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auxiliary case study</a></li><li><a href="../../page/19258/nuclear-medicine-.html">Nuclear medicine </a></li><li><a href="../../page/19273/drug-detection-analysis-.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../../page/16592/practical-scheme-of-work-ia-.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../../page/16682/internal-assessment.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../../page/18892/scaffolding-the-investigation.html">'Scaffolding' the investigation</a></li><li><a href="../../page/18896/timing-organisation-.html">Timing & organisation </a></li><li><a href="../../page/18905/choosing-the-research-question.html">Choosing the research question</a></li><li><a href="../../page/18946/personal-engagement.html">Personal engagement</a></li><li><a href="../../page/18950/exploration.html">Exploration</a></li><li><a href="../../page/18957/analysis.html">Analysis</a></li><li><a href="../../page/18965/evaluation.html">Evaluation</a></li><li><a href="../../page/18966/communication.html">Communication</a></li><li><a href="../../page/19882/internal-standardization-of-the-ia.html">Internal standardization of the IA</a></li><li><a href="../../page/19901/submitting-the-samples-for-moderation.html">Submitting the samples for moderation</a></li><li><a href="../../page/33754/ten-suggestions-for-ias-using-secondary-data.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../../page/37544/gaining-full-marks-for-a-databased-ia-.html">Gaining full marks for a databased IA </a></li><li><a href="../../page/19506/ia-example-marking-exercise-.html">IA example & marking exercise </a></li><li><a href="../../page/23929/genuine-examples-of-moderated-ia-reports.html">Genuine examples of moderated IA reports</a></li><li><a href="../../page/25234/examples-of-teacher-marked-ia-reports-.html">Examples of teacher-marked IA reports </a></li><li><a href="../../page/37542/history-of-internal-assessment.html">History of Internal Assessment</a></li></ul></li><li><a href="../../page/16598/mandatory-laboratory-components.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../../page/16613/formula-of-magnesium-oxide-.html">Formula of magnesium oxide </a></li><li><a href="../../page/16612/determining-the-mr-of-an-unknown-gas.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../../page/16615/acid-base-titrations-.html">Acid-base titrations </a></li><li><a href="../../page/16616/a-green-acid-base-practical.html">A green acid-base practical</a></li><li><a href="../../page/16617/analysis-of-aspirin-tablets.html">Analysis of aspirin tablets</a></li><li><a href="../../page/16618/caco3-in-egg-shells.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../../page/16644/enthalpy-changes.html">Enthalpy changes</a></li><li><a href="../../page/16631/reaction-rates.html">Reaction rates</a></li><li><a href="../../page/16635/rate-dependent-factors.html">Rate-dependent factors</a></li><li><a href="../../page/16636/determining-ea-for-a-reaction.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../../page/16637/iodination-of-propanone.html">Iodination of propanone</a></li><li><a href="../../page/18144/titrations-with-a-ph-meter.html">Titrations with a pH meter</a></li><li><a href="../../page/18355/redox-titration-with-kmno4-.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../../page/16640/voltaic-cells.html">Voltaic cells</a></li><li><a href="../../page/16659/3-d-molecular-modelling-.html">3-D molecular modelling </a></li></ul></li><li><a href="../../page/17168/other-good-practicals.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../../page/17196/common-chemical-reactions.html">Common chemical reactions</a></li><li><a href="../../page/227/elements-oxides-of-the-third-period-.html">Elements & oxides of the third period </a></li><li><a href="../../page/17239/the-halogens.html">The halogens</a></li><li><a href="../../page/17162/boiling-points-of-mixtures.html">Boiling points of mixtures</a></li><li><a href="../../page/17170/polarity-of-molecules.html">Polarity of molecules</a></li><li><a href="../../page/18083/le-chateliers-principle-.html">Le Chatelier's principle </a></li><li><a href="../../page/19582/determining-kc-for-an-esterification-reaction.