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auxiliary case study</a></li><li><a href="../../page/19258/nuclear-medicine-.html">Nuclear medicine </a></li><li><a href="../../page/19273/drug-detection-analysis-.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../../page/16592/practical-scheme-of-work-ia-.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../../page/16682/internal-assessment.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../../page/18892/scaffolding-the-investigation.html">'Scaffolding' the investigation</a></li><li><a href="../../page/18896/timing-organisation-.html">Timing & organisation </a></li><li><a href="../../page/18905/choosing-the-research-question.html">Choosing the research question</a></li><li><a href="../../page/18946/personal-engagement.html">Personal engagement</a></li><li><a href="../../page/18950/exploration.html">Exploration</a></li><li><a href="../../page/18957/analysis.html">Analysis</a></li><li><a href="../../page/18965/evaluation.html">Evaluation</a></li><li><a href="../../page/18966/communication.html">Communication</a></li><li><a href="../../page/19882/internal-standardization-of-the-ia.html">Internal standardization of the IA</a></li><li><a href="../../page/19901/submitting-the-samples-for-moderation.html">Submitting the samples for moderation</a></li><li><a href="../../page/33754/ten-suggestions-for-ias-using-secondary-data.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../../page/37544/gaining-full-marks-for-a-databased-ia-.html">Gaining full marks for a databased IA </a></li><li><a href="../../page/19506/ia-example-marking-exercise-.html">IA example & marking exercise </a></li><li><a href="../../page/23929/genuine-examples-of-moderated-ia-reports.html">Genuine examples of moderated IA reports</a></li><li><a href="../../page/25234/examples-of-teacher-marked-ia-reports-.html">Examples of teacher-marked IA reports </a></li><li><a href="../../page/37542/history-of-internal-assessment.html">History of Internal Assessment</a></li></ul></li><li><a href="../../page/16598/mandatory-laboratory-components.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../../page/16613/formula-of-magnesium-oxide-.html">Formula of magnesium oxide </a></li><li><a href="../../page/16612/determining-the-mr-of-an-unknown-gas.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../../page/16615/acid-base-titrations-.html">Acid-base titrations </a></li><li><a href="../../page/16616/a-green-acid-base-practical.html">A green acid-base practical</a></li><li><a href="../../page/16617/analysis-of-aspirin-tablets.html">Analysis of aspirin tablets</a></li><li><a href="../../page/16618/caco3-in-egg-shells.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../../page/16644/enthalpy-changes.html">Enthalpy changes</a></li><li><a href="../../page/16631/reaction-rates.html">Reaction rates</a></li><li><a href="../../page/16635/rate-dependent-factors.html">Rate-dependent factors</a></li><li><a href="../../page/16636/determining-ea-for-a-reaction.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../../page/16637/iodination-of-propanone.html">Iodination of propanone</a></li><li><a href="../../page/18144/titrations-with-a-ph-meter.html">Titrations with a pH meter</a></li><li><a href="../../page/18355/redox-titration-with-kmno4-.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../../page/16640/voltaic-cells.html">Voltaic cells</a></li><li><a href="../../page/16659/3-d-molecular-modelling-.html">3-D molecular modelling </a></li></ul></li><li><a href="../../page/17168/other-good-practicals.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../../page/17196/common-chemical-reactions.html">Common chemical reactions</a></li><li><a href="../../page/227/elements-oxides-of-the-third-period-.html">Elements & oxides of the third period </a></li><li><a href="../../page/17239/the-halogens.html">The halogens</a></li><li><a href="../../page/17162/boiling-points-of-mixtures.html">Boiling points of mixtures</a></li><li><a href="../../page/17170/polarity-of-molecules.html">Polarity of molecules</a></li><li><a href="../../page/18083/le-chateliers-principle-.html">Le Chatelier's principle </a></li><li><a href="../../page/19582/determining-kc-for-an-esterification-reaction.