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href="../2776/measurement-ahl-hl-only-paper-1-questions.html">Measurement AHL (HL only) paper 1 questions</a></label></li></ul></div> <button id="show-periodic-table" class="btn btn-default btn-block" style="margin-bottom: 10px"><i class="fa fa-table"></i>&nbsp;&nbsp;Periodic table</button> <div class="hidden-xs hidden-sm"> <button class="btn btn-default btn-block text-xs-center" data-toggle="modal" data-target="#modal-feedback" style="margin-bottom: 10px"><i class="fa fa-send"></i>&nbsp;&nbsp;Feedback</button> </div> </div> <div class="col-md-9" id="main-column"> <h1 class="page_title"> Energetics core (SL and HL) paper 1 questions <a href="#" class="mark-page-favorite pull-right" data-pid="2708" title="Mark as favorite" onclick="return false;"><i class="fa fa-star-o"></i></a> </h1> <ol class="breadcrumb"> <li><a href="../../../chemistry.html"><i class="fa fa-home"></i></a><i class="fa fa-fw fa-chevron-right divider"></i></li><li><a href="../2075/paper-1-exam-questions.html">Paper 1 Exam Questions</a><i class="fa fa-fw fa-chevron-right divider"></i></li><li><span class="gray">Energetics core (SL and HL) paper 1 questions</span></li> <span class="pull-right" style="color: #555" title="Suggested study time: 30 minutes"><i class="fa fa-clock-o"></i> 30&apos;</span> </ol> <article id="main-article"> <p><strong>Topics 5.1, 5.2 and 5.3</strong></p> <p><strong>Paper 1 style questions&nbsp;</strong>are multiple choice. You are&nbsp;<strong>not permitted to use a calculator or the data book</strong>&nbsp;for these questions, but you should use a periodic table.</p> <p>A&nbsp;<strong>periodic table pop-up</strong>&nbsp;is available on the left hand menu.</p> <div class="greenBg"> <div class="tib-quiz" data-stats="7-812-2708"><div class="label label-default q-number">1</div><div class="exercise shadow-bottom"><div class="q-question"><p>Using the standard enthalpies of combustion given below, what is enthalpy change for the following reaction?</p><p style="text-align: center;">C<sub>7</sub>H<sub>16</sub> (l) &rarr; C<sub>2</sub>H<sub>4 </sub>(g) + C<sub>5</sub>H<sub>12</sub> (l)</p><p>&Delta;Hc&deg;(C<sub>7</sub>H<sub>16 (l)</sub>) = &minus;4817 kJ mol<sup>&minus;1</sup></p><p>&Delta;Hc&deg;(C<sub>2</sub>H<sub>4 (g)</sub>) = &minus;1411 kJ mol<sup>&minus;1</sup></p><p>&Delta;Hc&deg;(C<sub>5</sub>H<sub>12</sub> <sub>(l)</sub>) = &minus;3509 kJ mol<sup>&minus;1</sup></p></div><div class="q-answer"><p><label class="radio"> <input class="c" type="radio"> + 1411 + 3509 &minus; 4817 </label></p><p><label class="radio"> <input type="radio"> <span>&minus; 1411 &minus; 3509 + 4817</span></label> </p><p><label class="radio"> <input type="radio"> <span>+ 1411 &minus; 3509 &minus; 4817</span></label> </p><p><label class="radio"> <input type="radio"> <span>+ 1411 + 3509 + 4817</span></label> </p></div><div class="q-explanation"><p>We are given &Delta;H combustion data so we construct the energy cycle by linking the reactants and products through the combustion products (arrows point down to combustion products):</p><p><img alt="" src="../../images/energetics-thermochemistry/hess-generic-comb.png" style="width: 240px; height: 103px;"></p><p>The enthalpy change for the reaction given (A) can then be found: The alternative route going via the combustion products is therefore A = B&minus;C (&minus;C because we are going against the arrow so the sign must be inverted).</p><p>All changes are for <strong>one mole </strong>of combustion, so the calculation is as follows:</p><p>B = &minus;4817</p><p>C = (&minus;1411)+(&minus;3509) = &minus;1411&minus;3509</p><p>A = B&minus;C = &minus;4817&minus;(&minus;1411&minus;3509) = &minus;4817+1411+3509 which rearranged in the order given in the answer gives + 1411 + 3509 &minus; 4817</p><p>The correct answer is therefore <strong>+ 1411 + 3509 &minus; 4817</strong></p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">2</div><div class="exercise shadow-bottom"><div class="q-question"><p>Which equation represents the P&minus;H bond enthalpy in PH<sub>3</sub>?