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../../page/18164/redox-reactions-of-vanadium-.html">Redox reactions of vanadium </a></li><li><a href="../../page/18351/chlorine-in-swimming-pools-.html">Chlorine in swimming pools </a></li><li><a href="../../page/18178/analysis-of-cuii-ions-in-solution-.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../../page/18179/percentage-of-copper-in-brass.html">Percentage of copper in brass</a></li><li><a href="../../page/18356/electrolytic-cells-.html">Electrolytic cells </a></li><li><a href="../../page/18598/reactions-of-organic-compounds.html">Reactions of organic compounds</a></li><li><a href="../../page/18752/hydrolysis-of-halogenoalkanes.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../../page/18784/preparation-of-13-dinitrobenzene-.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../../page/19022/determination-of-an-organic-structure.html">Determination of an organic structure</a></li><li><a href="../../page/19887/preparation-of-nylon-66.html">Preparation of nylon 6,6</a></li><li><a href="../../page/19343/determination-of-vitamin-c-content-.html">Determination of vitamin C content </a></li><li><a href="../../page/19342/hydrolysis-of-starch-.html">Hydrolysis of starch </a></li><li><a href="../../page/19159/preparation-purification-of-aspirin-.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../../page/18851/ict-in-practical-work.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../../page/18852/data-logging-.html">Data logging </a></li><li><a href="../../page/18853/software-for-graph-plotting-.html">Software for graph plotting </a></li><li><a href="../../page/18854/spreadsheets-for-data-processing-.html">Spreadsheets for data processing </a></li><li><a href="../../page/18855/databases.html">Databases</a></li><li><a href="../../page/18856/computer-modelling-simulations-.html">Computer modelling & simulations </a></li></ul></li><li><a href="../../page/16594/group-4-project.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../../page/16595/practicalities.html">Practicalities</a></li><li><a href="../../page/16596/reflective-statement-.html">Reflective statement </a></li></ul></li><li><a 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</a></li><li><a href="../../page/17787/hl-questions-on-each-sub-topic-.html">HL Questions on each sub-topic </a></li><li><a href="../../page/20428/hl-paper-3-section-a-questions.html">HL Paper 3 Section A questions</a></li><li><a href="../../page/17793/hl-questions-on-the-options.html">HL Questions on the options</a></li><li><a href="../../page/24973/hl-quizzes-on-option-sub-topics.html">HL Quizzes on option sub-topics</a></li><li><a href="../../page/41573/printable-versions-of-written-tasks-.html">Printable versions of written tasks </a></li></ul></li><li><a href="../../page/41465/complete-course-for-students-.html">Complete course for students </a><ul class="level-1"><li><a href="../../page/27988/full-coverage-of-each-topic-and-sub-topic.html" class="father">Full coverage of each topic and sub-topic</a><ul class="level-2"><li><a href="../../page/27959/topic-1-stoichiometric-relationships.html">Topic 1 : Stoichiometric relationships</a></li><li><a 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<h1 class="section-title">Design experiments with esters</h1>
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Thursday 24 October 2013
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Teachers are always looking for suitable topics to give their students for <a href="http://www.thinkib.net/chemistry/page/2380/design-practicals">design experiments</a>. One common starting point is “Investigate an aspect of esterification”. This is actually given as an example on page 25 of the current guide with the suggestion that the student may come up with a focused research question such as “How does changing the carboxylic acid affect the equilibrium constant of the esterification reaction with ethanol?” or “How does changing the acid catalyst concentration affect the rate of the esterification reaction between ethanol and ethanoic acid?”. In fact neither of these research questions is easy to design experiments to investigate as it typically takes one week for the reaction to reach equilibrium and without access to glc or some other sophisticated equipment it is not easy to follow the rate of the reaction. For this reason I steer students away from researching into the rate or position of equilibrium by giving them the design experiment before they have studied these topics but after they have done simple test tube reactions to make esters for Topic 10: Organic chemistry.</p>