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../../page/18164/redox-reactions-of-vanadium-.html">Redox reactions of vanadium </a></li><li><a href="../../page/18351/chlorine-in-swimming-pools-.html">Chlorine in swimming pools </a></li><li><a href="../../page/18178/analysis-of-cuii-ions-in-solution-.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../../page/18179/percentage-of-copper-in-brass.html">Percentage of copper in brass</a></li><li><a href="../../page/18356/electrolytic-cells-.html">Electrolytic cells </a></li><li><a href="../../page/18598/reactions-of-organic-compounds.html">Reactions of organic compounds</a></li><li><a href="../../page/18752/hydrolysis-of-halogenoalkanes.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../../page/18784/preparation-of-13-dinitrobenzene-.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../../page/19022/determination-of-an-organic-structure.html">Determination of an organic structure</a></li><li><a href="../../page/19887/preparation-of-nylon-66.html">Preparation of nylon 6,6</a></li><li><a href="../../page/19343/determination-of-vitamin-c-content-.html">Determination of vitamin C content </a></li><li><a href="../../page/19342/hydrolysis-of-starch-.html">Hydrolysis of starch </a></li><li><a href="../../page/19159/preparation-purification-of-aspirin-.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../../page/18851/ict-in-practical-work.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../../page/18852/data-logging-.html">Data logging </a></li><li><a href="../../page/18853/software-for-graph-plotting-.html">Software for graph plotting </a></li><li><a href="../../page/18854/spreadsheets-for-data-processing-.html">Spreadsheets for data processing </a></li><li><a href="../../page/18855/databases.html">Databases</a></li><li><a href="../../page/18856/computer-modelling-simulations-.html">Computer modelling & simulations </a></li></ul></li><li><a href="../../page/16594/group-4-project.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../../page/16595/practicalities.html">Practicalities</a></li><li><a href="../../page/16596/reflective-statement-.html">Reflective statement </a></li></ul></li><li><a 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</a></li><li><a href="../../page/17787/hl-questions-on-each-sub-topic-.html">HL Questions on each sub-topic </a></li><li><a href="../../page/20428/hl-paper-3-section-a-questions.html">HL Paper 3 Section A questions</a></li><li><a href="../../page/17793/hl-questions-on-the-options.html">HL Questions on the options</a></li><li><a href="../../page/24973/hl-quizzes-on-option-sub-topics.html">HL Quizzes on option sub-topics</a></li><li><a href="../../page/41573/printable-versions-of-written-tasks-.html">Printable versions of written tasks </a></li></ul></li><li><a href="../../page/41465/complete-course-for-students-.html">Complete course for students </a><ul class="level-1"><li><a href="../../page/27988/full-coverage-of-each-topic-and-sub-topic.html" class="father">Full coverage of each topic and sub-topic</a><ul class="level-2"><li><a href="../../page/27959/topic-1-stoichiometric-relationships.html">Topic 1 : Stoichiometric relationships</a></li><li><a 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<h1 class="section-title">Paraquat</h1>
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Monday 28 November 2011
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<img alt="" class="noborder" height="269" src="../../../ib/chemistry/images/blog/Spraying%20paraquat-1.jpg" title="Spraying a rice field near Alleppey in India with paraquat" width="640"></p>
<p>
I took some time off recently and went on a trip to India. Whilst wandering around the fields adjacent to the backwaters around Alappuzha (formerly Alleppey) in Kerala I came across a farmer spraying his rice crop (above). I noticed that he was not wearing any protection against the spray and wondered what chemical(s) he was actually spraying on his crops.</p>
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<br>
