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<title>DP Chemistry: Intermolecular forces</title>
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href="../19290/introduction-to-biochemistry--1.html">Introduction to biochemistry </a></li><li><a href="../19287/proteins-enzymes--1.html">Proteins & enzymes </a></li><li><a href="../19291/lipids-1.html">Lipids</a></li><li><a href="../19299/carbohydrates--1.html">Carbohydrates </a></li><li><a href="../19305/vitamins--1.html">Vitamins </a></li><li><a href="../19313/biochemistry-the-environment--1.html">Biochemistry & the environment </a></li><li><a href="../19336/proteins-enzymes-ahl--1.html">Proteins & enzymes (AHL) </a></li><li><a href="../19347/nucleic-acids--1.html">Nucleic acids </a></li><li><a href="../19361/biological-pigments--1.html">Biological pigments </a></li><li><a href="../19366/stereochemistry-in-biomolecules-1.html">Stereochemistry in biomolecules</a></li></ul></li><li><a href="../19390/option-c--1.html" class="father">Option C </a><ul class="level-2"><li><a href="../19391/energy-sources-1.html">Energy sources</a></li><li><a href="../19407/fossil-fuels-1.html">Fossil fuels</a></li><li><a href="../19411/nuclear-fusion-nuclear-fission-reactions-1.html">Nuclear fusion & nuclear fission reactions</a></li><li><a href="../19429/solar-energy-1.html">Solar energy</a></li><li><a href="../19437/environmental-impact-global-warming-1.html">Environmental impact - global warming</a></li><li><a href="../19453/electrochemistry-rechargeable-batteries-fuel-cells-1.html">Electrochemistry, rechargeable batteries & fuel cells</a></li><li><a href="../19458/nuclear-fusion-fission-hl--1.html">Nuclear fusion & fission (HL) </a></li><li><a href="../19470/photovoltaic-cells-and-dsscs-1.html">Photovoltaic cells and DSSCs</a></li></ul></li><li><a href="../19078/option-d-1.html" class="father">Option D</a><ul class="level-2"><li><a href="../19079/pharmaceutical-products-drug-action--1.html">Pharmaceutical products & drug action </a></li><li><a href="../19158/aspirin-penicillin--1.html">Aspirin & penicillin </a></li><li><a href="../19174/opiates-1.html">Opiates</a></li><li><a href="../19184/ph-regulation-of-the-stomach-1.html">pH regulation of the stomach</a></li><li><a href="../19194/antiviral-medications--1.html">Antiviral medications </a></li><li><a href="../19211/environmental-impact-of-some-medications-1.html">Environmental impact of some medications</a></li><li><a href="../19254/taxol-a-chiral-auxiliary-case-study-1.html">Taxol - a chiral auxiliary case study</a></li><li><a href="../19258/nuclear-medicine--1.html">Nuclear medicine </a></li><li><a href="../19273/drug-detection-analysis--1.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../16592/practical-scheme-of-work-ia--1.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../16682/internal-assessment-1.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../18892/scaffolding-the-investigation-1.html">'Scaffolding' the investigation</a></li><li><a href="../18896/timing-organisation--1.html">Timing & organisation </a></li><li><a href="../18905/choosing-the-research-question-1.html">Choosing the research question</a></li><li><a href="../18946/personal-engagement-1.html">Personal engagement</a></li><li><a href="../18950/exploration-1.html">Exploration</a></li><li><a href="../18957/analysis-1.html">Analysis</a></li><li><a href="../18965/evaluation-1.html">Evaluation</a></li><li><a href="../18966/communication-1.html">Communication</a></li><li><a href="../19882/internal-standardization-of-the-ia-1.html">Internal standardization of the IA</a></li><li><a href="../19901/submitting-the-samples-for-moderation-2.html">Submitting the samples for moderation</a></li><li><a href="../33754/ten-suggestions-for-ias-using-secondary-data-1.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../37544/gaining-full-marks-for-a-databased-ia--1.html">Gaining full marks for a databased IA </a></li><li><a href="../19506/ia-example-marking-exercise--1.html">IA example & marking exercise </a></li><li><a href="../23929/genuine-examples-of-moderated-ia-reports-1.html">Genuine examples of moderated IA reports</a></li><li><a href="../25234/examples-of-teacher-marked-ia-reports--1.html">Examples of teacher-marked IA reports </a></li><li><a href="../37542/history-of-internal-assessment-1.html">History of Internal Assessment</a></li></ul></li><li><a href="../16598/mandatory-laboratory-components-1.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../16613/formula-of-magnesium-oxide--1.html">Formula of magnesium oxide </a></li><li><a href="../16612/determining-the-mr-of-an-unknown-gas-1.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../16615/acid-base-titrations--1.html">Acid-base titrations </a></li><li><a href="../16616/a-green-acid-base-practical-1.html">A green acid-base practical</a></li><li><a href="../16617/analysis-of-aspirin-tablets-1.html">Analysis of aspirin tablets</a></li><li><a href="../16618/caco3-in-egg-shells-1.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../16644/enthalpy-changes-1.html">Enthalpy changes</a></li><li><a href="../16631/reaction-rates-1.html">Reaction rates</a></li><li><a href="../16635/rate-dependent-factors-1.html">Rate-dependent factors</a></li><li><a href="../16636/determining-ea-for-a-reaction-1.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../16637/iodination-of-propanone-1.html">Iodination of propanone</a></li><li><a href="../18144/titrations-with-a-ph-meter-1.html">Titrations with a pH meter</a></li><li><a href="../18355/redox-titration-with-kmno4--1.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../16640/voltaic-cells-1.html">Voltaic cells</a></li><li><a href="../16659/3-d-molecular-modelling--1.html">3-D molecular modelling </a></li></ul></li><li><a href="../17168/other-good-practicals-1.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../17196/common-chemical-reactions-1.html">Common chemical reactions</a></li><li><a href="../227/elements-oxides-of-the-third-period--1.html">Elements & oxides of the third period </a></li><li><a href="../17239/the-halogens-1.html">The halogens</a></li><li><a href="../17162/boiling-points-of-mixtures-1.html">Boiling points of mixtures</a></li><li><a href="../17170/polarity-of-molecules-1.html">Polarity of molecules</a></li><li><a href="../18083/le-chateliers-principle--1.html">Le Chatelier's principle </a></li><li><a href="../19582/determining-kc-for-an-esterification-reaction-1.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../18164/redox-reactions-of-vanadium--1.html">Redox reactions of vanadium </a></li><li><a href="../18351/chlorine-in-swimming-pools--1.html">Chlorine in swimming pools </a></li><li><a href="../18178/analysis-of-cuii-ions-in-solution--1.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../18179/percentage-of-copper-in-brass-1.html">Percentage of copper in brass</a></li><li><a href="../18356/electrolytic-cells--1.html">Electrolytic cells </a></li><li><a href="../18598/reactions-of-organic-compounds-1.html">Reactions of organic compounds</a></li><li><a href="../18752/hydrolysis-of-halogenoalkanes-1.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../18784/preparation-of-13-dinitrobenzene--1.