</p></div><div class="q-answer"><p><label class="radio"> <input type="radio"> <span>PH<sub>3(g)</sub> &rarr; P<sub>(g)</sub> + 1&frac12;H<sub>2(g)</sub></span></label> </p><p><label class="radio"> <input type="radio"> <span>PH<sub>3(g) </sub>&rarr; P<sub>(g)</sub> + 3H<sub>(g)</sub></span></label> </p><p><label class="radio"> <input type="radio"> <span>PH<sub>3(g)</sub> &rarr; PH<sub>2(g)</sub> + H<sub>(g)</sub></span></label> </p><p><label class="radio"> <input class="c" type="radio"> ⅓<span>PH<sub>3(g)</sub> &rarr; ⅓P<sub>(g)</sub> + H<sub>(g)</sub></span></label> </p></div><div class="q-explanation"><p>Bond enthalpy is defined as the <strong>average</strong> enthalpy required to break one mole of covalent bonds in the gaseous state.</p><p>So the best representation is going to be a chemical change showing the average breaking of one mole of P&minus;H bonds in the gaseous state.</p><p>PH<sub>3(g)</sub> &rarr; PH<sub>2(g)</sub> + H<sub>(g)</sub> shows a single P&minus;H bond breaking and by definition (stoichiometric coefficients) we have one mole of bonds breaking. But, when we break the bonds in any molecule one-by-one the bonds will all have different enthalpies as the environment of the bonds is changing.</p><p>Therefore we need to break <strong>all three bonds</strong> in PH<sub>3</sub> and find the <strong>average enthalpy</strong>:</p><p>⅓PH<sub>3(g)</sub> &rarr; ⅓P<sub>(g)</sub> + H<sub>(g) </sub>is thus the correct answer.</p><p><strong>Incorrect answers</strong></p><p>PH<sub>3(g) </sub>&rarr; P<sub>(g)</sub> + 3H<sub>(g)</sub> and PH<sub>3(g)</sub> &rarr; P<sub>(g)</sub> + 1&frac12;H<sub>2(g) </sub>both show <strong>three </strong>moles of P&minus;H bonds breaking, with the hydrogen products shown as atoms or molecules.</p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">3</div><div class="exercise shadow-bottom"><div class="q-question"><p>When equal masses of X and Z absorb the same amount of energy their temperatures rise by 10&deg;C and 20&deg;C respectively.</p><p>Which is correct?</p></div><div class="q-answer"><p><label class="radio"><input type="radio"> The specific heat capacity of X is half that of Z</label></p><p><label class="radio"><input type="radio"> The specific heat capacity of X is ten times that of Z</label></p><p><label class="radio"><input class="c" type="radio"> The specific heat capacity of X is twice that of Z</label></p><p><label class="radio"><input type="radio"> The specific heat capacity of X is the same as Z</label></p></div><div class="q-explanation"><p>Specific heat capacity is the amount of energy needed (J) to raise one unit of mass (g) by one unit of temperature (K or &deg;C - the interval/unit size is the same so either if fine). E.g. the specific heat capacity of water is 4.18 JK<sup>&minus;1</sup>g<sup>&minus;1</sup></p><p>In this question the same amount of energy raises X by 10&deg;C and Z by 20&deg;C. So it takes more energy to raise the temperature of X than Z. In fact, as the relationship between mass and energy needed to raise the temperature is linear, it must take twice as much energy to raise X by 20&deg;C. So X must have twice the specific heat capacity of Z.</p><p><strong>The specific heat capacity of X is twice that of Y</strong> is therefore the correct answer.</p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">4</div><div class="exercise shadow-bottom"><div class="q-question"><p>Which is correct for the reaction?</p><p>2NO<sub>2</sub> &rarr; N<sub>2</sub>O<sub>4</sub> &Delta;H = &minus;57.6 kJ mol<sup>&minus;1</sup></p></div><div class="q-answer"><p><label class="radio"> <input type="radio"> <span>The products are less stable than the reactants and the reaction is endothermic.