<img alt="" class="noborder left" height="150" src="../../../ib/chemistry/images/blog/empty%20paraquat%20cannisters.jpg" title="Discarded empty cannisters of paraquat left by the farmer on the edge of the field." width="200"><img alt="" class="noborder right" height="218" src="../../../ib/chemistry/images/blog/paraquat%20label.jpg" title="Label on one of the empty cannisters of 'Chemspray' containing paraquat" width="200">At the edge of the field I came across his discarded canisters (left and expanded on right). He was using the herbicide paraquat. Paraquat is a substituted bipyridine salt and has the chemical name <em>N</em>,<em>N</em>′-dimethyl-4,4′-bipyridinium dichloride. Although herbicides and pesticides were once on the old Applied Chemistry syllabus they no longer form part of the food option so IB students would not be expected to know anything about them. However paraquat could be used to illustrate a couple of useful concepts that are on the current syllabus. (Remember that future exam questions may well use unfamiliar substances such as paraquat to test the understanding of objective 3 concepts that are on the syllabus.)</p>
<p>
One is the international aspect. Although paraquat is one of the <a href="http://www.pan-uk.org/pestnews/Actives/paraquat.htm">most widely used herbicides in the world</a> farmers and gardeners who live in the European Union cannot purchase it or use it as it has been <a href="http://www.fwi.co.uk/Articles/27/07/2007/105481/Court-bans-paraquat-use.htm">banned since 2007</a>. This is because it is very toxic and there is no known antidote – hence my surprise at seeing the farmer use it with no protection (and leaving the canisters lying around where possibly children could find them and play with them). The laws governing the use of certain chemicals in different countries provide a good example of the international aspects of chemistry.</p>
<p>
<img alt="" class="left noborder" height="68" src="../../../ib/chemistry/images/blog/Paraquat%20structure.png" title="Structure of paraquat (image form Wikimedia commons)" width="214"><img alt="" class="noborder right" height="107" src="../../../ib/chemistry/images/blog/Paraquat-3D-balls.png" title="Model of paraquat molecule (image from Wikimedia commons)" width="214"></p>
<p>
The second is that paraquat provides a good example to test the understanding of hybridization for Higher Level students in Topic 14.2. Students have learned that the nitrogen atom is sp<sup>3</sup> hybridized in both ammonia and the ammonium ion. Ask them what the hybridization of the nitrogen is in paraquat. They should be able to deduce that as both nitrogen atoms (actually ions) are part of the aromatic ring system the hybridization is the same and the nitrogen must be sp<sup>2</sup> hybridized. Two of the p orbitals hybridize with the s orbital to give three sp<sup>2</sup> hybrid orbitals with bond angles of 120<sup>o</sup> leaving one electron in the p orbital of each nitrogen ion to contribute to the delocalisation within the aromatic ring.</p>
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<p class="search-tags"><strong>Tags: </strong><a href="../../search/hybridization.html">hybridization</a>, <a href="../../search/sp3.html">sp3</a>, <a href="../../search/internationalism.html">internationalism</a>, <a href="../../search/index.htm"></a></p>
<div class="prevnext-posts"><div class="pull-right text-right"><a href="../11176/curriculum-review-progress.html" style="font-style: normal">Curriculum review progress <i class="fa fa-chevron-circle-right"></i></a><br><em class="gray"><small>2 Dec 2011</small></em></div><div class="pull-left"><a href="../11026/peer-reviewed-articles.html" style="font-style: normal"><i class="fa fa-chevron-circle-left"></i> Peer reviewed articles</a><br><em class="gray"><small>2 Nov 2011</small></em></div></div>