<p>
<img alt="" class="left noborder" height="315" src="../../../ib/chemistry/images/Practicals/Making%20esters-1.jpg" title="Students making esters in the lab" width="236">Relevant esters can be made in a few minutes by warming a carboxylic acid and an alcohol in the presence of a few drops of sulfuric acid and then pouring the resulting mixture into sodium carbonate solution. This neutralizes the acid and the ester floats on the top. The dependent variable is then the smell of the ester. This has produced some excellent research questions such as:</p>
<p>
Does changing the type of alcohol from primary to secondary to tertiary have any effect on the odour of the ester?</p>
<p>
Is there is a trend in the smells of the esters produced between salicylic acid and a homologous series of alcohols?</p>
<p>
Does <em>cis</em>/<em>trans</em> isomerism affect the smell of an ester? (This was determined by making esters with <em>cis-</em>but-2-ene-1,4-dioic acid and <em> trans</em>-but-2-ene-1,4-dioic acid).</p>
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<br>
Smell is an interesting property and students usually devise their own scale to measure it such as from 0 (revolting) to 10 (ecstatic). Clearly this is subjective but it does provide one way of obtaining some ‘quantitative’ data so that it could be assessed for Design although realistically not for Data collection and processing (DCP) and/or Conclusion and evaluation (CE). I actually use esterification as an introduction to design but some teachers do include it in their assessed samples. Usually moderators are quite happy with this but I was surprised by the comment from one moderator who stated that “smell is not chemistry”. Try telling this to all the chemists who work in the perfumes and food industries! Smell is actually a really interesting chemical property. Unlike colour it cannot be defined simply by a number such as wavelength. The commonly accepted theory of smell is that it depends on the shape of the odorant which fits into receptors in the nose by some sort of ‘lock and key’ mechanism. Recent work is challenging this and suggesting that it may also be due to molecular vibrations within the odorants. In <a href="http://www.ncbi.nlm.nih.gov/pubmed/15034588">2004 Keller and Vosshall </a>showed that humans could not tell the difference in smell between deuterated and undeuterated acetophenone. However earlier this year <a href="http://www.plosone.org/article/info%3Adoi%2F10.1371%2Fjournal.pone.0055780">Gane et al.</a> extended this work. Although humans cannot tell the difference between acetophenone and deuterated acetophenone they can distinguish between deuterated and undeuterated musk odorants. It seems as if we may be getting closer to quantifying one of the last chemical properties that has so far had to rely on subjective descriptions. </p>
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<div class="prevnext-posts"><div class="pull-right text-right"><a href="../15978/investigate-an-aspect-of-diving-submarines.html" style="font-style: normal">Investigate an aspect of diving submarines <i class="fa fa-chevron-circle-right"></i></a><br><em class="gray"><small>30 Oct 2013</small></em></div><div class="pull-left"><a href="../15956/cnt-computers.html" style="font-style: normal"><i class="fa fa-chevron-circle-left"></i> CNT computers</a><br><em class="gray"><small>15 Oct 2013</small></em></div></div>