</span></label> </p><p><label class="radio"> <input class="c" type="radio"> <span>The products are more stable than the reactants and the reaction is exothermic.</span></label> </p><p><label class="radio"> <input type="radio"> <span>The products are less stable than the reactants and the reaction is exothermic.</span></label> </p><p><label class="radio"> <input type="radio"> <span>The products are more stable than the reactants and the reaction is endothermic.</span></label> </p></div><div class="q-explanation"><p>A negative &Delta;H indicates that the reaction is exothermic.</p><p>If a reaction is exothermic, then heat energy (enthaply) is transferred from the system to the surroundings. Thus the system loses energy; &Delta;H is negative, and the energy of the products is lower than the energy of the reactants; so the products are <strong>more stable </strong>than the reactants.</p><p>Thus<strong>, the products are more stable than the reactants and the reaction is exothermic</strong> is the correct answer.</p><p>On the left; exothermic - on the right; endothermic.</p><p><img alt="" src="../../images/energetics-thermochemistry/exo-endo.png" style="width: 486px; height: 270px;"></p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">5</div><div class="exercise shadow-bottom"><div class="q-question"><p>What is the enthalpy change for the incomplete combustion of ethene using average bond enthalpies given below.</p><p><span style="font-size: 15px;">C<sub>2</sub></span><span style="font-size: 15px;">H<sub>4 </sub></span>(g) + 2O<sub>2 </sub>(g) &rarr; 2CO (g) + 2H<sub>2</sub>O (g)</p><p>Bond enthalpies (in kJ mol<sup>&minus;1</sup>) that you may require: C&minus;H 414 / C=C 614 / O=O 498 / C&equiv;O 1077 / O&minus;H 463</p></div><div class="q-answer"><p><label class="radio"> <input type="radio"> [2(1077) + 2(463)] &minus; [614 + 4(414) + 2(498)]</label></p><p><label class="radio"> <input type="radio"> [614 + 4(414) + 2(498)] &minus; [2(1077) + 2(463)]</label></p><p><label class="radio"> <input class="c" type="radio"> [614 + 4(414) + 2(498)] &minus; [2(1077) + 4(463)]</label></p><p><label class="radio"> <input type="radio"> [2(1077) + 4(463)] &minus; [614 + 4(414) + 2(498)]</label></p></div><div class="q-explanation"><p>Total energy change = bonds broken &minus; bonds made</p><p>Bonds present in reactants: 1&times;C=C, 4&times;C&minus;H, 2&times;O=O</p><p>Bonds present in products: 2&times;C&equiv;O, 4&times;O&minus;H</p><p>Assuming all the bonds in reactants are broken and all bonds in products are made:</p><p>Enthalpy for bonds broken: 614 + 4(414) + 2(498)</p><p>Enthalpy for bonds made: 2(1077) + 4(463)</p><p>Thus the correct answer is<strong> [614 + 4(414) + 2(498)] &minus; [2(1077) + 4(463)]</strong></p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">6</div><div class="exercise shadow-bottom"><div class="q-question"><p>Using the standard enthalpies given below, what is the standard enthalpy of combustion of ethane in <strong>kJ mol<sup>&minus;1</sup></strong>?</p><p style="text-align: center;">2C<sub>2</sub>H<sub>6</sub> (g) + 7O<sub>2</sub> (g) &rarr; 4CO<sub>2</sub> (g) + 6H<sub>2</sub>O (l)</p><p>C (s) + O<sub>2</sub> (g) &rarr; CO<sub>2</sub> (g) = <strong><em>X</em></strong> kJ mol<sup>&minus;1</sup></p><p>H<sub>2</sub> (g) + &frac12;O<sub>2</sub> (g) &rarr; H<sub>2</sub>O (l) = <strong><em>Y</em></strong> kJ mol<sup>&minus;1</sup></p><p>2C (s) + 3H<sub>2</sub> (g) &rarr; C<sub>2</sub>H<sub>6</sub> (g) = <strong><em>Z</em></strong> kJ mol<sup>&minus;1</sup></p></div><div class="q-answer"><p><label class="radio"><input type="radio"> 2<em><strong>X</strong></em> + 3<em><strong>Y</strong></em> + <em><strong>Z</strong></em></label></p><p><label class="radio"><input type="radio"> 4<em><strong>X</strong></em> + 6<em><strong>Y</strong></em> + 2<em><strong>Z</strong></em></label></p><p><label class="radio"><input type="radio"> 