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Please enable cookies to log in.</div><div class="alert alert-info"><i class="fa fa-question-circle"></i> Enabling cookies in <a target="_blank" style="margin: 0; padding: 0;" href="https://support.mozilla.org/en-US/kb/enable-and-disable-cookies-website-preferences">Firefox</a>, <a target="_blank" style="margin: 0; padding: 0;" href="https://support.google.com/accounts/answer/61416?hl=en">Chrome</a>, <a target="_blank" style="margin: 0; padding: 0;" href="http://windows.microsoft.com/en-us/windows-vista/block-or-allow-cookies">Explorer</a></div>';$("#modal-login .modal-header").append(msg)}if($(".panel-expandable > .panel-heading").click((function(e){e.preventDefault();var panel=$(this).closest(".panel-expandable"),expandables=panel.hasClass("panel-has-footer")?".panel-body, .panel-footer":".panel-body";panel.find(".panel-body").is(":visible")?(panel.find(expandables).slideUp("fast"),panel.find(".expander > .fa-minus").removeClass("fa-minus").addClass("fa-plus")):(panel.find(expandables).slideDown("fast"),panel.find(".expander > .fa-plus").removeClass("fa-plus").addClass("fa-minus"))})),$("#modal-find-out-more").css({width:.8*$("#container").width()+"px","margin-left":-.4*$("#container").width()+"px"}),$(".modal-xxl").length){var modalTopPos=Math.round(.07*$(window).height());$(window).width()>1200&&$(".modal-xxl").css({"max-width":$(window).width()>960?"960px":$(window).width()+"px",width:$(window).width()>960?"960px":$(window).width()+"px","margin-left":$(window).width()>960?"-480px":Math.round($(window).width()/2)}),$(".modal-xxl").css("top",modalTopPos+"px"),$(".modal-xxl").on("shown",(function(){var mHeaderH=$(this).find(".modal-header").outerHeight(),mBody=$(this).find(".modal-body"),mBodyH=mBody.outerHeight(),mFooterH=$(this).find(".modal-footer").outerHeight(),bottomOfTheModal=modalTopPos+mHeaderH+mBodyH+mFooterH;if(bottomOfTheModal<$(window).height())mBodyH+=$(window).height()-bottomOfTheModal-60,mBody.css("max-height",mBodyH+"px");else{$(window).scrollTop(0),modalTopPos=10,$(".modal-xxl").css("top",modalTopPos+"px"),bottomOfTheModal=modalTopPos+mHeaderH+mBodyH+mFooterH,availableScroll=bottomOfTheModal-$(window).height()+modalTopPos;var lastPos=-1;$(window).on("scroll",(function(){var s=$(window).scrollTop()>availableScroll?availableScroll:$(window).scrollTop();newPos=modalTopPos-s,newPos!=lastPos&&($(".modal-xxl").css("top",newPos+"px"),lastPos=newPos)}))}}))}function popupHelp(url,title,w,h){var dualScreenLeft=void 0!==window.screenLeft?window.screenLeft:screen.left,dualScreenTop=void 0!==window.screenTop?window.screenTop:screen.top,width,height,left=(window.innerWidth?window.innerWidth:document.documentElement.clientWidth?document.documentElement.clientWidth:screen.width)/2-w/2+dualScreenLeft,top=(window.innerHeight?window.innerHeight:document.documentElement.clientHeight?document.documentElement.clientHeight:screen.height)/2-h/2+dualScreenTop,newWindow=window.open(url,title,"menubar=no,location=no,resizable=0, width="+w+", height="+h+", top="+top+", left="+left);return window.focus&&(newWindow?newWindow.focus():$('<div class="alert alert-warning" style="margin-bottom: 0px;"><p class="help-block">Pop Up blocked. Please allow Pop Ups in your browser settings.</p></div>').insertBefore("body")),newWindow}if($(".open-student-access-help").click((function(e){e.preventDefault();var h=$(window).height()-20,w=$(window).width()<1280?$(window).width():1280;popupHelp(helpURL,"Student Access Help",w,h)})),$(".pop-up-help").click((function(e){e.preventDefault();var url=$(this).attr("href"),title=$(this).data("title"),h=$(window).height()-20,w;popupHelp(url,title,$(window).width()<1280?$(window).width():1280,h)})),$("section.tib-hiddenbox").length){var count=0;$($("section.tib-hiddenbox").get().reverse()).each((function(){var box=$(this),revealButton;$("<a />").attr("class","btn showhider").attr("rel","hiddenBoxContent"+count).attr("style","margin-bottom: 0;").html('<i class="fa fa-eye"></i>').insertBefore(box);var newContainer=$("<div />").attr("class","hidden-content").attr("id","hiddenBoxContent"+count).html(box.html());newContainer.hide(),newContainer.insertBefore(box),box.remove(),count++})),$("a.showhider").on("click",(function(e){var container=$("#"+$(this).attr("rel"));container.is(":hidden")?(container.fadeIn("fast"),$(this).html('<i class="fa fa-eye-slash"></i>')):(container.fadeOut("fast"),$(this).html('<i class="fa fa-eye"></i>'))}))}
