Question 16</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39381/identification-from-spectra-question-17-1.html" title="Identification from spectra - Question 17">Identification from spectra - Question 17</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39382/identification-from-spectra-question-18-1.html" title="Identification from spectra - Question 18">Identification from spectra - Question 18</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39383/identification-from-spectra-question-19-1.html" title="Identification from spectra - Question 19">Identification from spectra - Question 19</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39385/identification-from-spectra-question-20-1.html" title="Identification from spectra - Question 20">Identification from spectra - Question 20</a></li></ul></ul></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../16441/the-nature-of-science-1.html" title="The Nature of Science">The Nature of Science</a></li><ul class="level-1 "><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16450/key-terms-concepts-1.html" title="Key terms & concepts">Key terms & concepts</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../34566/nos-critical-thinking-1.html" title="NOS & Critical Thinking">NOS & Critical Thinking</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../32100/how-the-elements-were-named-1.html" title="How the elements were named">How the elements were named</a></li><li class="" 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style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16687/sl-questions-by-topic-1.html" title="SL Questions by topic">SL Questions by topic</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16903/1-stoichiometric-relationships-1--1.html" title="1. Stoichiometric relationships (1) ">1. Stoichiometric relationships (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16904/1-stoichiometric-relationships-2--1.html" title="1. Stoichiometric relationships (2) ">1. Stoichiometric relationships (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16710/2-atomic-structure-1.html" title="2. Atomic structure">2. Atomic structure</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16738/3-periodicity-1.html" title="3. Periodicity">3. Periodicity</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16822/4-chemical-bonding-structure-1-1.html" title="4. Chemical bonding & structure (1)">4. 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Acids and bases</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17416/9-redox-processes-1.html" title="9. Redox processes">9. Redox processes</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17411/10-organic-chemistry-1--1.html" title="10. Organic chemistry (1) ">10. Organic chemistry (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17412/10-organic-chemistry-2--1.html" title="10. Organic chemistry (2) ">10. Organic chemistry (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17286/11-measurement-data-processing-1--1.html" title="11. Measurement & data processing (1) ">11. Measurement & data processing (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17287/11-measurement-data-processing-2-1.html" title="11. Measurement & data processing (2)">11. Measurement & data processing (2)</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16688/hl-questions-by-topic-1.html" title="HL Questions by topic">HL Questions by topic</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16709/1-stoichiometric-relationships-1-1.html" title="1. Stoichiometric relationships (1)">1. Stoichiometric relationships (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16735/1-stoichiometric-relationships-2-1.html" title="1. Stoichiometric relationships (2)">1. Stoichiometric relationships (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../37016/2-12-atomic-structure-1-1.html" title="2 &12. Atomic structure (1)">2 &12. Atomic structure (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16721/2-12-atomic-structure-2-1.html" title="2 &12. Atomic structure (2)">2 &12. Atomic structure (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16815/3-13-periodicity-transition-metals-1--1.html" title="3 & 13. Periodicity & transition metals (1) ">3 & 13. Periodicity & transition metals (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16816/3-13-periodicity-transition-metals-2--1.html" title="3 & 13. Periodicity & transition metals (2) ">3 & 13. Periodicity & transition metals (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16861/4-14-chemical-bonding-structure-1-1.html" title="4 & 14. Chemical bonding & structure (1)">4 & 14. Chemical bonding & structure (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16862/4-14-chemical-bonding-structure-2-1.html" title="4 & 14. Chemical bonding & structure (2)">4 & 14. Chemical bonding & structure (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16894/5-15-energetics-thermochemistry-1--1.html" title="5 & 15. Energetics & thermochemistry (1) ">5 & 15. Energetics & thermochemistry (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16893/5-15-energetics-thermochemistry-2--1.html" title="5 & 15. Energetics & thermochemistry (2) ">5 & 15. Energetics & thermochemistry (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17654/6-16-chemical-kinetics-1--1.html" title="6 & 16. Chemical kinetics (1) ">6 & 16. Chemical kinetics (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17655/6-16-chemical-kinetics-2--1.html" title="6 & 16. Chemical kinetics (2) ">6 & 16. Chemical kinetics (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17471/7-17-equilibrium-1--1.html" title="7 & 17. Equilibrium (1) ">7 & 17. Equilibrium (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17472/7-17-equilibrium-2--1.html" title="7 & 17. Equilibrium (2) ">7 & 17. Equilibrium (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17421/8-18-acids-bases-1--1.html" title="8 & 18. Acids & bases (1) ">8 & 18. Acids & bases (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17422/8-18-acids-bases-2--1.html" title="8 & 18. Acids & bases (2) ">8 & 18. Acids & bases (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17417/9-19-redox-processes-1--1.html" title="9 & 19 Redox processes (1) ">9 & 19 Redox processes (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17418/9-19-redox-processes-2--1.html" title="9 & 19. Redox processes (2) ">9 & 19. Redox processes (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17413/10-20-organic-chemistry-1--1.html" title="10 & 20. 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</div><section id="main-content"><div id="toc-1672972910" class="toc"><a href="#" class="toc-switcher" title="Show table of contents"><small><i class="fa fa-reorder"></i> Table of contents <span class="pull-right"><i class="fa fa-chevron-down"></i></span></small></a></div><h1><img class="ico" src="../../../img/icons/standard-1.png"> <img class="ico" src="../../../img/icons/higher-1.png"> 7.1 Equilibrium (4.5 hours)</h1><div class="pinkBg"><div><h2>Pause for thought</h2><p>Once you have explained the concept of dynamic equilibrium (as opposed to static equilibrium) it is worth challenging your students by asking them to suggest how it could be shown experimentally that either chemical or physical equilibrium is dynamic and not static. There are several ways in which it could be done but one of the most obvious is to use a radioactive isotope. Although there is no need to mention examples of specific isotopes in Topic 2.1:<a href="../16914/the-nuclear-atom--1.html" title="New 2014 programme (First exams 2016) » Core & AHL » Teaching each topic & sub-topic » Topics 2 & 12 » The nuclear atom ">The nuclear atom</a> the dangers posed by 131-iodine in nuclear accidents is a good example of utilization and other specific isotopes are mentioned in several of the options.</p><p>Imagine pouring a saturated solution of potassium iodide (made with normal non-radioactive iodide ions) onto some solid potassium iodide containing 131-iodide ions. The mixture is then stirred and left for several hours. If the equilibrium was static then once the solid had been filtered from the solution the solution should not show any radioactivity as none of the iodide ions would have exchanged. However, if the iodide ions in solution are in dynamic equilibrium with the iodide ions in the solid then over time the solution will become increasingly more radioactive as more and more 131-iodide ions are incorporated into the solution.</p><p style="text-align: center;"><br><br><img alt="" height="300" src="../../../ib/chemistry/images/Core%20and%20AHL/Equilibrium/Fukushima%20nuclear%20power%20plant%20explosion.jpg" title="The meltdown in the Fukushima nuclear plant which followed the earthquake and tsunami of 11 March 2011." width="400"></p><hr class="hidden"><p>You could then utilise this explanation to explain why normal iodine is kept as a safeguard at nuclear reactors. This is because if there is an explosion or melt-down one of the radioactive products is 131-iodine. If it escapes, which did happen for real at the Fukushima nuclear reactor in Japan in 2011 (see above), then flooding the body with normal iodine helps to prevent, or at least minimise, 131-iodine being incorporated into humans via the hormone thyroxine.</p><hr class="hidden"><p>Students should be able to write equilibrium expressions and have some idea about what the size of the equilibrium constant tells them about the position of equilibrium. It is therefore reasonable to ask whether equilibrium constants have units. Consider the Contact process.