4<em><strong>X</strong></em> + 6<em><strong>Y</strong></em> &minus; 2<em><strong>Z</strong></em></label></p><p><label class="radio"><input class="c" type="radio"> 2<em><strong>X</strong></em> + 3<em><strong>Y</strong></em> &minus; <em><strong>Z</strong></em></label></p></div><div class="q-explanation"><p>We are given &Delta;H formation data so we construct the energy cycle by linking the reactants and products through the elements (arrows point up from elements):</p><p><img alt="" src="../../images/energetics-thermochemistry/hess-generic-form.png" style="width:240px;height:100px;"></p><p>The enthalpy change for the reaction given (A) can then be found: The alternative route going via the elements is therefore A = &minus;B+C (&minus;B because we are going against the arrow so the sign must be inverted).</p><p>As <strong>written in the question</strong>, the changes are:</p><p>B = 2<strong><em>Z</em></strong> (O<sub>2</sub> is already an element so there is no change)</p><p>C = 4<em><strong>X</strong></em> + 6<em><strong>Y</strong></em></p><p>A = &minus;B+C = &minus;2<em><strong>Z</strong></em> + 4<strong><em>X</em></strong> + 6<em><strong>Y</strong></em></p><p>or rearranged: 4<em><strong>X</strong></em> + 6<em><strong>Y</strong></em> &minus; 2<em><strong>Z</strong></em></p><p>But this is for <strong>two moles</strong> of ethane! The standard enthalpy of combustion is always <strong>per mole</strong> (hence units <strong>kJ mol<sup>&minus;1</sup></strong>).</p><p>The correct answer is therefore 2<em><strong>X</strong></em> + 3<em><strong>Y</strong></em> &minus; <em><strong>Z</strong></em></p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">7</div><div class="exercise shadow-bottom"><div class="q-question"><p>Two 50.0 cm<sup>3</sup> aqueous solutions containing 0.020 mol of hydrochloric acid and 0.020 mol of sodium hydroxide respectively are both at 298K.</p><p>When the two solutions are mixed the temperature rises by <i>y</i> &deg;C.</p><p>Assume that the density of the final solution is 1.00 g cm<sup>&minus;3</sup> and the specific heat capacity is 4.18 J K<sup>&minus;1</sup> g<sup>&minus;1.</sup></p><p>What is the enthalpy change of neutralisation in <strong>kJ mol<sup>&minus;1</sup></strong>?</p></div><div class="q-answer"><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\({100 \times 4.18 \times y \over 0.020}\)</span></span></label></p><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\({100 \times 4.18 \times (y+273) \over 1000 \times 0.040}\)</span></span></label> </p><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\({100 \times 4.18 \times y \over 0.040}\)</span></span></label></p><p><label class="radio"> <input class="c" type="radio"> <span class="math-tex">\({100 \times 4.18 \times y \over 1000 \times 0.020}\)</span></label></p></div><div class="q-explanation"><p>Using Q=mc&Delta;T.</p><p>Q (heat energy) = mass &times; specific heat capacity &times; temperature change (these three values are for whatever substance is absorbing the heat energy; in this case, the final solution). The final solution is assumed to have a density of 1.00 g cm<sup>&minus;3</sup> (so 100cm<sup>3</sup> is 100g; that is the two solutions poured together).</p><p>Q = 100 &times; 4.18 &times; <em>y<strong> </strong></em><strong>Joules</strong></p><p>The enthalpy change of neutralisation must be given <strong>per mole </strong>(of HCl or NaOH) <strong>and in kJ </strong>(not in Joules).</p><p>Dividing by 0.020 will give the value <strong>per mole</strong> of HCl (or NaOH), and dividing by 1000 will give the value in<strong> kJ</strong> <strong>mol<sup>&minus;1</sup></strong>.</p><p>Thus the answer is <span class="math-tex">\({100 \times 4.18 \times y \over 1000 \times 0.020}\)</span> </p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">8</div><div class="exercise shadow-bottom"><div class="q-question"><p>Which expression gives the mass, in g, of propan-1-ol required to produce 790 kJ of heat energy upon complete combustion?