let commentEditor={};function initCommentsEditor(){const t=document.querySelector("#comment-content");t&&CKEDITOR.BasicEditor.create(t,{toolbar:{viewportTopOffset:50,items:["bold","italic","link","subscript","superscript"]},link:{decorators:{addLinkNoFollow:{mode:"automatic",callback:function(t){if(null!=t)return["http://","http://www","https://","https://www","ftp:"].some((o=>t.startsWith(o)))},attributes:{target:"_blank",class:"ck-link",rel:"nofollow"}}}}}).then((function(t){commentEditor=t,commentEditor.execute("heading",{value:"paragraph"})})).catch((function(t){console.error(t)}))}function replaceComment(content,commentId){$("#cancel-comment-post").trigger("click"),$("#comm-"+commentId+" > .comment-content div.comment-text").html(content)}function placeComment(html,fatherId){$("#comment-form").hide(),$("#comment-form textarea").val(""),fatherId>0?($("#comments #comm-"+fatherId).append(html),$("#comments").append($("#comment-form"))):$("#comments").append(html).append($("#comment-form")),$(".comment .fa-arrow-down").removeClass("fa-arrow-down").addClass("fa-reply"),$(".comment-content").removeClass("marked"),$("#comment-form").show("fast")}function update_sticky_comments(arrIds,mode){$.post("pages/edit/update-sticky-comments.php?mode="+mode,{ids:arrIds,ticket:$("#comment-ticket").val()},(function(data){1==data.success?("set"==data.mode&&$("#sticky-"+data.id).parents("div.comment").each((function(e){$(this).find("a.pull-right").first().addClass("sticky"),$(this).find("a.pull-right").first().attr("title","Unmark as important")})),"unset"==data.mode&&($("#sticky-"+data.id).removeClass("sticky"),$("#sticky-"+data.id).attr("title","Mark as important"),$("#sticky-"+data.id).closest("div.comment").find("div.comment").each((function(e){$(this).find("a.pull-right").first().removeClass("sticky"),$(this).find("a.pull-right").first().attr("title","Mark as important")})))):alert(data.error)}),"json")}"undefined"!=typeof CKEDITOR&&initCommentsEditor(),$("section#comments").on("click","#edit-comment",(function(e){e.preventDefault();var commentId=$("form#comment-form #comment-mode").val(),commentContent=commentEditor.getData(),ticket=$("#comment-ticket").val(),sectionId=$("#section-id").val();$.post("pages/comment.php",{action:"edit",comment_id:commentId,content:commentContent,ticket:ticket},(function(data){"0"==data.success?alert(data.error):replaceComment(data.text,commentId)}),"json")})),$("section#comments").on("click","a.edit-comment",(function(e){e.preventDefault(),$(".comment .hidden").removeClass("hidden");var commentId=$(this).data("comment-id"),form=$("form#comment-form"),text=$("#comm-"+commentId+" > .comment-content div.comment-text").html();commentEditor.setData(text),$("form#comment-form textarea").val(""),$("form#comment-form textarea").val(text),$("#comm-"+commentId+" > .comment-content > img").addClass("hidden"),$("#comm-"+commentId+" > .comment-content > div.comment-text").addClass("hidden"),$("#comm-"+commentId+" > .comment-footer").addClass("hidden"),$("#comm-"+commentId+" > .comment-content").append(form),$("form#comment-form #submit-comment").hide(),$("form#comment-form #edit-comment").show(),$("form#comment-form #cancel-comment-post").show(),$("form#comment-form #comment-mode").val(commentId),fancyScrollTo("comment-form"),$("form#comment-form textarea").focus()})),$("section#comments").on("click","#submit-comment",(function(e){e.preventDefault();var commentContent=commentEditor.getData(),fatherId=$("#father-comment").val(),ticket=$("#comment-ticket").val(),sectionId=$("#section-id").val();$.post("pages/comment.php",{action:"post",section_id:sectionId,father_id:fatherId,content:commentContent,ticket:ticket},(function(data){if("0"==data.success)alert(data.error);else{commentEditor.setData(""),placeComment(data.html,fatherId),$("form#comment-form #cancel-comment-post").hide();var n=0;$("#n-comments").text().length>0&&(n=parseInt($("#n-comments").text())),$("#n-comments").text(n+1)}}),"json")})),$("section#comments").on("click","a.reply-comment",(function(e){e.preventDefault(),$(".comment .fa-arrow-down").removeClass("fa-arrow-down").addClass("fa-reply"),$(".comment-content").removeClass("marked");var form=$("form#comment-form"),fatherId=$(this).parent().parent(".comment").attr("rel");form.find("#father-comment").val(fatherId),$(this).parent().parent(".comment").find("> .reply-area").append(form),$(this).find(".fa-reply").removeClass("fa-reply").addClass("fa-arrow-down"),$(this).parent().prev(".comment-content").addClass("marked"),$("form#comment-form #cancel-comment-post").show(),fancyScrollTo("comment-form"),$("form#comment-form