</p><p style="text-align: center;">2SO<sub>2</sub>(g) + O<sub>2</sub>(g) ⇌ 2SO<sub>3</sub>(g)</p><p>Students should be able to deduce that:</p><p style="text-align: center;"><img alt="" class="noborder" height="68" src="../../../ib/chemistry/images/Core%20and%20AHL/Equilibrium/KcSO3.jpg" width="180"></p><p>Since they are told that [ ] means 'concentration' then in terms of units <em>K</em><sub>c</sub> is equal to concentration squared divided by concentration cubed which simplifies to one over concentration, or concentration<sup>-1</sup>. The units of the equilibrium constant, <em>K</em><sub>c</sub>, will therefore be mol<sup>-1</sup> dm<sup>3</sup>. Using similar logic the units for the equilibrium constant for the Haber process will be concentration<sup>-2</sup>, or mol<sup>-2</sup> dm<sup>6</sup>. In fact until 2007 the units of equilibrium constants was a specific assessment statement on the IB Chemistry Diploma programme and questions involving the units were often asked in the exams. The problem is that equilibrium constants do not in fact have units! The reasons is that the square brackets, [ ], actually mean activity rather than concentration and activity has no units. For this reason the values given for all equilibrium constants in examinations (and for <em>K</em><sub>w</sub> in the IB Data booklet) on the current syllabus do not have units.<sup data-footnote-id="k610o"><a class="scroll-to" data-target="footnote-1" id="footnote-marker-1-1" rel="footnote">[1]</a></sup></p><p>This can cause difficulties when comparing values of <em>K</em><sub>c</sub> for different reactions but not really at IB level. For example, the solubility product, <em>K</em><sub>sp</sub>, for silver chloride, AgCl, is 1.8 x 10<sup>-10</sup> whereas the solubility product for silver chromate, Ag<sub>2</sub>CrO<sub>4</sub>, is 1.3 x 10<sup>-12</sup>. Although both are very 'insoluble' it would appear that silver chloride is more soluble as it has a higher <em>K</em><sub>sp</sub> value. However the concentration of silver ions in solution will be greater for silver chromate as the expression is [Ag<sup>+</sup>(aq)]<sup>2</sup>[CrO<sub>4</sub><sup>2</sup><sup>-</sup>(aq)], i.e. concentration cubed, compared to the concentration squared expression, [Ag<sup>+</sup>(aq)][Cl<sup>-</sup>(aq)] for silver chloride.</p><hr class="hidden"></div></div><hr class="hidden"><div class="box"><h2>Nature of science</h2><p>The use of isotopic labelling to define equilibrium provides good evidence for a scientific theory. The term dynamic equilibrium is used in other contexts so is an example of the use of a common language across different disciplines although the chemistry definition may not always be born in mind.</p><hr class="hidden"></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><div class="yellowBg"><div><h2><strong><strong>Learning outcomes</strong></strong></h2><p>After studying this topic students should be able to:</p><p><strong><strong>Understand</strong></strong></p><ul><li>In a closed system, equilibrium is reached when the rate of the forward reaction is equal to the rate of the reverse reaction.</li><li>The equilibrium law describes how the equilibrium constant, <em>K</em><sub>c</sub> relates to the concentrations of the products and the reactants from which its value can be determined for a particular chemical reaction. The extent of a reaction at equilibrium is indicated by the magnitude of the equilibrium constant whose value is also dependent upon temperature.</li><li>The position of the equilibrium changes with changes in concentration, pressure, and temperature.</li><li>The relative amount of products and reactants present during a reaction at a particular point in time are given by the reaction quotient, <em>Q</em>. <em>Q </em>is the equilibrium expression using non-equilibrium concentrations.</li><li>Adding a catalyst has no effect on the position of equilibrium or the equilibrium constant.</li></ul><p><strong>Apply their knowledge to:</strong></p><ul><li>Characterise chemical and physical systems in a state of equilibrium.</li><li>Deduce the equilibrium constant expression, <em>K</em><sub>c</sub>, from an equation for a homogeneous reaction.</li><li>Determine the relationship between different equilibrium constants for the same reaction at the same temperature.</li><li>Apply Le Chatelier’s principle to predict the qualitative effects of changes of temperature, pressure and concentration on the position of equilibrium and on the value of the equilibrium constant.</li></ul></div></div></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal;"></span></b></h4><div class="yellowBg"><div><h4><b><span style="font-weight: normal;"><strong>Clarification notes</strong></span></b></h4><p>Both physical and chemical systems should be covered.<br>The relationship between <em>K</em><sub>c</sub> values for reactions that are multiples or inverses of one another should be covered.<br>No specific details of any industrial process are required.</p><hr class="hidden"><h4>International-mindedness</h4>The Haber process has huge global significance as it has revolutionized world food production due to artificial fertilizers. However, because the oxidation of ammonia forms nitric acid, the precursor for many explosives, it has also had a large impact on weaponry in many world conflicts.