</p><p>(M<sub>r</sub> for propan-1-ol = 60.1, &Delta;H<sup><s>o</s></sup>c = &minus;2021 kJ mol<sup>&minus;1</sup>)</p></div><div class="q-answer"><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\({2021 \times 60.1 \over 790}\)</span></span></label></p><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\({2021 \over 790 \times 60.1}\)</span></span></label></p><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\({790 \over 2021 \times 60.1}\)</span></span></label> </p><p><label class="radio"> <input class="c" type="radio"> <span class="math-tex">\({790 \times 60.1 \over 2021}\)</span></label></p></div><div class="q-explanation"><p>One mole of propan-1-ol produces 2021 kJ of heat energy and has a molar mass of 60.1g.</p><p>The fraction of one mole needed to produce 790 kJ of energy will therefore be <span class="math-tex">\({790 \over 2021}\)</span></p><p>Therefore the mass of propan-1-ol needed will be the mole fraction &times; molar mass, which is <span class="math-tex">\({790 \over 2021}\)</span> &times; 60.1</p><p>Thus the answer is <span class="math-tex">\({790 \times 60.1 \over 2021}\)</span> </p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">9</div><div class="exercise shadow-bottom"><div class="q-question"><p>Why is the enthalpy change for this reaction calculated from bond enthalpy data less accurate than that calculated using standard enthalpies of formation?</p><p>C<sub>3</sub>H<sub>6</sub> (g) + 4&frac12;O<sub>2</sub> (g) &rarr; 3CO<sub>2</sub> (g) + 3H<sub>2</sub>O (g)</p></div><div class="q-answer"><p><label class="radio"> <input type="radio"> Elements do not have standard enthalpies of formation</label></p><p><label class="radio"> <input type="radio"> All of the reactants and products are gases</label></p><p><label class="radio"> <input class="c" type="radio"> Bond enthalpies are average values of many compounds</label></p><p><label class="radio"> <input type="radio"> The equation is incorrectly balanced</label></p></div><div class="q-explanation"><p>Bond enthalpy is defined as the <strong>average</strong> enthalpy required to break one mole of covalent bonds in the <strong>gaseous </strong>state.</p><p>All of the species in this equation are gaseous, so that is not a problem for a bond enthalpy calculation. However, since bond enthalpies are average values, the enthalpy change calculated using bond enthalpies will not be accurate to this reaction.</p><p>Therefore the correct answer is <strong>Bond enthalpies are average values of many compounds</strong>.</p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">10</div><div class="exercise shadow-bottom"><div class="q-question"><p>What can be deduced from the knowledge that ozone absorbs ultraviolet radiation of a greater wavelength than oxygen?</p></div><div class="q-answer"><p><label class="radio"> <input type="radio"> The bonds between atoms in ozone are stronger than those in oxygen </label></p><p><label class="radio"> <input type="radio"> Only ozone can form free radicals </label></p><p><label class="radio"> <input type="radio"> Ozone absorbs radiation of a higher energy than oxygen </label></p><p><label class="radio"> <input class="c" type="radio"> The bonds between atoms in oxygen require more energy to break than those in ozone</label></p></div><div class="q-explanation"><p>Both oxygen and ozone will absorb ultraviolet radiation in the atmosphere and the bonds of both molecules may break to form oxygen free radicals. Ozone absorbs energy of a greater wavelength. Wavelength is inversely proportional to frequency and hence energy, so ozone absorbs radiation of a lower energy. </p><p>The double bond in oxygen (O<sub>2</sub>) is therefore stronger and requires more energy to break than the &#39;1&frac12;&#39; bonds in ozone (O<sub>3</sub>).