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../19022/determination-of-an-organic-structure-1.html">Determination of an organic structure</a></li><li><a href="../19887/preparation-of-nylon-66-1.html">Preparation of nylon 6,6</a></li><li><a href="../19343/determination-of-vitamin-c-content--1.html">Determination of vitamin C content </a></li><li><a href="../19342/hydrolysis-of-starch--1.html">Hydrolysis of starch </a></li><li><a href="../19159/preparation-purification-of-aspirin--1.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../18851/ict-in-practical-work-1.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../18852/data-logging--1.html">Data logging </a></li><li><a href="../18853/software-for-graph-plotting--1.html">Software for graph plotting </a></li><li><a href="../18854/spreadsheets-for-data-processing--1.html">Spreadsheets for data processing </a></li><li><a href="../18855/databases-1.html">Databases</a></li><li><a href="../18856/computer-modelling-simulations--1.html">Computer modelling & simulations </a></li></ul></li><li><a href="../16594/group-4-project-1.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../16595/practicalities-1.html">Practicalities</a></li><li><a href="../16596/reflective-statement--2.html">Reflective statement </a></li></ul></li><li><a href="../16666/a-new-laboratory-1.html">A new laboratory?</a></li></ul></li><li><a href="../16284/exams-1.html">Exams</a><ul class="level-1"><li><a href="../16286/essential-facts-1.html" class="father">Essential Facts</a><ul class="level-2"><li><a href="../16287/objectives-command-terms-1.html">Objectives & command terms</a></li><li><a href="../16288/grade-descriptors-1.html">Grade descriptors</a></li><li><a href="../16289/grade-boundaries-1.html">Grade boundaries</a></li></ul></li><li><a href="../16302/paper-1-multiple-choice-1.html" class="father">Paper 1 (Multiple Choice)</a><ul class="level-2"><li><a href="../16303/advice-to-students-paper-1-1.html">Advice to students (Paper 1)</a></li><li><a href="../31515/practice-paper-1-exams-1.html">Practice Paper 1 exams</a></li></ul></li><li><a href="../16305/paper-2-1.html" class="father">Paper 2</a><ul class="level-2"><li><a href="../16306/advice-to-students-paper-2-1.html">Advice to students (Paper 2)</a></li><li><a href="../16307/areas-of-difficulty-1.html">Areas of difficulty</a></li></ul></li><li><a href="../16313/paper-3--1.html" class="father">Paper 3 </a><ul class="level-2"><li><a 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options</a></li><li><a href="../24897/sl-quizzes-on-option-sub-topics--1.html">SL Quizzes on option sub-topics </a></li><li><a href="../17785/hl-multiple-choice-tests-on-individual-topics-1.html">HL Multiple choice tests on individual topics</a></li><li><a href="../24352/hl-multiple-choice-quizzes-on-sub-topics-1.html">HL Multiple choice 'quizzes' on sub-topics</a></li><li><a href="../31520/hl-practice-paper-1-exams--1.html">HL Practice Paper 1 exams </a></li><li><a href="../17787/hl-questions-on-each-sub-topic--1.html">HL Questions on each sub-topic </a></li><li><a href="../20428/hl-paper-3-section-a-questions-1.html">HL Paper 3 Section A questions</a></li><li><a href="../17793/hl-questions-on-the-options-1.html">HL Questions on the options</a></li><li><a href="../24973/hl-quizzes-on-option-sub-topics-1.html">HL Quizzes on option sub-topics</a></li><li><a href="../41573/printable-versions-of-written-tasks--1.html">Printable versions of written tasks </a></li></ul></li><li><a 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class="expander fa fa-caret-right "></i><a href="../24660/mc-test-the-equilibrium-law-1.html" title="MC test: The equilibrium law">MC test: The equilibrium law</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40961/equilibrium-law-questions-1.html" title="Equilibrium law questions">Equilibrium law questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18120/topics-8-18--1.html" title="Topics 8 & 18 ">Topics 8 & 18 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18124/theories-of-acids-bases--1.html" title="Theories of acids & bases ">Theories of acids & bases </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24662/mc-test-theories-of-acids-bases-1.html" title="MC test: Theories of acids & bases">MC test: Theories of acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40963/theories-of-acids-bases-questions-1.html" title="Theories of acids & bases questions">Theories of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18126/properties-of-acids-bases-1.html" title="Properties of acids & bases">Properties of acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24663/mc-test-properties-of-acids-bases--1.html" title="MC test: Properties of acids & bases ">MC test: Properties of acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40964/properties-of-acids-bases-questions-1.html" title="Properties of acids & bases questions">Properties of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18140/ph-scale-1.html" title="pH scale">pH scale</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24668/mc-test-the-ph-scale-1.html" title="MC test: The pH scale">MC test: The pH scale</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40971/ph-scale-questions-1.html" title="pH scale questions">pH scale questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18152/strong-weak-acids-bases-1.html" title="Strong & weak acids & bases">Strong & weak acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24670/mc-test-strong-weak-acids-bases-1.html" title="MC test: Strong & weak acids & bases">MC test: Strong & weak acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40972/strong-weak-acid-bases-questions-1.html" title="Strong & weak acid & bases questions">Strong & weak acid & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18156/acid-deposition-1.html" title="Acid deposition">Acid deposition</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24674/mc-test-acid-deposition-1.html" title="MC test: Acid deposition">MC test: Acid deposition</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40983/acid-deposition-questions-1.html" title="Acid deposition questions">Acid deposition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18160/lewis-acids-bases-1.html" title="Lewis acids & bases">Lewis acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24710/mc-test-lewis-acids-bases-1.html" title="MC test: Lewis acids & bases">MC test: Lewis acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40986/lewis-acids-bases-questions-1.html" title="Lewis acids & bases questions">Lewis acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18250/acid-base-calculations-1.html" title="Acid base calculations">Acid base calculations</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24714/mc-test-calculations-involving-acids-bases--1.html" title="MC test: Calculations involving acids & bases ">MC test: Calculations involving acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40988/acid-base-calculations-questions--1.html" title="Acid-base calculations questions ">Acid-base calculations questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../26161/ph-titration-curves-1.html" title="pH titration curves">pH titration curves</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../26158/mc-test-ph-curves-1.html" title="MC test: pH curves">MC test: pH curves</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41000/ph-curves-questions--1.html" title="pH curves questions ">pH curves questions </a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18350/topics-9-19-1.html" title="Topics 