</div></div></td></tr></tbody></table></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h2><span style=""><b><span style="font-weight: normal;"><strong>Teaching tips</strong></span></b></span></h2><p>To illustrate static equilibrium I often balance a ruler on a pencil. Once equilibrium has been reached there is no more movement until a force is added to one of the sides. In fact, although demonstrating dynamic equilibrium is more spectacular, it is still not obvious that the reactions are still continuing once the position of equilibrium has been reached.</p><p>You will need to explain the concept of closed and open systems and the fact that at equilibrium the concentrations of reactants and products are constant because the rate of the forward reaction is equal to the rate of the reverse reaction.<br><br>Suitable experiments for demonstrating dynamic equilibrium are the <a href="http://youtu.be/LgJGTH5Xp0o">formation of iron(III) thiocyanate</a>, [FeSCN]<sup>2+</sup>, a <a href="http://youtu.be/YMqyG9QG6oc">gas syringe full of nitrogen (IV) oxide</a> or by adding <a href="chemistry/practicals-for-hl-only/determining-a-kc-value.htm">ammonia and/or hydrochloric acid to aqueous copper(II) ions</a>. Better still is to get your students to do the experiments themselves - the iron(III) thiocyanate formation is the easiest and safest.<br><br>You should also discuss dynamic physical equilibrium. Some teachers use the analogy of pouring water into a tub with a hole in the bottom. Equilibrium will be reached when the rate of water entering the tub is the same as the rate of water leaving through the hole. It is also worth asking students to explain what constitutes a good 'drying day' for washed clothes and why wet clothes do not dry in a closed space.</p><p>I tend to put much more emphasis on getting students to be able to write correct equilibrium expressions than on quoting Le Chatelier's principle. The principle is useful for predicting what will happen when a change is made to an equilibrium system but the equilibrium expression can be used to actually explain it.</p><p>For example, in the expression for the Contact process above adding more SO<sub>2</sub>(g) looks as if it will lower the value of <em>K</em><sub>c</sub>, but <em>K</em><sub>c</sub> is a constant so to keep it constant the concentration of SO<sub>3</sub>(g) must increase.</p><p>For temperature heat can be thought of as a reactant for endothermic reactions, so putting in more heat will move the position of equilibrium to the product side. Similarly, for exothermic reactions think of heat as a product so taking heat away (i.e. lowering the temperature) will cause more product to form.</p><p><em>K</em><sub>c</sub> is of course only a constant at a stated temperature. By applying the equilibrium law it is easy to see that <em>K</em><sub>c</sub> must increase at higher temperatures for endothermic reactions and decrease at higher temperatures for exothermic reactions.</p><p>It is also easy for students to deduce how the reaction quotient, Q, will change as the system proceeds towards equilibrium provided they know the initial concentrations of all the reactants (and products, if any). You will also need to give students practice at manipulating equilibrium constants if the reactions are written differently.</p><p>Catalysts work by providing an alternative pathway with a lower activation energy. They affect the rate of forward and reverse reactions equally so do not affect the position of equilibrium. However equilibrium will be reached quicker so they tend to be used in industry for exothermic processes where higher temperatures result in a lower yield.</p><hr class="hidden"></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal; "><strong>Study guide</strong></span></b></h4><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><img alt="" src="../../../ib/chemistry/images/2014%20Basic%20information/New%20cover.jpg" style="width: 67px; height: 96px;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><b><span style="font-weight: normal;">Pages 54 & 55 </span></b></p><hr class="hidden"><h2>Questions</h2><p>For ten 'quiz' multiple choice questions with the answers explained see <a href="../24656/mc-test-equilibrium-1.html" title="Core & AHL » Teaching each topic & sub-topic » Topics 7 & 17 » Equilibrium » MC test: Equilibrium">MC test: Equilibrium</a>.</p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;">For short-answer questions which can be set as an assignment for a test, homework or given for self study together with model answers see <a href="../40959/equilibrium-questions-1.html" title="Core & AHL » Teaching each topic & sub-topic » Topics 7 & 17 » Equilibrium » Equilibrium questions">Equilibrium questions</a>.