</p><p>The correct answer is therefore <strong>The bonds between atoms in oxygen require more energy to break than those in ozone</strong></p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">11</div><div class="exercise shadow-bottom"><div class="q-question"><p>What is the enthalpy of formation of carbon monoxide, in kJ mol<sup>&minus;1</sup>, as represented by &Delta;H<sub>3</sub>?</p><p><img alt="" src="../../images/energetics-thermochemistry/hesseleveldiagram.png" style="width: 480px; height: 339px;"></p></div><div class="q-answer"><p><label class="radio"> <input class="c" type="radio"> 282&minus;393</label></p><p><label class="radio"> <input type="radio"> 393+282</label></p><p><label class="radio"> <input type="radio"> 393&minus;282 </label></p><p><label class="radio"> <input type="radio"> &minus;393&minus;282</label></p></div><div class="q-explanation"><p class="MsoNormal"><span calibri="" style="font-size:14.0pt;font-family:"></span></p><div><p>&Delta;H<sub>3 </sub>is the enthalpy change from elements to carbon monoxide. An alternative route is to go from elements to carbon dioxide and then back up to carbon dioxide. This alternative route &#39;goes with&#39; the first arrow of the enthalpy change &Delta;H<sub>1</sub><span style="font-size: 11.25px;"> </span>so the sign (indicating the exothermic or endothermic nature) of the enthalpy change is unchanged. And this alternative route then &#39;goes against&#39; the second arrow of the enthalpy change &Delta;H<sub>2</sub> so the sign (indicating the exothermic or endothermic nature) of the enthalpy change is inverted (minus-minus is a plus).</p><p>Therefore the enthalpy change is &minus;393&minus;(&minus;282) = 282&minus;393</p><p>Thus, the correct answer is <strong>282&minus;393</strong></p></div><p class="MsoNormal"><span calibri="" style="font-size:14.0pt;font-family:"></span></p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="label label-default q-number">12</div><div class="exercise shadow-bottom"><div class="q-question"><p>5.85g of solid sodium chloride, NaCl(s), was added to water to form 25.0g of solution. The maximum decrease in temperature was 3.7&deg;C.</p><p>What is the enthalpy change, in kJ mol<sup>&minus;1</sup> for this process?</p><p>(Assume that the specific heat capacity of the solution is 4.18 J K<sup>&minus;1</sup> g&minus;1 and the molar mass of NaCl is 58.5 g mol<sup>&minus;1</sup>.)</p></div><div class="q-answer"><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\(\Delta H=- {25\times 4.18 \times 3.7 \over 1000 \times 0.1}\)</span></span></label></p><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\(\Delta H=- {25\times 4.18 \times (3.7+273) \over 0.1}\)</span></span></label> </p><p><label class="radio"> <input type="radio"> <span><span class="math-tex">\(\Delta H=+ {25\times 4.18 \times 3.7 \over 0.1}\)</span></span></label></p><p><label class="radio"> <input class="c" type="radio"> <span class="math-tex">\(\Delta H=+ {25\times 4.18 \times 3.7 \over 1000 \times 0.1}\)</span></label></p></div><div class="q-explanation"><p>Using Q=mc&Delta;T.</p><p>Q (heat energy) = mass &times; specific heat capacity &times; temperature change (these three values are for whatever substance is absorbing the heat energy; in this case, the resulting solution).</p><p>Q = 25.0 &times; 4.18 &times; 3.7<strong> Joules</strong></p><p>The enthalpy change must be given <strong>per mole </strong><strong>and in kJ </strong>(not in Joules).</p><p>Moles of sodium chloride = <span class="math-tex">\({5.85 \over 58.5}\)</span>= 0.100 (or 0.1 for simplicity)</p><p>Dividing by 0.1 will give the value <strong>per mole</strong> of NaCl, and dividing by 1000 will give the value in<strong> kJ</strong> <strong>mol<sup>&minus;1</sup></strong>.</p><p>The temperature decreases so the reaction is endothermic, and therefore &Delta;H is positive.