9 & 19">Topics 9 & 19</a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18365/oxidation-reduction-1.html" title="Oxidation & reduction">Oxidation & reduction</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24725/mc-test-oxidation-reduction-1.html" title="MC test: Oxidation & reduction">MC test: Oxidation & reduction</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41033/oxidation-reduction-questions-1--1.html" title="Oxidation & reduction questions (1) ">Oxidation & reduction questions (1) </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41034/oxidation-reduction-questions-2-1.html" title="Oxidation & reduction questions (2)">Oxidation & reduction questions (2)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41035/oxidation-reduction-questions-3-1.html" title="Oxidation & reduction questions (3)">Oxidation & reduction questions (3)</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18383/electrochemical-cells-1.html" title="Electrochemical cells">Electrochemical cells</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24740/mc-test-electrochemical-cells-1.html" title="MC test: Electrochemical cells">MC test: Electrochemical cells</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41072/electrochemical-cells-questions--1.html" title="Electrochemical cells questions ">Electrochemical cells questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18401/electrochemical-cells-ahl--1.html" title="Electrochemical cells (AHL) ">Electrochemical cells (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24742/mc-test-electrochemical-cells-ahl-1.html" title="MC test: Electrochemical cells (AHL)">MC test: Electrochemical cells (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41098/electrochemical-cells-1-ahl-questions-1.html" title="Electrochemical cells (1) (AHL) questions">Electrochemical cells (1) (AHL) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41099/electrochemical-cells-2-ahl-questions-1.html" title="Electrochemical cells (2) (AHL) questions">Electrochemical cells (2) (AHL) questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18475/topics-10-20--1.html" title="Topics 10 & 20 ">Topics 10 & 20 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18497/fundamentals-of-organic-chemistry--1.html" title="Fundamentals of organic chemistry ">Fundamentals of organic chemistry </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24749/mc-test-fundamentals-of-organic-chemistry-1.html" title="MC test: Fundamentals of organic chemistry">MC test: Fundamentals of organic chemistry</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41111/fundamentals-of-organic-chemistry-1-questions-1.html" title="Fundamentals of organic chemistry (1) questions">Fundamentals of organic chemistry (1) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41112/fundamentals-of-organic-chemistry-2-questions-1.html" title="Fundamentals of organic chemistry (2) questions">Fundamentals of organic chemistry (2) questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18597/alkanes-alkenes-addition-polymers-1.html" title="Alkanes, alkenes & addition polymers">Alkanes, alkenes & addition polymers</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24750/mc-test-alkanes-alkenes-addition-polymers-1.html" title="MC test: Alkanes, alkenes & addition polymers">MC test: Alkanes, alkenes & addition polymers</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41121/alkanes-questions-1.html" title="Alkanes questions">Alkanes questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41124/alkenes-questions-1.html" title="Alkenes questions">Alkenes questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18741/alcohols--1.html" title="Alcohols ">Alcohols </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24772/mc-test-alcohols-1.html" title="MC test: Alcohols">MC test: Alcohols</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41125/alcohols-questions-1.html" title="Alcohols questions">Alcohols questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18742/halogenoalkanes-benzene--1.html" title="Halogenoalkanes & benzene ">Halogenoalkanes & benzene </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24797/mc-test-halogenoalkanes-benzene-1.html" title="MC test: Halogenoalkanes & benzene">MC test: Halogenoalkanes & benzene</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41130/halogenoalkanes-benzene-questions-1.html" title="Halogenoalkanes & benzene questions">Halogenoalkanes & benzene questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18762/nucleophilic-substitution--1.html" title="Nucleophilic substitution ">Nucleophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24757/mc-test-nucleophilic-substitution-1.html" title="MC test: Nucleophilic substitution">MC test: Nucleophilic substitution</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41138/nucleophilic-substitution-questions-1.html" title="Nucleophilic substitution questions">Nucleophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18766/electrophilic-addition--1.html" title="Electrophilic addition ">Electrophilic addition </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24805/mc-test-electrophilic-addition-electrophilic-substitution-reacti-2.html" title="MC test: Electrophilic addition & electrophilic substitution reactions">MC test: Electrophilic addition & electrophilic substitution reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41148/electrophilic-addition-questions-1.html" title="Electrophilic addition questions">Electrophilic addition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18780/electrophilic-substitution--2.html" title="Electrophilic substitution ">Electrophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41149/electrophilic-substitution-questions-1.html" title="Electrophilic substitution questions">Electrophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18793/reduction-reactions--1.html" title="Reduction reactions ">Reduction reactions </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24811/mc-test-reduction-reactions-1.html" title="MC test: Reduction reactions">MC test: Reduction reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41150/reduction-reactions-questions-1.html" title="Reduction reactions questions">Reduction reactions questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18797/synthetic-routes--1.html" title="Synthetic routes ">Synthetic routes </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24822/mc-test-synthetic-routes-1.html" title="MC test: Synthetic routes">MC test: Synthetic routes</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41152/synthetic-routes-questions--1.html" title="Synthetic routes questions ">Synthetic routes questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18844/stereoisomerism--1.html" title="Stereoisomerism ">Stereoisomerism </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24817/mc-test-stereoisomerism-1.html" title="MC test: Stereoisomerism">MC test: Stereoisomerism</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41166/stereoisomerism-questions-1.html" title="Stereoisomerism questions">Stereoisomerism questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17285/topics-11-21--1.html" title="Topics 11 & 21 ">Topics 11 & 21 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17276/uncertainty-errors--1.html" title="Uncertainty & errors ">Uncertainty & errors </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24818/mc-test-uncertainties-errors-1.html" title="MC test: Uncertainties & errors">MC test: Uncertainties & errors</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../38869/uncertainty-error-questions--1.html" title="Uncertainty & error questions ">Uncertainty & error questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../15014/graphical-techniques-1.html" title="Graphical techniques">Graphical techniques</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24819/mc-test-graphical-techniques-1.html" title="MC test: Graphical techniques">MC test: Graphical techniques</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39387/graphical-techniques-questions--1.html" title="Graphical techniques questions ">Graphical techniques questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18968/spectroscopic-identification-of-organic-compounds-1.html" title="Spectroscopic identification of organic compounds">Spectroscopic identification of organic compounds</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24820/mc-test-spectroscopic-identification-of-organic-compounds--1.html" title="MC test: Spectroscopic identification of organic compounds ">MC test: Spectroscopic identification of organic compounds </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39388/index-of-hydrogen-deficiency-questions-1.html" title="Index of hydrogen deficiency questions">Index of hydrogen deficiency questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39351/identification-from-spectra-question-1-1.html" title="Identification from spectra - Question 1">Identification from spectra - Question 1</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39353/identification-from-spectra-question-2-1.html" title="Identification from spectra - Question 2">Identification from spectra - Question 2</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39354/identification-from-spectra-question-3-1.html" title="Identification from spectra - Question 3">Identification from spectra - Question 3</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39355/identification-from-spectra-question-4-1.html" title="Identification from spectra - Question 4">Identification from spectra - Question 4</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39356/identification-from-spectra-question-5-1.html" title="Identification from spectra - Question 5">Identification from spectra - Question 5</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39357/identification-from-spectra-question-6-1.html" title="Identification from spectra - Question 6">Identification from spectra - Question 6</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39358/identification-from-spectra-question-7-1.html" title="Identification from spectra - Question 7">Identification from spectra - Question 7</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39359/identification-from-spectra-question-8-1.html" title="Identification from spectra - Question 8">Identification from spectra - Question 8</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39360/identification-from-spectra-question-9-1.html" title="Identification from spectra - Question 9">Identification from spectra - Question 9</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39361/identification-from-spectra-question-10-1.html" title="Identification from spectra - Question 10">Identification from spectra - Question 10</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19027/spectroscopic-identification-of-organic-compounds-ahl--1.html" title="Spectroscopic identification of organic compounds (AHL) ">Spectroscopic identification of organic compounds (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24821/mc-test-spectroscopic-identification-of-organic-compounds-ahl-1.html" title="MC test: Spectroscopic identification of organic compounds (AHL)">MC test: Spectroscopic identification of organic compounds (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39375/identification-from-spectra-question-11-1.html" title="Identification from spectra - Question 11">Identification from spectra - Question 11</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39376/identification-from-spectra-question-12-1.html" title="Identification from spectra - Question 12">Identification from spectra - Question 12</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39377/identification-from-spectra-question-13-1.html" title="Identification from spectra - Question 13">Identification from spectra - Question 13</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39378/identification-from-spectra-question-14-1.html" title="Identification from spectra - Question 14">Identification from spectra - Question 14</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39379/identification-from-spectra-question-15-1.html" title="Identification from spectra - Question 15">Identification from spectra - Question 15</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39380/identification-from-spectra-question-16-1.html" title="Identification from spectra - Question 16">Identification from spectra - Question 16</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39381/identification-from-spectra-question-17-1.html" title="Identification from spectra - Question 17">Identification from spectra - Question 17</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39382/identification-from-spectra-question-18-1.html" title="Identification from spectra - Question 18">Identification from spectra - Question 18</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39383/identification-from-spectra-question-19-1.html" title="Identification from spectra - Question 19">Identification from spectra - Question 19</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39385/identification-from-spectra-question-20-1.html" title="Identification from spectra - Question 20">Identification from spectra - Question 20</a></li></ul></ul></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../16441/the-nature-of-science-1.html" title="The Nature of Science">The Nature of Science</a></li><ul class="level-1 "><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16450/key-terms-concepts-1.html" title="Key terms & concepts">Key terms & concepts</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../34566/nos-critical-thinking-1.html" title="NOS & Critical Thinking">NOS & Critical Thinking</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../32100/how-the-elements-were-named-1.html" title="How the elements were named">How the elements were named</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../36753/the-culture-of-chemistry-1.html" title="The Culture of Chemistry">The Culture of Chemistry</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17333/nature-of-science-questions-1.html" title="Nature of Science questions">Nature of Science questions</a></li></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../16413/incorporating-im-tok-utilization-etc-1.html" title="Incorporating IM, TOK, 'Utilization' etc.">Incorporating IM, TOK, 'Utilization' etc.