<a href="chemistry/page/24164/empirical-molecular-formula-answers-" title="Core & AHL » Teaching each topic & sub-topic » Topic 1 » The mole & Avogadro's constant » Empirical & molecular formula answers "> </a></p><hr class="hidden"><h4><span style=""><b><span style="font-weight: normal;"><strong>Vocabulary list</strong></span></b></span></h4><p>Dynamic<br>Static<br>Steady state<br>Closed system<br>Macroscopic properties<br><span style=""><span style="font-weight: normal;">Ho</span></span>mogeneous equilibria<br>Heterogeneous equilibria<br>Le Chatelier's principle<br>Equilibrium law<br>Equilibrium constant,<em> </em><em>K</em><sub>c</sub><br>Reaction quotient, <em>Q</em></p><hr class="hidden"><h4><strong><strong>IM, TOK, Utilization etc.</strong></strong></h4><p>See <a href="../18041/topics-7-17--1.html" title="New 2014 programme (First exams 2016) » Core & AHL » Incorporating IM, TOK, 'Utilization' etc. » Topics 7 & 17 ">separate page</a> which covers all of Topic 7</p><hr class="hidden"><h2><span style=""><b><span style="font-weight: normal;"><strong>Practical work</strong></span></b></span></h2><p><a href="../18083/le-chateliers-principle--1.html"><span style=""><b><span style="font-weight: normal;"><strong><img class="ico" src="../../../img/icons/lab-1.png"> </strong></span></b><span style="font-weight: normal;">Le Chatelier's principle</span></span></a></p></td></tr></tbody></table></div><hr class="hidden"><div class="greenBg"><h2 id="header-12">Teaching slides</h2><p>Teachers may wish to share these slides with students for learning or for reviewing key concepts.</p><div id="myCarousel-13" class="carousel slide" data-id="273"><!-- Carousel items --><div class="carousel-inner"><div class="active item"><a class="fancy" href="../../../tib-galleries/3-273/711.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/711.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/712.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/712.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/713.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/713.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/714.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/714.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/715.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/715.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/716.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/716.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/717.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/717.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/718.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/718.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/719.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/719.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/7110.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/7110.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/7111.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/7111.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/7112.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/7112.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-273/7113.png" rel="gallery-273" title=""><img alt="" src="files/tib-galleries/3-273/7113.png"></a><div class="carousel-caption"><p>Equilibrium: </p></div></div></div><!-- Carousel nav --><a class="carousel-control left" href="#myCarousel-13" data-slide="prev">‹</a><a class="carousel-control right" href="#myCarousel-13" data-slide="next">›</a><div class="tib-indicators"><img class="" title="Click to view" style="margin: 10px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/711-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/712-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/713-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/714-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/715-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/716-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/717-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/718-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/719-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/7110-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/7111-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/7112-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-273/7113-thumb128.jpg"></div></div><p> </p></div><hr class="hidden"><div class="blueBg"><h2><span style="font-weight: bold;">Other resources</span></h2><p><strong>1.</strong> A video produced by the University of Surrey for revision purposes. It has quite a good illustration of the liquid water - water vapour equilibrium in open and closed systems.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/JsoawKguU6A?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/JsoawKguU6A">Dynamic equilibrium (1) <img class="ico" src="http://www.thinkib.net/img/icons/video.png"></a></p><hr class="hidden"><p><strong>2. </strong>A good video to illustrate Le Chatelier's principle. It shows how colourless SCN<sup>-</sup>(aq) ions and a very pale yellow solution of Fe<sup>3</sup><sup>+</sup>(aq) ions react to form the red complex [Fe(H<sub>2</sub>O)<sub>5</sub>SCN]<sup>2+</sup> ion using petri dishes and the effect of changing concentrations on the position of equilibrium.