</p><p>Thus the answer is <span class="math-tex">\(\Delta H=+ {25\times 4.18 \times 3.7 \over 1000 \times 0.1}\)</span> </p></div><div class="actions"><span class="score" data-score="0"></span><button class="btn btn-default btn-sm btn-xs-block text-xs-center check"><i class="fa fa-check-square-o"></i> Check</button></div></div><div class="totals"><span class="score"></span><button class="btn btn-success btn-block text-center check-total"><i class="fa fa-check-square-o"></i> Check</button></div></div><hr> </div> <div class="page-container panel-self-assessment" data-id="2708"> <div class="panel-heading">MY PROGRESS</div> <div class="panel-body understanding-rate"> <div class="msg"></div>  <label class="label-lg">Self-assessment</label><p>How much of <strong>Energetics core (SL and HL) paper 1 questions</strong> have you understood?</p><div class="slider-container text-center"><div id="self-assessment-slider" class="sib-slider self-assessment " data-value="1" data-percentage=""></div></div>  <label class="label-lg">My notes</label> <textarea name="page-notes" class="form-control" rows="3" placeholder="Write your notes here..."></textarea> </div> <div class="panel-footer text-xs-center"> <span id="last-edited" class="mb-xs-3"> </span> <div class="actions mt-xs-3">  <button id="save-my-progress" type="button" class="btn btn-sm btn-primary text-center btn-xs-block"> <i class="fa fa-fw fa-floppy-o"></i> Save </button> </div> </div></div> <div id="modal-feedback" class="modal fade" tabindex="-1" role="dialog"> <div class="modal-dialog" role="document"> <div class="modal-content"> <div class="modal-header"> <h4 class="modal-title">Feedback</h4> <button type="button" class="close hidden-xs hidden-sm" data-dismiss="modal" aria-label="Close"> <span aria-hidden="true">&times;</span> </button> </div> <div class="modal-body"> <div class="errors"></div> <p><strong>Which of the following best describes your feedback?</strong></p> <form method="post" style="overflow: hidden"> <div class="form-group"> <div class="radio"><label style="color: #121212;"><input type="radio" name="feedback-type" value="Recommendation"> Recommend</label></div><div class="radio"><label style="color: #121212;"><input type="radio" name="feedback-type" value="Problem"> Report a problem</label></div><div class="radio"><label style="color: #121212;"><input type="radio" name="feedback-type" value="Improvement"> Suggest an improvement</label></div><div class="radio"><label style="color: #121212;"><input type="radio" name="feedback-type" value="Other"> Other</label></div> </div> <hr> <div class="row"> <div class="col-md-6"> <div class="form-group"> <label for="feedback-name">Name</label> <input type="text" class="form-control" name="feedback-name" placeholder="Name" value=" "> </div> </div> <div class="col-md-6"> <div class="form-group"> <label for="feedback-email">Email address</label> <input type="email" class="form-control" name="feedback-email" placeholder="Email" value="@airmail.cc"> </div> </div> </div> <div class="form-group"> <label for="feedback-comments">Comments</label> <textarea class="form-control" name="feedback-comments" style="resize: vertical;"></textarea> </div> <input type="hidden" name="feedback-ticket" value="082b9c9c4ae3624d"> <input type="hidden" name="feedback-url" value="https://studyib.net/chemistry/page/2708/energetics-core-sl-and-hl-paper-1-questions"> <input type="hidden" name="feedback-subject" value="7"> <input type="hidden" name="feedback-subject-name" value="Chemistry"> <div class="pull-left"> </div> </form> </div> <div class="modal-footer"> <button type="button" class="btn btn-primary btn-xs-block feedback-submit mb-xs-3 pull-right"> <i class="fa fa-send"></i> Send </button> <button type="button" class="btn btn-default btn-xs-block m-xs-0 pull-left" data-dismiss="modal"> Close </button> </div> </div> </div></div> <style type="text/css" media="screen">/* Important part */
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