</a></li><ul class="level-1 "><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16414/topic-1-1.html" title="Topic 1">Topic 1</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16916/topics-2-12-1.html" title="Topics 2 & 12">Topics 2 & 12</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a 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style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17868/example-of-connections-1.html" title="Example of connections">Example of connections</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../34404/hydroxychloroquine-ib-chemistry-1.html" title="Hydroxychloroquine & IB Chemistry">Hydroxychloroquine & IB Chemistry</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../35418/ammonium-nitrate-ib-chemistry-1.html" title="Ammonium nitrate & IB Chemistry">Ammonium nitrate & IB Chemistry</a></li></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../16685/multiple-choice-tests-for-each-topic-1.html" title="Multiple choice tests for each topic">Multiple choice tests for each topic</a></li><ul class="level-1 "><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16687/sl-questions-by-topic-1.html" title="SL Questions by topic">SL Questions by topic</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16903/1-stoichiometric-relationships-1--1.html" title="1. Stoichiometric relationships (1) ">1. Stoichiometric relationships (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16904/1-stoichiometric-relationships-2--1.html" title="1. Stoichiometric relationships (2) ">1. Stoichiometric relationships (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16710/2-atomic-structure-1.html" title="2. Atomic structure">2. Atomic structure</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16738/3-periodicity-1.html" title="3. Periodicity">3. Periodicity</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16822/4-chemical-bonding-structure-1-1.html" title="4. Chemical bonding & structure (1)">4. Chemical bonding & structure (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16823/4-chemical-bonding-structure-2-1.html" title="4. Chemical bonding & structure (2)">4. Chemical bonding & structure (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16887/5-energetics-thermochemistry-1.html" title="5. Energetics & thermochemistry">5. Energetics & thermochemistry</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16906/6-chemical-kinetics-1.html" title="6. Chemical kinetics">6. Chemical kinetics</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17464/7-equilibrium-1.html" title="7. Equilibrium">7. Equilibrium</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17420/8-acids-and-bases-1.html" title="8. Acids and bases">8. Acids and bases</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17416/9-redox-processes-1.html" title="9. Redox processes">9. Redox processes</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17411/10-organic-chemistry-1--1.html" title="10. Organic chemistry (1) ">10. Organic chemistry (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17412/10-organic-chemistry-2--1.html" title="10. Organic chemistry (2) ">10. Organic chemistry (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17286/11-measurement-data-processing-1--1.html" title="11. Measurement & data processing (1) ">11. Measurement & data processing (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17287/11-measurement-data-processing-2-1.html" title="11. Measurement & data processing (2)">11. Measurement & data processing (2)</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16688/hl-questions-by-topic-1.html" title="HL Questions by topic">HL Questions by topic</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16709/1-stoichiometric-relationships-1-1.html" title="1. Stoichiometric relationships (1)">1. Stoichiometric relationships (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16735/1-stoichiometric-relationships-2-1.html" title="1. Stoichiometric relationships (2)">1. Stoichiometric relationships (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../37016/2-12-atomic-structure-1-1.html" title="2 &12. Atomic structure (1)">2 &12. Atomic structure (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16721/2-12-atomic-structure-2-1.html" title="2 &12. Atomic structure (2)">2 &12. Atomic structure (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16815/3-13-periodicity-transition-metals-1--1.html" title="3 & 13. Periodicity & transition metals (1) ">3 & 13. Periodicity & transition metals (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16816/3-13-periodicity-transition-metals-2--1.html" title="3 & 13. Periodicity & transition metals (2) ">3 & 13. Periodicity & transition metals (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16861/4-14-chemical-bonding-structure-1-1.html" title="4 & 14. Chemical bonding & structure (1)">4 & 14. Chemical bonding & structure (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16862/4-14-chemical-bonding-structure-2-1.html" title="4 & 14. Chemical bonding & structure (2)">4 & 14. Chemical bonding & structure (2)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16894/5-15-energetics-thermochemistry-1--1.html" title="5 & 15. Energetics & thermochemistry (1) ">5 & 15. Energetics & thermochemistry (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../16893/5-15-energetics-thermochemistry-2--1.html" title="5 & 15. Energetics & thermochemistry (2) ">5 & 15. Energetics & thermochemistry (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17654/6-16-chemical-kinetics-1--1.html" title="6 & 16. Chemical kinetics (1) ">6 & 16. Chemical kinetics (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17655/6-16-chemical-kinetics-2--1.html" title="6 & 16. Chemical kinetics (2) ">6 & 16. Chemical kinetics (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17471/7-17-equilibrium-1--1.html" title="7 & 17. Equilibrium (1) ">7 & 17. Equilibrium (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17472/7-17-equilibrium-2--1.html" title="7 & 17. Equilibrium (2) ">7 & 17. Equilibrium (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17421/8-18-acids-bases-1--1.html" title="8 & 18. Acids & bases (1) ">8 & 18. Acids & bases (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17422/8-18-acids-bases-2--1.html" title="8 & 18. Acids & bases (2) ">8 & 18. Acids & bases (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17417/9-19-redox-processes-1--1.html" title="9 & 19 Redox processes (1) ">9 & 19 Redox processes (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17418/9-19-redox-processes-2--1.html" title="9 & 19. Redox processes (2) ">9 & 19. Redox processes (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17413/10-20-organic-chemistry-1--1.html" title="10 & 20. Organic chemistry (1) ">10 & 20. Organic chemistry (1) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17415/10-20-organic-chemistry-2--1.html" title="10 & 20. Organic chemistry (2) ">10 & 20. Organic chemistry (2) </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17288/11-21-measurement-data-processing-analysis-1-1.html" title="11 & 21. Measurement, data processing & analysis (1)">11 & 21. Measurement, data processing & analysis (1)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17289/11-21-measurement-data-processing-analysis-2--1.html" title="11 & 21. Measurement, data processing & analysis (2) ">11 & 21. Measurement, data processing & analysis (2) </a></li></ul></ul></ul></nav></div><!-- /#left-column-->