textarea").focus()})),$("section#comments").on("click","#cancel-comment-post",(function(e){e.preventDefault(),$(".comment .hidden").removeClass("hidden"),$(".comment .fa-arrow-down").removeClass("fa-arrow-down").addClass("fa-reply"),$(".comment-content.marked").removeClass("marked"),commentEditor.setData("");var form=$("form#comment-form");$("section#comments").append(form),$("form#comment-form #father-comment").val("0"),$("form#comment-form textarea").val(""),$("form#comment-form #comment-mode").val("new"),$("#edit-comment").hide(),$(this).hide(),$("#submit-comment").show()})),$("section#comments").on("click","a.delete-comment",(function(e){var commentId=$(this).data("comment-id"),isFather=$("#comm-"+commentId).children(".comment").length>0,ticket=$("#comment-ticket").val(),msg="You are going to delete a comment.\n\nThis action cannot be undone.\n\nAre you sure?";isFather&&(msg="You are going to delete a comment and all its replies.\n\nThis action cannot be undone.\n\nAre you sure?"),confirm(msg)&&$.post("pages/comment.php",{action:"delete",comment_id:commentId,is_father:isFather,ticket:ticket},(function(data){if("0"==data.success)alert(data.error);else{$("#comm-"+commentId+".comment").replaceWith(data.text);var n=0;$("#n-comments").text().length&&(n=parseInt($("#n-comments").text())),$("#n-comments").text(n-parseInt(data.deleted))}}),"json"),e.preventDefault(),e.stopPropagation()})),$("section#comments").on("click","a.pull-right",(function(e){e.preventDefault();var arrayIds=[];$(this).hasClass("sticky")?(arrayIds.push($(this).closest("div.comment").attr("rel")),$(this).closest("div.comment").find("div.comment").each((function(e){arrayIds.push($(this).attr("rel"))})),update_sticky_comments(arrayIds,"unset")):($(this).parents("div.comment").each((function(e){arrayIds.push($(this).attr("rel"))})),update_sticky_comments(arrayIds,"set"))}));
$('.page-bookmarker').click(function(e){
e.preventDefault();
var pid = $(this).data('pid');
var random = $(this).data('ticket');
bookmarkPage(pid, random);
});
function bookmarkPage(pageId, random){
$.get(
'pages/bookmarks.php',
{
'id' : pageId,
'ticket' : random
},
function(data){
if(data['success'] == '1') {
var buttonTitle = 'Favourite';
if( $('.page-bookmarker').attr('title') == 'Favourite' ) {
buttonTitle = 'Unfavourite';
}
$('.page-bookmarker > i').toggleClass('colored');
$('.page-bookmarker.stacked > span').text(buttonTitle);
$('.page-bookmarker').attr('title', buttonTitle);
}
},
'json'
);
}
// the comment icon becomes a popover
$('img.ico[src="/img/icons/comments.png"]').each(function(){
var comment = $(this).attr('title');
$(this).removeAttr('title');
$(this).wrap('<a class="tib-popover" href="#" data-content="'+comment+'" data-togle="popover" data-placement="top" />');
});
$('img.ico[src="img/icons/comments.png"]').each(function(){
var comment = $(this).attr('title');
$(this).removeAttr('title');
$(this).wrap('<a class="tib-popover" href="#" data-content="'+comment+'" data-togle="popover" data-placement="top" />');
});
$('.tib-popover').popover({
html : true,
trigger : 'hover',
delay : {show: 300, hide: 300},
placement : function (context, source) {
var position = $(source).position();
if (position.top > 200) { return "top";}
if (position.left < 515) { return "right"; }
if (position.top < 200) { return "bottom";}
if (position.left > 515) { return "left"; }
return "top";
}
}).click(function(e){
e.preventDefault();
});
// LIVE CAROUSEL MANAGEMENT
// Miliseconds for the next slide
var carouselTime = 6500;
// Start carousels
$('div.carousel.slide').carousel({interval: carouselTime});
$('.tib-indicators > img').click(function(){
// IN
var index = $(this).index();
var container = $(this).closest('.carousel.slide');
container.carousel(index);
});
$('a.btn.showhider').click(function(e) {
var showHiderId = $( this ).attr('rel');
if ( $('#'+showHiderId).find('iframe').length > 0 ) {
$('#'+showHiderId+' iframe').each(function() {
if ( $(this).attr('src').indexOf('.pdf') > 0 ) {
this.contentWindow.location.reload(true);
}
});
}
});
var hTopmenu = $('#topmenu').height();
var n = 0;
$('nav.top-nav > ul > li').each(function(k, e) {
if (n > 1) {
var diff = hTopmenu-(e.offsetTop+e.offsetHeight);
$(e).find(' > ul ').css('margin-top', '-'+diff+'px');
}
n++;
});
});
</script>
</body>
</html>