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Please enable cookies to log in.</div><div class="alert alert-info"><i class="fa fa-question-circle"></i> Enabling cookies in <a target="_blank" style="margin: 0; padding: 0;" href="https://support.mozilla.org/en-US/kb/enable-and-disable-cookies-website-preferences">Firefox</a>, <a target="_blank" style="margin: 0; padding: 0;" href="https://support.google.com/accounts/answer/61416?hl=en">Chrome</a>, <a target="_blank" style="margin: 0; padding: 0;" href="http://windows.microsoft.com/en-us/windows-vista/block-or-allow-cookies">Explorer</a></div>';$("#modal-login .modal-header").append(msg)}if($(".panel-expandable > .panel-heading").click((function(e){e.preventDefault();var panel=$(this).closest(".panel-expandable"),expandables=panel.hasClass("panel-has-footer")?".panel-body, .panel-footer":".panel-body";panel.find(".panel-body").is(":visible")?(panel.find(expandables).slideUp("fast"),panel.find(".expander > .fa-minus").removeClass("fa-minus").addClass("fa-plus")):(panel.find(expandables).slideDown("fast"),panel.find(".expander > .fa-plus").removeClass("fa-plus").addClass("fa-minus"))})),$("#modal-find-out-more").css({width:.8*$("#container").width()+"px","margin-left":-.4*$("#container").width()+"px"}),$(".modal-xxl").length){var modalTopPos=Math.round(.07*$(window).height());$(window).width()>1200&&$(".modal-xxl").css({"max-width":$(window).width()>960?"960px":$(window).width()+"px",width:$(window).width()>960?"960px":$(window).width()+"px","margin-left":$(window).width()>960?"-480px":Math.round($(window).width()/2)}),$(".modal-xxl").css("top",modalTopPos+"px"),$(".modal-xxl").on("shown",(function(){var mHeaderH=$(this).find(".modal-header").outerHeight(),mBody=$(this).find(".modal-body"),mBodyH=mBody.outerHeight(),mFooterH=$(this).find(".modal-footer").outerHeight(),bottomOfTheModal=modalTopPos+mHeaderH+mBodyH+mFooterH;if(bottomOfTheModal<$(window).height())mBodyH+=$(window).height()-bottomOfTheModal-60,mBody.css("max-height",mBodyH+"px");else{$(window).scrollTop(0),modalTopPos=10,$(".modal-xxl").css("top",modalTopPos+"px"),bottomOfTheModal=modalTopPos+mHeaderH+mBodyH+mFooterH,availableScroll=bottomOfTheModal-$(window).height()+modalTopPos;var lastPos=-1;$(window).on("scroll",(function(){var s=$(window).scrollTop()>availableScroll?availableScroll:$(window).scrollTop();newPos=modalTopPos-s,newPos!=lastPos&&($(".modal-xxl").css("top",newPos+"px"),lastPos=newPos)}))}}))}function popupHelp(url,title,w,h){var dualScreenLeft=void 0!==window.screenLeft?window.screenLeft:screen.left,dualScreenTop=void 0!==window.screenTop?window.screenTop:screen.top,width,height,left=(window.innerWidth?window.innerWidth:document.documentElement.clientWidth?document.documentElement.clientWidth:screen.width)/2-w/2+dualScreenLeft,top=(window.innerHeight?window.innerHeight:document.documentElement.clientHeight?document.documentElement.clientHeight:screen.height)/2-h/2+dualScreenTop,newWindow=window.open(url,title,"menubar=no,location=no,resizable=0, width="+w+", height="+h+", top="+top+", left="+left);return window.focus&&(newWindow?newWindow.focus():$('<div class="alert alert-warning" style="margin-bottom: 0px;"><p class="help-block">Pop Up blocked. Please allow Pop Ups in your browser settings.</p></div>').insertBefore("body")),newWindow}if($(".open-student-access-help").click((function(e){e.preventDefault();var h=$(window).height()-20,w=$(window).width()<1280?$(window).width():1280;popupHelp(helpURL,"Student Access Help",w,h)})),$(".pop-up-help").click((function(e){e.preventDefault();var url=$(this).attr("href"),title=$(this).data("title"),h=$(window).height()-20,w;popupHelp(url,title,$(window).width()<1280?$(window).width():1280,h)})),$("section.tib-hiddenbox").length){var count=0;$($("section.tib-hiddenbox").get().reverse()).each((function(){var box=$(this),revealButton;$("<a />").attr("class","btn showhider").attr("rel","hiddenBoxContent"+count).attr("style","margin-bottom: 0;").html('<i class="fa fa-eye"></i>').insertBefore(box);var newContainer=$("<div />").attr("class","hidden-content").attr("id","hiddenBoxContent"+count).html(box.html());newContainer.hide(),newContainer.insertBefore(box),box.remove(),count++})),$("a.showhider").on("click",(function(e){var container=$("#"+$(this).attr("rel"));container.is(":hidden")?(container.fadeIn("fast"),$(this).html('<i class="fa fa-eye-slash"></i>')):(container.fadeOut("fast"),$(this).html('<i class="fa fa-eye"></i>'))}))}