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</div><section id="main-content"><div id="toc-1672972894" class="toc"><a href="#" class="toc-switcher" title="Show table of contents"><small><i class="fa fa-reorder"></i> Table of contents <span class="pull-right"><i class="fa fa-chevron-down"></i></span></small></a></div><h1><img class="ico" src="../../../img/icons/standard-1.png"> <img class="ico" src="../../../img/icons/higher-1.png"> 4.4 Intermolecular forces (3 hours)</h1><div class="pinkBg"><div><h2>Pause for thought</h2><p><strong>1. What’s in a name?</strong></p><p>Clearly there are attractive forces between all molecules and even between individual noble gas atoms. Helium has an extremely low melting point (-272 <sup>o</sup>C) but nevertheless it does freeze so some force must be holding helium atoms together below this temperature. Most books explain this by referring to the formation of ‘temporary dipoles’. Many give quite elaborate diagrams to show how at any one instant the electrons in one molecule are not evenly spaced so produce a very short-lasting dipole which causes it to be attracted to another molecule with a similar temporarily induced dipole. It is an appealing explanation but as far as I am aware no-one has ever actually proved it to be true. They have given this force a name though – the problem is that not everyone agrees on which name to give it. In the past the IB programme called it van der Waals' forces whereas on this new programme they call it 'London (dispersion) forces'. In fact both are correct.</p><p><img alt="" class="no border" src="../../../ib/chemistry/images/2014%20Core%20%26%20AHL/Topics%204%20%26%2014/fritz-london-.png" style="float: right; width: 310px; height: 347px;">‘van der Waals forces’ is a generic term. Technically it refers to any force present between molecules other than those due to much stronger covalent bonds or electrostatic interactions between ions (ionic bonds). London dispersion forces (which are very weak) are more specific and refer only to the forces of attraction between two non-polar molecules due (presumably) to temporary induced dipoles. They are named after Fritz Wolfgang London (1900 –1954) an American physicist. A specific name is also given to the slightly stronger van der Waals' attractive forces between a polar molecule and a non-polar molecule. This is known as a Debye force and is named after a Dutch physicist, Petrus Josephus Wilhelmus Debye (1884-1966). Stronger still van der Waals forces are present between molecules (such as propanone molecules) which possess a permanent dipole. The specific name for these is a Keesom force. This is named after Willem Hendrik Keesom (1876 –1956) who like Debye and Johannes Diderik van der Waals (1837– 1923) was also a Dutch physicist. Technically there is yet another even stronger van der Waals force of attraction known as hydrogen bonding but this is almost always referred to by its own name. Recently IUPAC has changed the way in which a hydrogen bond is defined to include some weaker interactions not necessarily involving fluorine, nitrogen or oxygen so even this can be quite confusing (see my blog on<a href="chemistry/blog-post/10664/hydrogen-bonding.htm"> Hydrogen bonding</a>).</p><hr class="hidden"><p>To try to bring some simplification to our students the IB specifies which nomenclature should be used (an example of language in Chemistry). Debye and London forces are both referred to by the IB simply as 'London (dispersion) forces' of attraction and Keesom forces are known as dipole-dipole interactions. Hydrogen bonding is reserved for the specific stronger dipole-dipole interactions between hydrogen bonded directly to fluorine, oxygen or nitrogen atoms in one molecule and the fluorine, oxygen or nitrogen atoms bonded to hydrogen in another molecule. Sometimes this can occur within the same molecule, then it is known as intramolecular hydrogen bonding. For example, consider hydroquinone and catechol.</p><p style="text-align: center; "><img alt="" class="noborder" height="80" src="../../../ib/chemistry/images/Core and AHL/Bonding/hydroquinone.jpg" width="218"></p><p style="text-align: center; ">benzene-1,4-diol (hydroquinone) - boiling point 287 <sup>o</sup>C</p><hr class="hidden"><p style="text-align: center; "><img alt="" class="noborder" height="151" src="../../../ib/chemistry/images/Core and AHL/Bonding/Catechol.png" width="150"></p><p style="text-align: center; ">benzene-1,2-diol (catechol) - boiling point 245 <sup>o</sup>C</p><p>Intramolecular hydrogen bonding is not possible in hydroquinone as the two -OH groups are too far apart to interact so there is stronger intermolecular hydrogen bonding between the molecules. In catechol there will be some intramolecular hydrogen bonding between the hydrogen atoms on one of the phenolic groups with the oxygen atoms on the other phenolic group. This means the intermolecular forces of attraction will be weaker between the molecules so the boiling point is lower.</p><hr class="hidden"><p><strong>2. Solubility</strong></p><p>In sub-topic 4.4 students are asked to compare the properties of covalent substances resulting from different types of bonding. This includes solubility in polar and non-polar solvents. Students are fond of the 'like dissolves like' concept. Thus alkanes, which are non-polar, are immiscible with water but dissolve in non-polar solvents as they can form London (dispersion) forces of attraction with the non-polar solvent molecules. Of course, they could also form London (dispersion) forces of attraction with water molecules but the polar water molecules prefer to attract each other through hydrogen bonding. Polar molecules such as ethanol and propanone are miscible with water because the hydrocarbon part of the molecule is small. As the length of the carbon chain increases in the homologous series of alcohols the solubility in water rapidly decreases so that butan-1-ol is only slightly soluble in water and pentan-1-ol is hardly soluble at all.</p><hr class="hidden"><table border="0" cellpadding="0" cellspacing="0"><tbody><tr><td><img alt="" class="noborder" height="150" src="../../../ib/chemistry/images/Core and AHL/Bonding/butan-1-ol.jpg" width="150"></td><td><img alt="" class="noborder" height="150" src="../../../ib/chemistry/images/Core and AHL/Bonding/2R-butan-2-ol-jmol.jpeg" width="150"></td><td><img alt="" src="../../../ib/chemistry/images/2014%20Core%20%26%20AHL/Topics%204%20%26%2014/pentan-1-ol.png" style="width: 150px; height: 150px;"></td><td style="text-align: center;"><img alt="" class="noborder" height="150" src="../../../ib/chemistry/images/Core and AHL/Bonding/2S-pentan-2-ol-jmol.jpeg" width="150"></td></tr><tr><td style="text-align: center;">butan-1-ol</td><td style="text-align: center;">butan-2-ol</td><td style="text-align: center;">pentan-1-ol</td><td style="text-align: center;">pentan-2-ol</td></tr></tbody></table><hr class="hidden"><p>Note that as the molecule becomes more spherical the London (dispersion) forces of attraction between molecules becomes less, so butan-2-ol (290 g dm<sup>-3</sup>) is more soluble in water than butan-1-ol (63.2 g dm<sup>-3</sup>) and pentan-2-ol (45 g dm<sup>-3</sup>) is more soluble in water than pentan-1-ol (22 g dm<sup>-3</sup>).</p><p>All this is fine, but what about ionic compounds?