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/LgJGTH5Xp0o?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/LgJGTH5Xp0o">Le Chatelier's principle (1) <img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-1" name="video-1"> </span></a></p><hr class="hidden"><p><strong>3. </strong>A University of Surrey video which applies Le Chatelier's principle to the Haber process.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/dIDgPFEucFM?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/dIDgPFEucFM">Le Chatelier's principle (2) <img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-2" name="video-2"> </span></a></p><hr class="hidden"><p><strong>4.</strong> A good example of both concentration effect and le Chatelier's principle using a gas syringe filled with a mixture of NO<sub>2</sub>(g) and N<sub>2</sub>O<sub>4</sub>(g).</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/YMqyG9QG6oc?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/YMqyG9QG6oc">Le Chatelier's principle (3) <img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-3" name="video-3"> </span></a></p><p style="text-align: center;"></p><hr class="hidden"><p><strong>5. </strong>A really good and informative article on the <a href="http://www.theguardian.com/science/2013/nov/03/fritz-haber-fertiliser-ammonia-centenary">Fritz Haber story</a> which you could give your students to read. Also see the information given in 'Incorporating IM, TOK, 'Utilization etc. for <a href="../18041/topics-7-17--1.html" title="New 2014 programme (First exams 2016) » Core & AHL » Incorporating IM, TOK, 'Utilization' etc. » Topics 7 & 17 ">Topics 7 & 17.</a></p><hr class="hidden"><section class="footnotes"><header><h2>Footnotes</h2></header><ol><li data-footnote-id="k610o" id="footnote-1"><a class="scroll-to" data-target="footnote-marker-1-1">^</a> <cite>Actually in the current version of the IB data booklet (4th. edition dated JIB Docs (2) Teamary 2017) in Section 2 the ionic product for water, Kw is given units whereas the solubility product constants, Ksp given in Section 32 do not have units! </cite></li></ol></section></div></section></article><section id="media-extras"><div class="page-actions no-print navbar inline hidden-desktop"><div class="navbar-inner"><ul class="nav"><li><a class="presentation" href="#" onclick="return false;"><i class="fa fa-desktop"></i></a></li><li><a class="print-section-blog" href="#" onclick="return false;"><i class="fa fa-print"></i></a></li><li><a class="page-bookmarker" data-ticket="IB Docs (2) Team" data-pid="18040" href="#" onclick="return false;"><i class="fa fa-star"></i></a></li><li><a class="personal-notes" href="#" onclick="return false;"><i class="fa fa-file-text"></i></a></li><li><a class="" data-toggle="modal" href="#modal-feedback" onclick="return false;"><i class="fa fa-envelope-o"></i></a></li><li class="dropdown"><a class="dropdown-toggle" data-toggle="dropdown" data-target="#" href="#"><i class="fa fa-share-alt"></i></a><ul class="dropdown-menu" role="menu"><li><a class="" target="_blank" title="Share on Twitter" href="https://twitter.com/share?text=%22Equilibrium+%22+-+via+%40InThinker+%23chemistry%0A&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18040%2Fequilibrium-"><i class="fa fa-twitter-square"></i><span>Twitter</span></a></li><li><a class="" target="_blank" title="Share on Facebook" href="https://www.facebook.com/sharer.php?u=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18040%2Fequilibrium-&t=Equilibrium+"><i class="fa fa-facebook-square"></i><span>Facebook</span></a></li><li><a class="" href="http://www.linkedin.com/shareArticle?mini=true&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18040%2Fequilibrium-"><i class="fa fa-linkedin-square"></i><span>LinkedIn</span></a></li><li><a class="" href="https://plus.google.com/share?url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18040%2Fequilibrium-"><i class="fa fa-google-plus-square"></i><span>Google +</span></a></li><li><a class="" href="mailto:?subject=Equilibrium &body=Once you have explained the concept of dynamic equilibrium (as opposed to static equilibrium) it is worth challenging your students by asking them to suggest how it could be shown experimentally that either chemical or physical...%0Ahttps%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18040%2Fequilibrium-"><i class="fa fa-envelope"></i><span>Email</span></a></li></ul></li><li><a class="" href="chemistry/teaching-materials"><i class="fa fa-puzzle-piece colored"></i></a></li></ul></div></div><div style="border-top: solid 1px #eee;border-bottom: solid 1px #eee;padding: 4px 0 4px 0;line-height: 1em;color: #666;font-size: .8em"><small><em>All materials on this website are for the exclusive use of teachers and students at subscribing schools for the period of their subscription. 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