let commentEditor={};function initCommentsEditor(){const t=document.querySelector("#comment-content");t&&CKEDITOR.BasicEditor.create(t,{toolbar:{viewportTopOffset:50,items:["bold","italic","link","subscript","superscript"]},link:{decorators:{addLinkNoFollow:{mode:"automatic",callback:function(t){if(null!=t)return["http://","http://www","https://","https://www","ftp:"].some((o=>t.startsWith(o)))},attributes:{target:"_blank",class:"ck-link",rel:"nofollow"}}}}}).then((function(t){commentEditor=t,commentEditor.execute("heading",{value:"paragraph"})})).catch((function(t){console.error(t)}))}function replaceComment(content,commentId){$("#cancel-comment-post").trigger("click"),$("#comm-"+commentId+" > .comment-content div.comment-text").html(content)}function placeComment(html,fatherId){$("#comment-form").hide(),$("#comment-form textarea").val(""),fatherId>0?($("#comments #comm-"+fatherId).append(html),$("#comments").append($("#comment-form"))):$("#comments").append(html).append($("#comment-form")),$(".comment .fa-arrow-down").removeClass("fa-arrow-down").addClass("fa-reply"),$(".comment-content").removeClass("marked"),$("#comment-form").show("fast")}function update_sticky_comments(arrIds,mode){$.post("pages/edit/update-sticky-comments.php?mode="+mode,{ids:arrIds,ticket:$("#comment-ticket").val()},(function(data){1==data.success?("set"==data.mode&&$("#sticky-"+data.id).parents("div.comment").each((function(e){$(this).find("a.pull-right").first().addClass("sticky"),$(this).find("a.pull-right").first().attr("title","Unmark as important")})),"unset"==data.mode&&($("#sticky-"+data.id).removeClass("sticky"),$("#sticky-"+data.id).attr("title","Mark as important"),$("#sticky-"+data.id).closest("div.comment").find("div.comment").each((function(e){$(this).find("a.pull-right").first().removeClass("sticky"),$(this).find("a.pull-right").first().attr("title","Mark as important")})))):alert(data.error)}),"json")}"undefined"!=typeof CKEDITOR&&initCommentsEditor(),$("section#comments").on("click","#edit-comment",(function(e){e.preventDefault();var commentId=$("form#comment-form #comment-mode").val(),commentContent=commentEditor.getData(),ticket=$("#comment-ticket").val(),sectionId=$("#section-id").val();$.post("pages/comment.php",{action:"edit",comment_id:commentId,content:commentContent,ticket:ticket},(function(data){"0"==data.success?alert(data.error):replaceComment(data.text,commentId)}),"json")})),$("section#comments").on("click","a.edit-comment",(function(e){e.preventDefault(),$(".comment .hidden").removeClass("hidden");var commentId=$(this).data("comment-id"),form=$("form#comment-form"),text=$("#comm-"+commentId+" > .comment-content div.comment-text").html();commentEditor.setData(text),$("form#comment-form textarea").val(""),$("form#comment-form textarea").val(text),$("#comm-"+commentId+" > .comment-content > img").addClass("hidden"),$("#comm-"+commentId+" > .comment-content > div.comment-text").addClass("hidden"),$("#comm-"+commentId+" > .comment-footer").addClass("hidden"),$("#comm-"+commentId+" > .comment-content").append(form),$("form#comment-form #submit-comment").hide(),$("form#comment-form #edit-comment").show(),$("form#comment-form #cancel-comment-post").show(),$("form#comment-form #comment-mode").val(commentId),fancyScrollTo("comment-form"),$("form#comment-form textarea").focus()})),$("section#comments").on("click","#submit-comment",(function(e){e.preventDefault();var commentContent=commentEditor.getData(),fatherId=$("#father-comment").val(),ticket=$("#comment-ticket").val(),sectionId=$("#section-id").val();$.post("pages/comment.php",{action:"post",section_id:sectionId,father_id:fatherId,content:commentContent,ticket:ticket},(function(data){if("0"==data.success)alert(data.error);else{commentEditor.setData(""),placeComment(data.html,fatherId),$("form#comment-form #cancel-comment-post").hide();var n=0;$("#n-comments").text().length>0&&(n=parseInt($("#n-comments").text())),$("#n-comments").text(n+1)}}),"json")})),$("section#comments").on("click","a.reply-comment",(function(e){e.preventDefault(),$(".comment .fa-arrow-down").removeClass("fa-arrow-down").addClass("fa-reply"),$(".comment-content").removeClass("marked");var form=$("form#comment-form"),fatherId=$(this).parent().parent(".comment").attr("rel");form.find("#father-comment").val(fatherId),$(this).parent().parent(".comment").find("> .reply-area").append(form),$(this).find(".fa-reply").removeClass("fa-reply").addClass("fa-arrow-down"),$(this).parent().prev(".comment-content").addClass("marked"),$("form#comment-form #cancel-comment-post").show(),fancyScrollTo("comment-form"),$("form#comment-form