</p><p>Since ions are obviously charged it would be reasonable to assume they will dissolve in a polar solvent such as water and of course virtually all the salts of the alkali metals, such as sodium chloride, are very soluble in water. I like to ask students to explain why sodium chloride has a high melting point (801 <sup>o</sup>C) and they give the correct answer that considerable energy needs to be provided to overcome the lattice enthalpy. Fine - now ask them why it dissolves easily in water, which also breaks the crystal structure and yet the temperature hardly changes (in fact it does drop very slightly). It makes them realise how strong the enthalpy of hydration is - for Higher Level students this is covered in <a href="../17776/energy-cycles--1.html" title="Core & AHL » Teaching each topic & sub-topic » Topics 5 & 15 » Energy cycles ">15.1 Energy cycles</a>. The exothermic hydration enthalpy for sodium and chloride ions is only slightly less than the endothermic lattice enthalpy so by making up the difference by taking a small amount of heat from the water sodium chloride can dissolve. Once you move to group 2 salts though the lattice enthalpies get considerably larger. So do the hydration enthalpies as the smaller more highly charged cations attract water molecules more strongly. For some group 2 salts such as magnesium sulfate the difference is still small enough for the salt to be soluble but for others such as barium sulfate the difference is too much and the salt is essentially insoluble in water.</p><p><img alt="" class="noborder right" height="181" src="../../../ib/chemistry/images/Core and AHL/Bonding/H2So4 and water.jpg" title="Add concentrated sulfuric acid to water - not the other way round - in order to dilute it. (Image from Andrew Lambert Photography/Science Photo Library)" width="250"></p><p>One final point worth stressing with students is that if there is no lattice enthalpy to overcome the hydration enthalpy can be given off as a large amount of heat - for this reason you should never add water to concentrated sulfuric acid in order to dilute it. The image on the right shows the correct way to do it, although even then you should still take considerable care.</p><hr class="hidden"></div></div><hr class="hidden"><div class="box"><h2>Nature of Science</h2><p>Evidence for scientific theories can be obtained by making and testing predictions based on them. For example, London (dispersion) forces and hydrogen bonding can be used to explain specific interactions. Since molecular covalent compounds can exist in the liquid and solid states there must be attractive forces between their particles which are significantly greater than those due to gravity alone.</p></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h3><b><span style="font-weight: normal; "></span></b></h3><div class="yellowBg"><div><h2><b><span style="font-weight: normal; "><strong>Learning outcomes</strong></span></b></h2><p><span style="font-weight: normal; ">After studying this topic students should be able to:</span></p><p><b><span style="font-weight: normal; "><strong>Understand:</strong></span></b></p><ul><li>London (dispersion) forces, dipole-dipole forces and hydrogen bonding are all included in intermolecular forces.</li><li>In terms of their relative strengths the order of these interactive forces are London (dispersion) forces < dipole-dipole forces < hydrogen bonds.</li></ul><p><strong>Apply their knowledge to:</strong></p><ul><li>Deduce the types of intermolecular force present in substances, based on<br>the structure and chemical formula of the substance.</li><li>Explain the physical properties of covalent compounds (to include volatility, electrical conductivity and solubility) in terms of their structure and intermolecular forces.</li></ul></div></div></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal;"></span></b></h4><div class="yellowBg"><div><h4><b><span style="font-weight: normal;"><strong>Clarification notes</strong></span></b></h4><p>“London (dispersion) forces” should be used to describe the instantaneous induced dipole - induced dipole forces that exist between any atoms or groups of atoms and should be used for non-polar entities.<br>“van der Waals” is an inclusive term, which includes dipole–dipole, dipole-induced dipole and London (dispersion) forces.</p><hr class="hidden"><h4><strong>International-mindedness</strong></h4><p>(Nothing is listed in the programme for international-mindedness under this sub-topic)</p></div></div></td></tr></tbody></table></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h2><span style=""><b><span style="font-weight: normal;"><strong>Teaching tips</strong></span></b></span></h2><p>Although this topic may seem quite straightforward to us as teachers it is something that many students experience considerable difficulty with as evidenced by how they answer questions on intermolecular forces in exams. For this reason it needs to be taught thoroughly and carefully.</p><p>I start by looking at how we can gauge the strengths of the attractive forces and talk about what happens during changes of state. Melting points are not reliable as they depend on the packing in the solid and the particles are still close together in the liquid state so emphasise the importance of boiling points.</p><p>The practical on <a href="../17162/boiling-points-of-mixtures-1.html">boiling points of mixtures</a> is superb and well worth doing. Propan-1-ol and propan-2-ol both have hydrogen bonding, ethanol and cyclohexane show hydrogen bonding and London (dispersion) forces of attraction respectively and trichloromethane and ethyl ethanoate show dipole-dipole individually and hydrogen bonding when mixed.</p><p>As well as using water/ice and ammonia etc. to illustrate hydrogen bonding I also use HF and HCl, H<sub>2</sub>O and H<sub>2</sub>S, NH<sub>3</sub> and PH<sub>3</sub>, CH<sub>3</sub>OCH<sub>3</sub> and CH<sub>3</sub>CH<sub>2</sub>OH and propane, ethanal and ethanol. I also give a very simple account of hydrogen bonding between the bases in DNA as it helps those doing biology.</p><p>After covering all the different types of forces challenge them to put a list of compounds in increasing order of their boiling points. You need compounds with similar molar masses. A suitable list might be propan-1-ol (<em>M</em><sub>r</sub> = 60), propan-2-ol (<em>M</em><sub>r</sub> = 60), propanone (<em>M</em><sub>r</sub> = 58), butane (<em>M</em><sub>r</sub> = 58), 2-methypropane (<em>M</em><sub>r</sub> = 58), ethanoic acid (<em>M</em><sub>r</sub> = 60), methoxyethane (<em>M</em><sub>r</sub> = 60) and methyl methanoate (<em>M</em><sub>r</sub> = 60). You can even chuck in sodium chloride (<em>M</em><sub>r</sub> = 58.5) extra! If students can deduce the correct order for all these compounds then they will have gained an excellent understanding.</p><p>Finally one word of warning. Be careful if you use past IB questions because the answers may no longer be 'correct'. In the past an answer that was "van der Waals' forces" may now be "London (dispersion) forces".</p><hr class="hidden"></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal; "><strong>Study guide</strong></span></b></h4><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><b><span style="font-weight: normal;"><img alt="" class="left noborder" src="../../../ib/chemistry/images/2014%20Basic%20information/New%20cover.jpg" style="width: 67px; height: 96px;"></span></b></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><hr class="hidden"><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><b><span style="font-weight: normal;">Pages 29 & 30</span></b></p><hr class="hidden"><h2>Questions</h2><p>For ten 'quiz' multiple choice questions with the answers explained see <a href="../24512/mc-test-intermolecular-forces-1.html" title="Core & AHL » Teaching each topic & sub-topic » Topics 4 & 14 » Intermolecular forces » MC test: Intermolecular forces">MC test: Intermolecular forces</a>.</p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;">For short-answer questions which can be set as an assignment for a test, homework or given for self study together with model answers see <a href="../40937/intermolecular-forces-questions-1.html" title="Core & AHL » Teaching each topic & sub-topic » Topics 4 & 14 » Intermolecular forces » Intermolecular forces questions">Intermolecular forces questions</a>.</p><h4><b><span style="font-weight: normal;"><strong>Vocabulary list</strong></span></b></h4><p>London (dispersion) forces<br>induced dipole<br>van der Waals' forces<br>dipole-dipole interactions<br>hydrogen bonding<br>intramolecular<br>intermolecular</p><hr class="hidden"><h4><span style="font-family: "Arial Narrow",Arial,Helvetica,sans-serif; font-size: 17px; font-weight: bold;"><b><span style="font-weight: normal;"><strong>IM, TOK, 'Utilization' etc.</strong></span></b></span></h4><p>See <a href="../17055/topics-4-14--1.html">separate page</a> which covers all of Topic 4.</p><hr class="hidden"><h2>Practical work</h2><p><a href="../17162/boiling-points-of-mixtures-1.html"><img class="ico" src="../../../img/icons/lab-1.png"> Boiling points of mixtures</a></p><p><img class="ico" src="../../../img/icons/lab-1.png"> Non-polar iodine dissolves in a non-polar solvent such as heptane to give a purple solution - this is part of <a href="../17239/the-halogens-1.html"><img class="ico" src="../../../img/icons/lab-1.png"> The halogens </a>practical.</p><hr class="hidden"></td></tr></tbody></table></div><hr class="hidden"><div class="greenBg"><h2 id="anchor-12">Teaching slides</h2><p>Teachers may wish to share these slides with students for learning or for reviewing key concepts.</p><div id="myCarousel-13" class="carousel slide" data-id="242"><!-- Carousel items --><div class="carousel-inner"><div class="active item"><a class="fancy" href="../../../tib-galleries/3-242/44-1.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-1.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-242/44-2.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-2.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-242/44-3.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-3.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-242/44-4.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-4.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-242/44-5.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-5.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-242/44-6.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-6.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-242/44-7.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-7.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-242/44-8.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-8.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-242/44-9.png" rel="gallery-242" title=""><img alt="" src="files/tib-galleries/3-242/44-9.png"></a><div class="carousel-caption"><p>Intermolecular forces: </p></div></div></div><!-- Carousel nav --><a class="carousel-control left" href="#myCarousel-13" data-slide="prev">‹</a><a class="carousel-control right" href="#myCarousel-13" data-slide="next">›</a><div class="tib-indicators"><img class="" title="Click to view" style="margin: 10px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-1-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-2-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-3-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-4-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-5-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-6-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-7-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-8-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-242/44-9-thumb128.jpg"></div></div><p> </p></div><hr class="hidden"><div class="blueBg"><h2><span style="font-weight: bold;">Other resources</span></h2><p><strong>1. </strong>Relating inter- and intra- molecular attractions to basketball. Two teachers, Jonathan Bergman and Aaron Sams talk about all the different types of intermolecular attractive forces.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/-ipttIAvvCk?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="youtu.be/-ipttIAvvCk" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-1" name="video-1"> </span> Intermolecular forces</a></p><hr class="hidden"><p><strong>2.</strong> A very short but simple video showing how hydrogen bonding arises in water and the properties that depend upon it.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/aH2IbYs_XjY?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/aH2IbYs_XjY" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-2" name="video-2"> </span> Hydrogen bonding in water</a></p><hr class="hidden"><p><strong>3.</strong> A <a href="http://www.science.uwaterloo.ca/~cchieh/cact/c123/intermol.html">tutorial on intermolecular forces</a> with some good questions from the University of Waterloo, Canada.</p><hr class="hidden"></div></section></article><section id="media-extras"><div class="page-actions no-print navbar inline hidden-desktop"><div class="navbar-inner"><ul class="nav"><li><a class="presentation" href="#" onclick="return false;"><i class="fa fa-desktop"></i></a></li><li><a class="print-section-blog" href="#" onclick="return false;"><i class="fa fa-print"></i></a></li><li><a class="page-bookmarker" data-ticket="IB Docs (2) Team" data-pid="17160" href="#" onclick="return false;"><i class="fa fa-star"></i></a></li><li><a class="personal-notes" href="#" onclick="return false;"><i class="fa fa-file-text"></i></a></li><li><a class="" data-toggle="modal" href="#modal-feedback" onclick="return false;"><i class="fa fa-envelope-o"></i></a></li><li class="dropdown"><a class="dropdown-toggle" data-toggle="dropdown" data-target="#" href="#"><i class="fa fa-share-alt"></i></a><ul class="dropdown-menu" role="menu"><li><a class="" target="_blank" title="Share on Twitter" href="https://twitter.com/share?text=%22Intermolecular+forces%22+-+via+%40InThinker+%23chemistry%0A&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F17160%2Fintermolecular-forces"><i class="fa fa-twitter-square"></i><span>Twitter</span></a></li><li><a class="" target="_blank" title="Share on Facebook" href="https://www.facebook.com/sharer.php?u=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F17160%2Fintermolecular-forces&t=Intermolecular+forces"><i class="fa fa-facebook-square"></i><span>Facebook</span></a></li><li><a class="" href="http://www.linkedin.com/shareArticle?mini=true&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F17160%2Fintermolecular-forces"><i class="fa fa-linkedin-square"></i><span>LinkedIn</span></a></li><li><a class="" href="https://plus.google.com/share?url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F17160%2Fintermolecular-forces"><i class="fa fa-google-plus-square"></i><span>Google +</span></a></li><li><a class="" href="mailto:?subject=Intermolecular forces&body=1. 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