textarea").focus()})),$("section#comments").on("click","#cancel-comment-post",(function(e){e.preventDefault(),$(".comment .hidden").removeClass("hidden"),$(".comment .fa-arrow-down").removeClass("fa-arrow-down").addClass("fa-reply"),$(".comment-content.marked").removeClass("marked"),commentEditor.setData("");var form=$("form#comment-form");$("section#comments").append(form),$("form#comment-form #father-comment").val("0"),$("form#comment-form textarea").val(""),$("form#comment-form #comment-mode").val("new"),$("#edit-comment").hide(),$(this).hide(),$("#submit-comment").show()})),$("section#comments").on("click","a.delete-comment",(function(e){var commentId=$(this).data("comment-id"),isFather=$("#comm-"+commentId).children(".comment").length>0,ticket=$("#comment-ticket").val(),msg="You are going to delete a comment.\n\nThis action cannot be undone.\n\nAre you sure?";isFather&&(msg="You are going to delete a comment and all its replies.\n\nThis action cannot be undone.\n\nAre you sure?"),confirm(msg)&&$.post("pages/comment.php",{action:"delete",comment_id:commentId,is_father:isFather,ticket:ticket},(function(data){if("0"==data.success)alert(data.error);else{$("#comm-"+commentId+".comment").replaceWith(data.text);var n=0;$("#n-comments").text().length&&(n=parseInt($("#n-comments").text())),$("#n-comments").text(n-parseInt(data.deleted))}}),"json"),e.preventDefault(),e.stopPropagation()})),$("section#comments").on("click","a.pull-right",(function(e){e.preventDefault();var arrayIds=[];$(this).hasClass("sticky")?(arrayIds.push($(this).closest("div.comment").attr("rel")),$(this).closest("div.comment").find("div.comment").each((function(e){arrayIds.push($(this).attr("rel"))})),update_sticky_comments(arrayIds,"unset")):($(this).parents("div.comment").each((function(e){arrayIds.push($(this).attr("rel"))})),update_sticky_comments(arrayIds,"set"))}));
$('.page-bookmarker').click(function(e){
e.preventDefault();
var pid = $(this).data('pid');
var random = $(this).data('ticket');
bookmarkPage(pid, random);
});
function bookmarkPage(pageId, random){
$.get(
'pages/bookmarks.php',
{
'id' : pageId,
'ticket' : random
},
function(data){
if(data['success'] == '1') {
var buttonTitle = 'Favourite';
if( $('.page-bookmarker').attr('title') == 'Favourite' ) {
buttonTitle = 'Unfavourite';
}
$('.page-bookmarker > i').toggleClass('colored');
$('.page-bookmarker.stacked > span').text(buttonTitle);
$('.page-bookmarker').attr('title', buttonTitle);
}
},
'json'
);
}
// the comment icon becomes a popover
$('img.ico[src="/img/icons/comments.png"]').each(function(){
var comment = $(this).attr('title');
$(this).removeAttr('title');
$(this).wrap('<a class="tib-popover" href="#" data-content="'+comment+'" data-togle="popover" data-placement="top" />');
});
$('img.ico[src="img/icons/comments.png"]').each(function(){
var comment = $(this).attr('title');
$(this).removeAttr('title');
$(this).wrap('<a class="tib-popover" href="#" data-content="'+comment+'" data-togle="popover" data-placement="top" />');
});
$('.tib-popover').popover({
html : true,
trigger : 'hover',
delay : {show: 300, hide: 300},
placement : function (context, source) {
var position = $(source).position();
if (position.top > 200) { return "top";}
if (position.left < 515) { return "right"; }
if (position.top < 200) { return "bottom";}
if (position.left > 515) { return "left"; }
return "top";
}
}).click(function(e){
e.preventDefault();
});
// LIVE CAROUSEL MANAGEMENT
// Miliseconds for the next slide
var carouselTime = 6500;
// Start carousels
$('div.carousel.slide').carousel({interval: carouselTime});
$('.tib-indicators > img').click(function(){
// IN
var index = $(this).index();
var container = $(this).closest('.carousel.slide');
container.carousel(index);
});
$('a.btn.showhider').click(function(e) {
var showHiderId = $( this ).attr('rel');
if ( $('#'+showHiderId).find('iframe').length > 0 ) {
$('#'+showHiderId+' iframe').each(function() {
if ( $(this).attr('src').indexOf('.pdf') > 0 ) {
this.contentWindow.location.reload(true);
}
});
}
});
var hTopmenu = $('#topmenu').height();
var n = 0;
$('nav.top-nav > ul > li').each(function(k, e) {
if (n > 1) {
var diff = hTopmenu-(e.offsetTop+e.offsetHeight);
$(e).find(' > ul ').css('margin-top', '-'+diff+'px');
}
n++;
});
});
</script>
</body>
</html>